Indium-catalysed ring opening of 2-hydroxybutyrolactone through the cleavage of C(sp$^3$)–O bond

Indium-catalysed ring opening of 2-hydroxybutyrolactone through the cleavage of C(sp$^3$)–O bond

The ring opening by the cleavage of the C(sp$^3$)–O bond of 2-hydroxybutyrolactone with (ethylthio)trimethylsilane was effectively catalysed by indium triiodide. Screening the reaction conditions allowed optimizing the ring opening. The effect of the nucleophile/catalyst ratio on the reaction effici...

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Bibliographic Details
Main Authors: Aoun, Sameh, Massouh, Joe, Scornet, Noémie, Giordano, Laurent, Tenaglia, Alphonse, Buono, Gérard, Rey, Patrick, Bellière-Baca, Virginie, Hérault, Damien
Format: Article
Language:English
Published: Académie des sciences 2023-09-01
Series:Comptes Rendus. Chimie
Subjects:
Methionine
Lactone
Sulfur nucleophiles
Indium
Thiol
Online Access:https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.245/
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