Ultrasonic Investigations of Molecular Interaction in Binary Mixtures of Benzyl Benzoate with Acetonitrile and Benzonitrile
Ultrasonic velocity, density and viscosity have been measured in the binary mixtures of benzyl benzoate with acetonitrile, benzonitrile at three temperatures 30, 40 and 50 °C. From the experimental data, thermodynamic parameters like adiabatic compressibility, internal pressure, enthalpy, activation...
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| Format: | Article |
| Language: | English |
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Wiley
2011-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2011/464098 |
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| author | N. Jaya Madhuri P. S. Naidu J. Glory K. Ravindra Prasad |
| author_facet | N. Jaya Madhuri P. S. Naidu J. Glory K. Ravindra Prasad |
| author_sort | N. Jaya Madhuri |
| collection | DOAJ |
| description | Ultrasonic velocity, density and viscosity have been measured in the binary mixtures of benzyl benzoate with acetonitrile, benzonitrile at three temperatures 30, 40 and 50 °C. From the experimental data, thermodynamic parameters like adiabatic compressibility, internal pressure, enthalpy, activation energy etc., were computed and the molecular interactions were predicted based on the variation of excess parameters in the mixture. Also theoretical evaluation of velocities was made employing the standard theories. CFT and NOMOTO were found to have an edge. All the three mixtures have shown out strong intermolecular interactions between the unlike molecules and endothermic type of chemical reaction. |
| format | Article |
| id | doaj-art-30efd7a0bd0e4e7a8f54371423576b55 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2011-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-30efd7a0bd0e4e7a8f54371423576b552025-02-03T07:24:47ZengWileyE-Journal of Chemistry0973-49452090-98102011-01-018145746910.1155/2011/464098Ultrasonic Investigations of Molecular Interaction in Binary Mixtures of Benzyl Benzoate with Acetonitrile and BenzonitrileN. Jaya Madhuri0P. S. Naidu1J. Glory2K. Ravindra Prasad3Department of Physics, S.V.U.P.G.Centre, Kavali-524 201, IndiaDepartment of Physics, S.V.U.P.G.Centre, Kavali-524 201, IndiaDepartment of Physics, S.V.U.P.G.Centre, Kavali-524 201, IndiaDepartment of Physics, S.V.U.P.G.Centre, Kavali-524 201, IndiaUltrasonic velocity, density and viscosity have been measured in the binary mixtures of benzyl benzoate with acetonitrile, benzonitrile at three temperatures 30, 40 and 50 °C. From the experimental data, thermodynamic parameters like adiabatic compressibility, internal pressure, enthalpy, activation energy etc., were computed and the molecular interactions were predicted based on the variation of excess parameters in the mixture. Also theoretical evaluation of velocities was made employing the standard theories. CFT and NOMOTO were found to have an edge. All the three mixtures have shown out strong intermolecular interactions between the unlike molecules and endothermic type of chemical reaction.http://dx.doi.org/10.1155/2011/464098 |
| spellingShingle | N. Jaya Madhuri P. S. Naidu J. Glory K. Ravindra Prasad Ultrasonic Investigations of Molecular Interaction in Binary Mixtures of Benzyl Benzoate with Acetonitrile and Benzonitrile E-Journal of Chemistry |
| title | Ultrasonic Investigations of Molecular Interaction in Binary Mixtures of Benzyl Benzoate with Acetonitrile and Benzonitrile |
| title_full | Ultrasonic Investigations of Molecular Interaction in Binary Mixtures of Benzyl Benzoate with Acetonitrile and Benzonitrile |
| title_fullStr | Ultrasonic Investigations of Molecular Interaction in Binary Mixtures of Benzyl Benzoate with Acetonitrile and Benzonitrile |
| title_full_unstemmed | Ultrasonic Investigations of Molecular Interaction in Binary Mixtures of Benzyl Benzoate with Acetonitrile and Benzonitrile |
| title_short | Ultrasonic Investigations of Molecular Interaction in Binary Mixtures of Benzyl Benzoate with Acetonitrile and Benzonitrile |
| title_sort | ultrasonic investigations of molecular interaction in binary mixtures of benzyl benzoate with acetonitrile and benzonitrile |
| url | http://dx.doi.org/10.1155/2011/464098 |
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