The Effect of Oxetane as Active Diluent on Cationic UV Curing System of Fluorine-Containing Epoxy Prepolymer
A series of fluorine-containing polyacrylic epoxy (FPAE) prepolymers with different fluorine content and molecular weight are synthesized by solution free radical polymerization of hexafluorobutyl methacrylate (HFBMA), butyl acrylate (BA), and glycidyl methacrylate (GMA). The synthesized prepolymers...
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| Format: | Article |
| Language: | English |
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Wiley
2020-01-01
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| Series: | Advances in Polymer Technology |
| Online Access: | http://dx.doi.org/10.1155/2020/6120354 |
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| author | Baihong Chi Mengying Wei Yong He |
| author_facet | Baihong Chi Mengying Wei Yong He |
| author_sort | Baihong Chi |
| collection | DOAJ |
| description | A series of fluorine-containing polyacrylic epoxy (FPAE) prepolymers with different fluorine content and molecular weight are synthesized by solution free radical polymerization of hexafluorobutyl methacrylate (HFBMA), butyl acrylate (BA), and glycidyl methacrylate (GMA). The synthesized prepolymers show high conversion and low volume shrinkage. The effect of different types of active diluent for the cationic UV curing of FPAE was investigated, among which oxetane exhibits better comprehensive property than epoxy and vinyl ether. The formulations with the optimal ratio of different functionality oxetane combination show good flexibility, adhesion, hydrophobicity, and antistain property. |
| format | Article |
| id | doaj-art-32b95608f80b4cae9edf676b44e08944 |
| institution | OA Journals |
| issn | 0730-6679 1098-2329 |
| language | English |
| publishDate | 2020-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Advances in Polymer Technology |
| spelling | doaj-art-32b95608f80b4cae9edf676b44e089442025-08-20T02:24:19ZengWileyAdvances in Polymer Technology0730-66791098-23292020-01-01202010.1155/2020/61203546120354The Effect of Oxetane as Active Diluent on Cationic UV Curing System of Fluorine-Containing Epoxy PrepolymerBaihong Chi0Mengying Wei1Yong He2Beijing Institute of Satellite Information Engineering, Beijing 100086, ChinaCollege of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, ChinaCollege of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, ChinaA series of fluorine-containing polyacrylic epoxy (FPAE) prepolymers with different fluorine content and molecular weight are synthesized by solution free radical polymerization of hexafluorobutyl methacrylate (HFBMA), butyl acrylate (BA), and glycidyl methacrylate (GMA). The synthesized prepolymers show high conversion and low volume shrinkage. The effect of different types of active diluent for the cationic UV curing of FPAE was investigated, among which oxetane exhibits better comprehensive property than epoxy and vinyl ether. The formulations with the optimal ratio of different functionality oxetane combination show good flexibility, adhesion, hydrophobicity, and antistain property.http://dx.doi.org/10.1155/2020/6120354 |
| spellingShingle | Baihong Chi Mengying Wei Yong He The Effect of Oxetane as Active Diluent on Cationic UV Curing System of Fluorine-Containing Epoxy Prepolymer Advances in Polymer Technology |
| title | The Effect of Oxetane as Active Diluent on Cationic UV Curing System of Fluorine-Containing Epoxy Prepolymer |
| title_full | The Effect of Oxetane as Active Diluent on Cationic UV Curing System of Fluorine-Containing Epoxy Prepolymer |
| title_fullStr | The Effect of Oxetane as Active Diluent on Cationic UV Curing System of Fluorine-Containing Epoxy Prepolymer |
| title_full_unstemmed | The Effect of Oxetane as Active Diluent on Cationic UV Curing System of Fluorine-Containing Epoxy Prepolymer |
| title_short | The Effect of Oxetane as Active Diluent on Cationic UV Curing System of Fluorine-Containing Epoxy Prepolymer |
| title_sort | effect of oxetane as active diluent on cationic uv curing system of fluorine containing epoxy prepolymer |
| url | http://dx.doi.org/10.1155/2020/6120354 |
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