Study on Oil Displacement Mechanism of Betaine/Polymer Binary Flooding in High-Temperature and High-Salinity Reservoirs

As an efficient and economical method to enhance oil recovery (EOR), it is very important to explore the applicability of chemical flooding under harsh reservoir conditions, such as high temperature and high salinity. We designed microscopic visualization oil displacement experiments to comprehensiv...

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Main Authors: Xiuyu Zhu, Qun Zhang, Changkun Cheng, Lu Han, Hai Lin, Fan Zhang, Jian Fan, Lei Zhang, Zhaohui Zhou, Lu Zhang
Format: Article
Language:English
Published: MDPI AG 2025-03-01
Series:Molecules
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Online Access:https://www.mdpi.com/1420-3049/30/5/1145
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_version_ 1850053256613462016
author Xiuyu Zhu
Qun Zhang
Changkun Cheng
Lu Han
Hai Lin
Fan Zhang
Jian Fan
Lei Zhang
Zhaohui Zhou
Lu Zhang
author_facet Xiuyu Zhu
Qun Zhang
Changkun Cheng
Lu Han
Hai Lin
Fan Zhang
Jian Fan
Lei Zhang
Zhaohui Zhou
Lu Zhang
author_sort Xiuyu Zhu
collection DOAJ
description As an efficient and economical method to enhance oil recovery (EOR), it is very important to explore the applicability of chemical flooding under harsh reservoir conditions, such as high temperature and high salinity. We designed microscopic visualization oil displacement experiments to comprehensively evaluate the oil displacement performance of the zwitterionic surfactant betaine (BSB), a temperature- and salinity-resistant hydrophobically modified polymer (BHR), and surfactant–polymer (SP) binary systems. Based on macroscopic properties and microscopic oil displacement effects, we confirmed that the BSB/BHR binary solution has the potential to synergistically improve oil displacement efficiency and quantified the reduction in residual oil and oil displacement efficiency within the swept range. The experimental results show that after water flooding, a large amount of residual oil remains in the porous media in the form of clusters, porous structures, and columnar formations. After water flooding, only slight emulsification occurred after the injection of BSB solution, and the residual oil could not be activated. The injection of polymer after water flooding can expand the swept range to a certain extent. However, the distribution of residual oil in the swept range is similar to that of water flooding, and the oil washing efficiency is low. The SP binary flooding process can expand sweep coverage and effectively decompose large oil clusters simultaneously. This enhances the oil washing efficiency within the swept area and can significantly improve oil recovery. Finally, we obtained the microscopic oil displacement mechanism of BSB/BHR binary system to synergistically increase the swept volume and effectively activate the residual oil after water flooding. It is the result of the combined action of low interfacial tension (IFT) and suitable bulk viscosity. These findings provide critical insights for optimizing chemical flooding strategies in high-temperature and high-salinity reservoirs, significantly advancing EOR applications in harsh environments.
