Synthesis and crystal structures of palladium complexes based on $\alpha $-amino-oximes derived from ($R$)-limonene and their application in allylic alkylation of 1,3-dioxo compounds
Coordination compounds Pd(L1)Cl$_{2}$, Pd(L2)Cl$_{2}$, and Pd(L3)Cl$_{2}$ have been synthesized from optically pure $\alpha $-amino-oxime ligands L1–L3 based on $(R)$-limonene. Structures of the new palladium complexes are characterized and described by NMR spectroscopy and X-rays. These $\alpha $-a...
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Académie des sciences
2022-04-01
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| Series: | Comptes Rendus. Chimie |
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| Online Access: | https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.142/ |
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| author | Homrani, Yasmina El Amrani, Mohamed Amin Loxq, Pauline Capet, Frédéric Suisse, Isabelle Sauthier, Mathieu |
| author_facet | Homrani, Yasmina El Amrani, Mohamed Amin Loxq, Pauline Capet, Frédéric Suisse, Isabelle Sauthier, Mathieu |
| author_sort | Homrani, Yasmina |
| collection | DOAJ |
| description | Coordination compounds Pd(L1)Cl$_{2}$, Pd(L2)Cl$_{2}$, and Pd(L3)Cl$_{2}$ have been synthesized from optically pure $\alpha $-amino-oxime ligands L1–L3 based on $(R)$-limonene. Structures of the new palladium complexes are characterized and described by NMR spectroscopy and X-rays. These $\alpha $-amino-oxime ligands were then evaluated in the palladium-catalysed allylation of 1,3-dioxo compounds. |
| format | Article |
| id | doaj-art-337cbc6a624b42c5895daec5637cf541 |
| institution | Kabale University |
| issn | 1878-1543 |
| language | English |
| publishDate | 2022-04-01 |
| publisher | Académie des sciences |
| record_format | Article |
| series | Comptes Rendus. Chimie |
| spelling | doaj-art-337cbc6a624b42c5895daec5637cf5412025-02-07T13:31:13ZengAcadémie des sciencesComptes Rendus. Chimie1878-15432022-04-0125G112513510.5802/crchim.14210.5802/crchim.142Synthesis and crystal structures of palladium complexes based on $\alpha $-amino-oximes derived from ($R$)-limonene and their application in allylic alkylation of 1,3-dioxo compoundsHomrani, Yasmina0El Amrani, Mohamed Amin1Loxq, Pauline2Capet, Frédéric3https://orcid.org/0000-0002-8832-5381Suisse, Isabelle4https://orcid.org/0000-0002-6010-4042Sauthier, Mathieu5https://orcid.org/0000-0001-7047-0532Laboratoire de Chimie Organique Appliquée, Faculté des Sciences, BP 2121, Université Abdelmalek Essaadi, Tétouan, Morocco; Univ. Lille, CNRS, Centrale Lille, Univ. Artois, UMR 8181, UCCS, Unité de Catalyse et Chimie du Solide, F-59000, Lille, FranceLaboratoire de Chimie Organique Appliquée, Faculté des Sciences, BP 2121, Université Abdelmalek Essaadi, Tétouan, MoroccoUniv. Lille, CNRS, Centrale Lille, Univ. Artois, UMR 8181, UCCS, Unité de Catalyse et Chimie du Solide, F-59000, Lille, FranceUniv. Lille, CNRS, Centrale Lille, Univ. Artois, UMR 8181, UCCS, Unité de Catalyse et Chimie du Solide, F-59000, Lille, FranceUniv. Lille, CNRS, Centrale Lille, Univ. Artois, UMR 8181, UCCS, Unité de Catalyse et Chimie du Solide, F-59000, Lille, FranceUniv. Lille, CNRS, Centrale Lille, Univ. Artois, UMR 8181, UCCS, Unité de Catalyse et Chimie du Solide, F-59000, Lille, FranceCoordination compounds Pd(L1)Cl$_{2}$, Pd(L2)Cl$_{2}$, and Pd(L3)Cl$_{2}$ have been synthesized from optically pure $\alpha $-amino-oxime ligands L1–L3 based on $(R)$-limonene. Structures of the new palladium complexes are characterized and described by NMR spectroscopy and X-rays. These $\alpha $-amino-oxime ligands were then evaluated in the palladium-catalysed allylation of 1,3-dioxo compounds.https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.142/Terpenes$\alpha $-amino-oximePalladiumAllylic alkylationN-donor ligands |
| spellingShingle | Homrani, Yasmina El Amrani, Mohamed Amin Loxq, Pauline Capet, Frédéric Suisse, Isabelle Sauthier, Mathieu Synthesis and crystal structures of palladium complexes based on $\alpha $-amino-oximes derived from ($R$)-limonene and their application in allylic alkylation of 1,3-dioxo compounds Comptes Rendus. Chimie Terpenes $\alpha $-amino-oxime Palladium Allylic alkylation N-donor ligands |
| title | Synthesis and crystal structures of palladium complexes based on $\alpha $-amino-oximes derived from ($R$)-limonene and their application in allylic alkylation of 1,3-dioxo compounds |
| title_full | Synthesis and crystal structures of palladium complexes based on $\alpha $-amino-oximes derived from ($R$)-limonene and their application in allylic alkylation of 1,3-dioxo compounds |
| title_fullStr | Synthesis and crystal structures of palladium complexes based on $\alpha $-amino-oximes derived from ($R$)-limonene and their application in allylic alkylation of 1,3-dioxo compounds |
| title_full_unstemmed | Synthesis and crystal structures of palladium complexes based on $\alpha $-amino-oximes derived from ($R$)-limonene and their application in allylic alkylation of 1,3-dioxo compounds |
| title_short | Synthesis and crystal structures of palladium complexes based on $\alpha $-amino-oximes derived from ($R$)-limonene and their application in allylic alkylation of 1,3-dioxo compounds |
| title_sort | synthesis and crystal structures of palladium complexes based on alpha amino oximes derived from r limonene and their application in allylic alkylation of 1 3 dioxo compounds |
| topic | Terpenes $\alpha $-amino-oxime Palladium Allylic alkylation N-donor ligands |
| url | https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.142/ |
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