Enzyme-Free Electrochemical Glucose Sensors Prepared by Dealloying Pd-Ni-P Metallic Glasses

We report the formation of enzyme-free electrochemical glucose sensors by electrochemical dealloying palladium-containing Pd-Ni-P metallic glasses. When metallic glasses with different Pd contents are used as the dealloying precursor alloys, palladium-based nanoporous metals with different ligament...

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Main Authors: Yuqiao Zeng, Hua Xiang, Chunlei Yang, Shengchen Yang, Luyang Chen, Mingwei Chen, Akihisa Inoue, Xuhai Zhang, Jianqing Jiang
Format: Article
Language:English
Published: Wiley 2014-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2014/518641
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author Yuqiao Zeng
Hua Xiang
Chunlei Yang
Shengchen Yang
Luyang Chen
Mingwei Chen
Akihisa Inoue
Xuhai Zhang
Jianqing Jiang
author_facet Yuqiao Zeng
Hua Xiang
Chunlei Yang
Shengchen Yang
Luyang Chen
Mingwei Chen
Akihisa Inoue
Xuhai Zhang
Jianqing Jiang
author_sort Yuqiao Zeng
collection DOAJ
description We report the formation of enzyme-free electrochemical glucose sensors by electrochemical dealloying palladium-containing Pd-Ni-P metallic glasses. When metallic glasses with different Pd contents are used as the dealloying precursor alloys, palladium-based nanoporous metals with different ligament and pore sizes can be obtained. The chemical compositions of the nanoporous metals also vary according to the different precursor compositions. All the as-obtained nanoporous metals exhibit electrochemical catalytic activity towards the oxidation of d-glucose, indicating that the nanoporous metals prepared by dealloying the Pd-Ni-P metallic glasses are promising materials for enzyme-free electrochemical glucose sensor.
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institution OA Journals
issn 1687-8434
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publishDate 2014-01-01
publisher Wiley
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series Advances in Materials Science and Engineering
spelling doaj-art-33db203187c640e5a50477abc45e6dc92025-08-20T02:24:15ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422014-01-01201410.1155/2014/518641518641Enzyme-Free Electrochemical Glucose Sensors Prepared by Dealloying Pd-Ni-P Metallic GlassesYuqiao Zeng0Hua Xiang1Chunlei Yang2Shengchen Yang3Luyang Chen4Mingwei Chen5Akihisa Inoue6Xuhai Zhang7Jianqing Jiang8Jiangsu Key Laboratory of Advanced Metallic Materials, School of Materials Science and Engineering, Southeast University, Nanjing 211189, ChinaJiangsu Key Laboratory of Advanced Metallic Materials, School of Materials Science and Engineering, Southeast University, Nanjing 211189, ChinaJiangsu Key Laboratory of Advanced Metallic Materials, School of Materials Science and Engineering, Southeast University, Nanjing 211189, ChinaJiangsu Key Laboratory of Advanced Metallic Materials, School of Materials Science and Engineering, Southeast University, Nanjing 211189, ChinaInstitute for Materials Research, Tohoku University, Sendai 980-8577, JapanInstitute for Materials Research, Tohoku University, Sendai 980-8577, JapanInstitute for Materials Research, Tohoku University, Sendai 980-8577, JapanJiangsu Key Laboratory of Advanced Metallic Materials, School of Materials Science and Engineering, Southeast University, Nanjing 211189, ChinaJiangsu Key Laboratory of Advanced Metallic Materials, School of Materials Science and Engineering, Southeast University, Nanjing 211189, ChinaWe report the formation of enzyme-free electrochemical glucose sensors by electrochemical dealloying palladium-containing Pd-Ni-P metallic glasses. When metallic glasses with different Pd contents are used as the dealloying precursor alloys, palladium-based nanoporous metals with different ligament and pore sizes can be obtained. The chemical compositions of the nanoporous metals also vary according to the different precursor compositions. All the as-obtained nanoporous metals exhibit electrochemical catalytic activity towards the oxidation of d-glucose, indicating that the nanoporous metals prepared by dealloying the Pd-Ni-P metallic glasses are promising materials for enzyme-free electrochemical glucose sensor.http://dx.doi.org/10.1155/2014/518641
spellingShingle Yuqiao Zeng
Hua Xiang
Chunlei Yang
Shengchen Yang
Luyang Chen
Mingwei Chen
Akihisa Inoue
Xuhai Zhang
Jianqing Jiang
Enzyme-Free Electrochemical Glucose Sensors Prepared by Dealloying Pd-Ni-P Metallic Glasses
Advances in Materials Science and Engineering
title Enzyme-Free Electrochemical Glucose Sensors Prepared by Dealloying Pd-Ni-P Metallic Glasses
title_full Enzyme-Free Electrochemical Glucose Sensors Prepared by Dealloying Pd-Ni-P Metallic Glasses
title_fullStr Enzyme-Free Electrochemical Glucose Sensors Prepared by Dealloying Pd-Ni-P Metallic Glasses
title_full_unstemmed Enzyme-Free Electrochemical Glucose Sensors Prepared by Dealloying Pd-Ni-P Metallic Glasses
title_short Enzyme-Free Electrochemical Glucose Sensors Prepared by Dealloying Pd-Ni-P Metallic Glasses
title_sort enzyme free electrochemical glucose sensors prepared by dealloying pd ni p metallic glasses
url http://dx.doi.org/10.1155/2014/518641
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