Writing in a Polyaniline Film with Laser Beam and Stability of the Record: A Raman Spectroscopy Study

Lines were drawn on polyaniline (PANI) salt films with laser beam, and then the samples were left to age in air at room temperature. Both the irradiated and intact parts of the sample and their ageing were studied with Raman spectroscopy. It was found that the laser-written record is reasonably stab...

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Main Authors: Zuzana Morávková, Patrycja Bober
Format: Article
Language:English
Published: Wiley 2018-01-01
Series:International Journal of Polymer Science
Online Access:http://dx.doi.org/10.1155/2018/1797216
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author Zuzana Morávková
Patrycja Bober
author_facet Zuzana Morávková
Patrycja Bober
author_sort Zuzana Morávková
collection DOAJ
description Lines were drawn on polyaniline (PANI) salt films with laser beam, and then the samples were left to age in air at room temperature. Both the irradiated and intact parts of the sample and their ageing were studied with Raman spectroscopy. It was found that the laser-written record is reasonably stable. The degradation of polyaniline by laser irradiation and ageing was compared to the changes in PANI during heating. In all cases, deprotonation and crosslinking of PANI chains proceed but the relative rates of the processes vary with degradation conditions.
format Article
id doaj-art-349c1a82426147bab77db3cc84632977
institution Kabale University
issn 1687-9422
1687-9430
language English
publishDate 2018-01-01
publisher Wiley
record_format Article
series International Journal of Polymer Science
spelling doaj-art-349c1a82426147bab77db3cc846329772025-02-03T01:03:11ZengWileyInternational Journal of Polymer Science1687-94221687-94302018-01-01201810.1155/2018/17972161797216Writing in a Polyaniline Film with Laser Beam and Stability of the Record: A Raman Spectroscopy StudyZuzana Morávková0Patrycja Bober1Institute of Macromolecular Chemistry, Czech Academy of Sciences, Heyrovsky Sq. 2, Prague, Czech RepublicInstitute of Macromolecular Chemistry, Czech Academy of Sciences, Heyrovsky Sq. 2, Prague, Czech RepublicLines were drawn on polyaniline (PANI) salt films with laser beam, and then the samples were left to age in air at room temperature. Both the irradiated and intact parts of the sample and their ageing were studied with Raman spectroscopy. It was found that the laser-written record is reasonably stable. The degradation of polyaniline by laser irradiation and ageing was compared to the changes in PANI during heating. In all cases, deprotonation and crosslinking of PANI chains proceed but the relative rates of the processes vary with degradation conditions.http://dx.doi.org/10.1155/2018/1797216
spellingShingle Zuzana Morávková
Patrycja Bober
Writing in a Polyaniline Film with Laser Beam and Stability of the Record: A Raman Spectroscopy Study
International Journal of Polymer Science
title Writing in a Polyaniline Film with Laser Beam and Stability of the Record: A Raman Spectroscopy Study
title_full Writing in a Polyaniline Film with Laser Beam and Stability of the Record: A Raman Spectroscopy Study
title_fullStr Writing in a Polyaniline Film with Laser Beam and Stability of the Record: A Raman Spectroscopy Study
title_full_unstemmed Writing in a Polyaniline Film with Laser Beam and Stability of the Record: A Raman Spectroscopy Study
title_short Writing in a Polyaniline Film with Laser Beam and Stability of the Record: A Raman Spectroscopy Study
title_sort writing in a polyaniline film with laser beam and stability of the record a raman spectroscopy study
url http://dx.doi.org/10.1155/2018/1797216
work_keys_str_mv AT zuzanamoravkova writinginapolyanilinefilmwithlaserbeamandstabilityoftherecordaramanspectroscopystudy
AT patrycjabober writinginapolyanilinefilmwithlaserbeamandstabilityoftherecordaramanspectroscopystudy