Mode II fracture toughening and healing of composites using supramolecular polymer interlayers

This study focuses on the transfer of the healing functionality of supramolecular polymers (SP) to fibre reinforced composites through interleaving. SPs exhibiting self-healing based on hydrogen bonds were formed into films and were successfully incorporated into carbon fibre composites. The effect...

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Main Authors: V. Kostopoulos, A. Kotrotsos, A. Baltopoulos, S. Tsantzalis, P. Tsokanas, T. Loutas, A. W. Bosman
Format: Article
Language:English
Published: Budapest University of Technology and Economics 2016-11-01
Series:eXPRESS Polymer Letters
Subjects:
Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0007395&mi=cd
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author V. Kostopoulos
A. Kotrotsos
A. Baltopoulos
S. Tsantzalis
P. Tsokanas
T. Loutas
A. W. Bosman
author_facet V. Kostopoulos
A. Kotrotsos
A. Baltopoulos
S. Tsantzalis
P. Tsokanas
T. Loutas
A. W. Bosman
author_sort V. Kostopoulos
collection DOAJ
description This study focuses on the transfer of the healing functionality of supramolecular polymers (SP) to fibre reinforced composites through interleaving. SPs exhibiting self-healing based on hydrogen bonds were formed into films and were successfully incorporated into carbon fibre composites. The effect of the SP interleaves on in-plane fracture toughness and the subsequent healing capability of the hybrid composites were investigated under mode II fracture loading. The fracture toughness showed considerable increase since the maximum load (Pmax) of the hybrid composite approximately doubled, and consequently the mode II interlaminar fracture toughness energy (GIIC) exhibited an increase reaching nearly 100% compared to the reference composite. The healing component was activated using external heat. Pmax and GIIC recovery after activation were measured, exhibiting a healing efficiency after the first healing cycle close to 85% for Pmax and 100% for GIIC, eventually dropping to 80% for Pmax while GIIC was retained around 100% even after the fourth healing cycle. Acoustic Emission activity during the tests was monitored and was found to be strongly reduced due to the presence of the SP.
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institution Kabale University
issn 1788-618X
language English
publishDate 2016-11-01
publisher Budapest University of Technology and Economics
record_format Article
series eXPRESS Polymer Letters
spelling doaj-art-33019fbe58d6439c933afe9a158d12962025-08-20T03:29:34ZengBudapest University of Technology and EconomicseXPRESS Polymer Letters1788-618X2016-11-01101191492610.3144/expresspolymlett.2016.85Mode II fracture toughening and healing of composites using supramolecular polymer interlayersV. KostopoulosA. KotrotsosA. BaltopoulosS. TsantzalisP. TsokanasT. LoutasA. W. BosmanThis study focuses on the transfer of the healing functionality of supramolecular polymers (SP) to fibre reinforced composites through interleaving. SPs exhibiting self-healing based on hydrogen bonds were formed into films and were successfully incorporated into carbon fibre composites. The effect of the SP interleaves on in-plane fracture toughness and the subsequent healing capability of the hybrid composites were investigated under mode II fracture loading. The fracture toughness showed considerable increase since the maximum load (Pmax) of the hybrid composite approximately doubled, and consequently the mode II interlaminar fracture toughness energy (GIIC) exhibited an increase reaching nearly 100% compared to the reference composite. The healing component was activated using external heat. Pmax and GIIC recovery after activation were measured, exhibiting a healing efficiency after the first healing cycle close to 85% for Pmax and 100% for GIIC, eventually dropping to 80% for Pmax while GIIC was retained around 100% even after the fourth healing cycle. Acoustic Emission activity during the tests was monitored and was found to be strongly reduced due to the presence of the SP.http://www.expresspolymlett.com/letolt.php?file=EPL-0007395&mi=cdSmart polymersCFRPsSupramolecular polymersFracture toughnessSelf-healing
spellingShingle V. Kostopoulos
A. Kotrotsos
A. Baltopoulos
S. Tsantzalis
P. Tsokanas
T. Loutas
A. W. Bosman
Mode II fracture toughening and healing of composites using supramolecular polymer interlayers
eXPRESS Polymer Letters
Smart polymers
CFRPs
Supramolecular polymers
Fracture toughness
Self-healing
title Mode II fracture toughening and healing of composites using supramolecular polymer interlayers
title_full Mode II fracture toughening and healing of composites using supramolecular polymer interlayers
title_fullStr Mode II fracture toughening and healing of composites using supramolecular polymer interlayers
title_full_unstemmed Mode II fracture toughening and healing of composites using supramolecular polymer interlayers
title_short Mode II fracture toughening and healing of composites using supramolecular polymer interlayers
title_sort mode ii fracture toughening and healing of composites using supramolecular polymer interlayers
topic Smart polymers
CFRPs
Supramolecular polymers
Fracture toughness
Self-healing
url http://www.expresspolymlett.com/letolt.php?file=EPL-0007395&mi=cd
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AT akotrotsos modeiifracturetougheningandhealingofcompositesusingsupramolecularpolymerinterlayers
AT abaltopoulos modeiifracturetougheningandhealingofcompositesusingsupramolecularpolymerinterlayers
AT stsantzalis modeiifracturetougheningandhealingofcompositesusingsupramolecularpolymerinterlayers
AT ptsokanas modeiifracturetougheningandhealingofcompositesusingsupramolecularpolymerinterlayers
AT tloutas modeiifracturetougheningandhealingofcompositesusingsupramolecularpolymerinterlayers
AT awbosman modeiifracturetougheningandhealingofcompositesusingsupramolecularpolymerinterlayers