Nucleophilic conjugate trifluoromethylation of chromones and activated alkenes under the action of Ruppert’s reagent
This review summarizes data on the reactions of chromones and activated alkenes with trimethyl(trifluoromethyl)silane (Ruppert’s reagent), which occures as a nucleophilic 1,4-trifluoromethylation with high regioselectivity and good yields. The most important chemical properties of the formed product...
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| Format: | Article |
| Language: | English |
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Ural Federal University
2017-05-01
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| Series: | Chimica Techno Acta |
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| Online Access: | https://chimicatechnoacta.ru/article/view/2248 |
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| author | V. Ya. Sosnovskikh G.-V. Roshentaler |
| author_facet | V. Ya. Sosnovskikh G.-V. Roshentaler |
| author_sort | V. Ya. Sosnovskikh |
| collection | DOAJ |
| description | This review summarizes data on the reactions of chromones and activated alkenes with trimethyl(trifluoromethyl)silane (Ruppert’s reagent), which occures as a nucleophilic 1,4-trifluoromethylation with high regioselectivity and good yields. The most important chemical properties of the formed products are also considered. |
| format | Article |
| id | doaj-art-326f50cfeabc4debb85cd27fa231d8d2 |
| institution | OA Journals |
| issn | 2411-1414 |
| language | English |
| publishDate | 2017-05-01 |
| publisher | Ural Federal University |
| record_format | Article |
| series | Chimica Techno Acta |
| spelling | doaj-art-326f50cfeabc4debb85cd27fa231d8d22025-08-20T02:07:40ZengUral Federal UniversityChimica Techno Acta2411-14142017-05-0141294410.15826/chimtech.2017.4.1.0222115Nucleophilic conjugate trifluoromethylation of chromones and activated alkenes under the action of Ruppert’s reagentV. Ya. Sosnovskikh0G.-V. Roshentaler1Уральский федеральный университет, ЕкатеринбургУниверситет Якобса, БременThis review summarizes data on the reactions of chromones and activated alkenes with trimethyl(trifluoromethyl)silane (Ruppert’s reagent), which occures as a nucleophilic 1,4-trifluoromethylation with high regioselectivity and good yields. The most important chemical properties of the formed products are also considered.https://chimicatechnoacta.ru/article/view/2248хромоныактивированные алкенынуклеофильное 1,4-трифторметилированиетриметил(трифторметил)силан |
| spellingShingle | V. Ya. Sosnovskikh G.-V. Roshentaler Nucleophilic conjugate trifluoromethylation of chromones and activated alkenes under the action of Ruppert’s reagent Chimica Techno Acta хромоны активированные алкены нуклеофильное 1,4-трифторметилирование триметил(трифторметил)силан |
| title | Nucleophilic conjugate trifluoromethylation of chromones and activated alkenes under the action of Ruppert’s reagent |
| title_full | Nucleophilic conjugate trifluoromethylation of chromones and activated alkenes under the action of Ruppert’s reagent |
| title_fullStr | Nucleophilic conjugate trifluoromethylation of chromones and activated alkenes under the action of Ruppert’s reagent |
| title_full_unstemmed | Nucleophilic conjugate trifluoromethylation of chromones and activated alkenes under the action of Ruppert’s reagent |
| title_short | Nucleophilic conjugate trifluoromethylation of chromones and activated alkenes under the action of Ruppert’s reagent |
| title_sort | nucleophilic conjugate trifluoromethylation of chromones and activated alkenes under the action of ruppert s reagent |
| topic | хромоны активированные алкены нуклеофильное 1,4-трифторметилирование триметил(трифторметил)силан |
| url | https://chimicatechnoacta.ru/article/view/2248 |
| work_keys_str_mv | AT vyasosnovskikh nucleophilicconjugatetrifluoromethylationofchromonesandactivatedalkenesundertheactionofruppertsreagent AT gvroshentaler nucleophilicconjugatetrifluoromethylationofchromonesandactivatedalkenesundertheactionofruppertsreagent |