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spelling doaj-art-322c0634a80c4cabaff341cd8cc5532e2025-08-20T02:52:35ZengMDPI AGMolecules1420-30492025-03-01305114510.3390/molecules30051145Study on Oil Displacement Mechanism of Betaine/Polymer Binary Flooding in High-Temperature and High-Salinity ReservoirsXiuyu Zhu0Qun Zhang1Changkun Cheng2Lu Han3Hai Lin4Fan Zhang5Jian Fan6Lei Zhang7Zhaohui Zhou8Lu Zhang9Oil & Gas Technology Research Institute, PetroChina Qinghai Oilfield Company, Dunhuang 736202, ChinaState Key Laboratory of Enhanced Oil & Gas Recovery, PetroChina Research Institute of Petroleum Exploration & Development, Beijing 100083, ChinaOil & Gas Technology Research Institute, PetroChina Qinghai Oilfield Company, Dunhuang 736202, ChinaState Key Laboratory of Enhanced Oil & Gas Recovery, PetroChina Research Institute of Petroleum Exploration & Development, Beijing 100083, ChinaOil & Gas Technology Research Institute, PetroChina Qinghai Oilfield Company, Dunhuang 736202, ChinaState Key Laboratory of Enhanced Oil & Gas Recovery, PetroChina Research Institute of Petroleum Exploration & Development, Beijing 100083, ChinaState Key Laboratory of Enhanced Oil & Gas Recovery, PetroChina Research Institute of Petroleum Exploration & Development, Beijing 100083, ChinaKey Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, ChinaState Key Laboratory of Enhanced Oil & Gas Recovery, PetroChina Research Institute of Petroleum Exploration & Development, Beijing 100083, ChinaKey Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, ChinaAs an efficient and economical method to enhance oil recovery (EOR), it is very important to explore the applicability of chemical flooding under harsh reservoir conditions, such as high temperature and high salinity. We designed microscopic visualization oil displacement experiments to comprehensively evaluate the oil displacement performance of the zwitterionic surfactant betaine (BSB), a temperature- and salinity-resistant hydrophobically modified polymer (BHR), and surfactant–polymer (SP) binary systems. Based on macroscopic properties and microscopic oil displacement effects, we confirmed that the BSB/BHR binary solution has the potential to synergistically improve oil displacement efficiency and quantified the reduction in residual oil and oil displacement efficiency within the swept range. The experimental results show that after water flooding, a large amount of residual oil remains in the porous media in the form of clusters, porous structures, and columnar formations. After water flooding, only slight emulsification occurred after the injection of BSB solution, and the residual oil could not be activated. The injection of polymer after water flooding can expand the swept range to a certain extent. However, the distribution of residual oil in the swept range is similar to that of water flooding, and the oil washing efficiency is low. The SP binary flooding process can expand sweep coverage and effectively decompose large oil clusters simultaneously. This enhances the oil washing efficiency within the swept area and can significantly improve oil recovery. Finally, we obtained the microscopic oil displacement mechanism of BSB/BHR binary system to synergistically increase the swept volume and effectively activate the residual oil after water flooding. It is the result of the combined action of low interfacial tension (IFT) and suitable bulk viscosity. These findings provide critical insights for optimizing chemical flooding strategies in high-temperature and high-salinity reservoirs, significantly advancing EOR applications in harsh environments.https://www.mdpi.com/1420-3049/30/5/1145betainepolymerbulk viscositybinary floodingoil displacement mechanism
spellingShingle Xiuyu Zhu
Qun Zhang
Changkun Cheng
Lu Han
Hai Lin
Fan Zhang
Jian Fan
Lei Zhang
Zhaohui Zhou
Lu Zhang
Study on Oil Displacement Mechanism of Betaine/Polymer Binary Flooding in High-Temperature and High-Salinity Reservoirs
Molecules
betaine
polymer
bulk viscosity
binary flooding
oil displacement mechanism
title Study on Oil Displacement Mechanism of Betaine/Polymer Binary Flooding in High-Temperature and High-Salinity Reservoirs
title_full Study on Oil Displacement Mechanism of Betaine/Polymer Binary Flooding in High-Temperature and High-Salinity Reservoirs
title_fullStr Study on Oil Displacement Mechanism of Betaine/Polymer Binary Flooding in High-Temperature and High-Salinity Reservoirs
title_full_unstemmed Study on Oil Displacement Mechanism of Betaine/Polymer Binary Flooding in High-Temperature and High-Salinity Reservoirs
title_short Study on Oil Displacement Mechanism of Betaine/Polymer Binary Flooding in High-Temperature and High-Salinity Reservoirs
title_sort study on oil displacement mechanism of betaine polymer binary flooding in high temperature and high salinity reservoirs
topic betaine
polymer
bulk viscosity
binary flooding
oil displacement mechanism
url https://www.mdpi.com/1420-3049/30/5/1145
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