Synthesis and Characterization of 1,2,3- Triazole Derivatives from D-Mannitol

This research included the use of azido D-Mannitol (3) to synthesize 1,2,3 triazole derivatives. Azido D – Mannitol  (3) itself used as an intermediate which was prepared from reaction of  1, 2:5, 6-Di-o-isopropylidene-3,4-di-p-tosyl-D-Mannitol (2) with sodium azide. The prepared compound (3) was a...

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Main Author: Ihmood Kh. Juber
Format: Article
Language:English
Published: Tikrit University 2023-02-01
Series:Tikrit Journal of Pure Science
Subjects:
Online Access:https://tjpsj.org/index.php/tjps/article/view/876
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author Ihmood Kh. Juber
author_facet Ihmood Kh. Juber
author_sort Ihmood Kh. Juber
collection DOAJ
description This research included the use of azido D-Mannitol (3) to synthesize 1,2,3 triazole derivatives. Azido D – Mannitol  (3) itself used as an intermediate which was prepared from reaction of  1, 2:5, 6-Di-o-isopropylidene-3,4-di-p-tosyl-D-Mannitol (2) with sodium azide. The prepared compound (3) was allowed to react with alkenes for the formation of corresponding 1,2,3 triazole (4a-e ). The structures of some prepared compounds were confirmed by physical properties and  spectroscopic methods FT-IR , 1H-NMR , 13C-NMR and Mass spectra in addition to use TLC.
format Article
id doaj-art-30fa6db400ed4b5291eea338190e3974
institution OA Journals
issn 1813-1662
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language English
publishDate 2023-02-01
publisher Tikrit University
record_format Article
series Tikrit Journal of Pure Science
spelling doaj-art-30fa6db400ed4b5291eea338190e39742025-08-20T02:36:31ZengTikrit UniversityTikrit Journal of Pure Science1813-16622415-17262023-02-0122910.25130/tjps.v22i9.876Synthesis and Characterization of 1,2,3- Triazole Derivatives from D-MannitolIhmood Kh. Juber This research included the use of azido D-Mannitol (3) to synthesize 1,2,3 triazole derivatives. Azido D – Mannitol  (3) itself used as an intermediate which was prepared from reaction of  1, 2:5, 6-Di-o-isopropylidene-3,4-di-p-tosyl-D-Mannitol (2) with sodium azide. The prepared compound (3) was allowed to react with alkenes for the formation of corresponding 1,2,3 triazole (4a-e ). The structures of some prepared compounds were confirmed by physical properties and  spectroscopic methods FT-IR , 1H-NMR , 13C-NMR and Mass spectra in addition to use TLC. https://tjpsj.org/index.php/tjps/article/view/876D-Mannitol1,2,3-triazoleazideisopropylidene
spellingShingle Ihmood Kh. Juber
Synthesis and Characterization of 1,2,3- Triazole Derivatives from D-Mannitol
Tikrit Journal of Pure Science
D-Mannitol
1,2,3-triazole
azide
isopropylidene
title Synthesis and Characterization of 1,2,3- Triazole Derivatives from D-Mannitol
title_full Synthesis and Characterization of 1,2,3- Triazole Derivatives from D-Mannitol
title_fullStr Synthesis and Characterization of 1,2,3- Triazole Derivatives from D-Mannitol
title_full_unstemmed Synthesis and Characterization of 1,2,3- Triazole Derivatives from D-Mannitol
title_short Synthesis and Characterization of 1,2,3- Triazole Derivatives from D-Mannitol
title_sort synthesis and characterization of 1 2 3 triazole derivatives from d mannitol
topic D-Mannitol
1,2,3-triazole
azide
isopropylidene
url https://tjpsj.org/index.php/tjps/article/view/876
work_keys_str_mv AT ihmoodkhjuber synthesisandcharacterizationof123triazolederivativesfromdmannitol