Constructing Polymetallic Nodes in Metal–Organic Frameworks Enhance Antibacterial of Drug‐Resistant Bacteria

Abstract The misuse of antibiotics results in the emergence of a large number of drug‐resistant bacteria, which leads to huge financial and social burdens. Exploring artificial nanozymes is regarded as a promising candidates for the substitution of antibiotics, but still remain a huge challenge. Her...

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Main Authors: Qinqin Li, Shihan Zhang, Yachao Xu, Yaru Guo, Youxing Liu
Format: Article
Language:English
Published: Wiley 2025-07-01
Series:Advanced Science
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Online Access:https://doi.org/10.1002/advs.202501327
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author Qinqin Li
Shihan Zhang
Yachao Xu
Yaru Guo
Youxing Liu
author_facet Qinqin Li
Shihan Zhang
Yachao Xu
Yaru Guo
Youxing Liu
author_sort Qinqin Li
collection DOAJ
description Abstract The misuse of antibiotics results in the emergence of a large number of drug‐resistant bacteria, which leads to huge financial and social burdens. Exploring artificial nanozymes is regarded as a promising candidates for the substitution of antibiotics, but still remain a huge challenge. Herein, a new strategy is reported for constructing polymetallic indium coordination node Metal‐organic frameworks (MOFs) (polyIn‐BTB) for enhancing the production of reactive oxygen species (ROS), which significantly promote antibacterial activity. Theoretical research reveals that, compared to monometallic indium coordination node MOFs (monoIn‐BTB), polyIn‐BTB exhibits a stronger electron‐donating ability, which can facilitate the efficient production of ROS. Thus, polyIn‐BTB shows outstanding antibacterial properties of 87.0% and 92.0% for Methicillin‐Resistant Staphylococcus aureus (MRS. aureus) and Escherichia coli (E. coli) respectively, which is significantly higher than that of monoIn‐BTB (42% for MRS. Aureus and 50% for E. coli). The in vivo experiments demonstrate that polyIn‐BTB accelerates wound healing by killing bacteria and inhibiting the inflammatory response they cause, with a wound healing rate of 98.0% in 8 days. Overall, this work reports a new strategy for constructing polyIn‐BTB for enhancing the antibacterial performance, which opens the door to fundamental research on designing the nanozyme with high performance.
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language English
publishDate 2025-07-01
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spelling doaj-art-32644f983b6a48deb4d13fdfb224cb412025-08-20T03:30:48ZengWileyAdvanced Science2198-38442025-07-011225n/an/a10.1002/advs.202501327Constructing Polymetallic Nodes in Metal–Organic Frameworks Enhance Antibacterial of Drug‐Resistant BacteriaQinqin Li0Shihan Zhang1Yachao Xu2Yaru Guo3Youxing Liu4Beijing Key Laboratory of Electrochemical Process and Technology for Materials Beijing University of Chemical Technology Beijing 100029 ChinaDepartment of Geriatric Dentistry Peking University School and Hospital of Stomatology Beijing 100081 ChinaSchool of Materials Science and Engineering Peking University Beijing 100871 ChinaDepartment of Geriatric Dentistry Peking University School and Hospital of Stomatology Beijing 100081 ChinaBeijing Key Laboratory of Electrochemical Process and Technology for Materials Beijing University of Chemical Technology Beijing 100029 ChinaAbstract The misuse of antibiotics results in the emergence of a large number of drug‐resistant bacteria, which leads to huge financial and social burdens. Exploring artificial nanozymes is regarded as a promising candidates for the substitution of antibiotics, but still remain a huge challenge. Herein, a new strategy is reported for constructing polymetallic indium coordination node Metal‐organic frameworks (MOFs) (polyIn‐BTB) for enhancing the production of reactive oxygen species (ROS), which significantly promote antibacterial activity. Theoretical research reveals that, compared to monometallic indium coordination node MOFs (monoIn‐BTB), polyIn‐BTB exhibits a stronger electron‐donating ability, which can facilitate the efficient production of ROS. Thus, polyIn‐BTB shows outstanding antibacterial properties of 87.0% and 92.0% for Methicillin‐Resistant Staphylococcus aureus (MRS. aureus) and Escherichia coli (E. coli) respectively, which is significantly higher than that of monoIn‐BTB (42% for MRS. Aureus and 50% for E. coli). The in vivo experiments demonstrate that polyIn‐BTB accelerates wound healing by killing bacteria and inhibiting the inflammatory response they cause, with a wound healing rate of 98.0% in 8 days. Overall, this work reports a new strategy for constructing polyIn‐BTB for enhancing the antibacterial performance, which opens the door to fundamental research on designing the nanozyme with high performance.https://doi.org/10.1002/advs.202501327antibacterialantibacterial therapymetal–organic framework materialspolymetallic coordination nodereactive oxygen species
spellingShingle Qinqin Li
Shihan Zhang
Yachao Xu
Yaru Guo
Youxing Liu
Constructing Polymetallic Nodes in Metal–Organic Frameworks Enhance Antibacterial of Drug‐Resistant Bacteria
Advanced Science
antibacterial
antibacterial therapy
metal–organic framework materials
polymetallic coordination node
reactive oxygen species
title Constructing Polymetallic Nodes in Metal–Organic Frameworks Enhance Antibacterial of Drug‐Resistant Bacteria
title_full Constructing Polymetallic Nodes in Metal–Organic Frameworks Enhance Antibacterial of Drug‐Resistant Bacteria
title_fullStr Constructing Polymetallic Nodes in Metal–Organic Frameworks Enhance Antibacterial of Drug‐Resistant Bacteria
title_full_unstemmed Constructing Polymetallic Nodes in Metal–Organic Frameworks Enhance Antibacterial of Drug‐Resistant Bacteria
title_short Constructing Polymetallic Nodes in Metal–Organic Frameworks Enhance Antibacterial of Drug‐Resistant Bacteria
title_sort constructing polymetallic nodes in metal organic frameworks enhance antibacterial of drug resistant bacteria
topic antibacterial
antibacterial therapy
metal–organic framework materials
polymetallic coordination node
reactive oxygen species
url https://doi.org/10.1002/advs.202501327
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