Detoxification of Ochratoxin A in Rice and Maize using ethanolic leaf extracts of  Moringa oleifera and Vernonia amygdalina

The non-availability of research data in North-central Nigeria coupled with the toxic and prevalent nature of ochratoxin A makes it necessary to quantity and identify possible remediative techniques that are effective, less toxic, locally available, cost friendly and easy to deploy. This research w...

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Main Authors: OLUWAGBENGA ANIFOWOSE, Bitrus W Tukura, Obaje D Opaluwa
Format: Article
Language:English
Published: Nigerian Society of Physical Sciences 2025-08-01
Series:African Scientific Reports
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Online Access:https://asr.nsps.org.ng/index.php/asr/article/view/294
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author OLUWAGBENGA ANIFOWOSE
Bitrus W Tukura
Obaje D Opaluwa
author_facet OLUWAGBENGA ANIFOWOSE
Bitrus W Tukura
Obaje D Opaluwa
author_sort OLUWAGBENGA ANIFOWOSE
collection DOAJ
description The non-availability of research data in North-central Nigeria coupled with the toxic and prevalent nature of ochratoxin A makes it necessary to quantity and identify possible remediative techniques that are effective, less toxic, locally available, cost friendly and easy to deploy. This research was aimed at evaluating the potency of phytochemical remediation on ochratoxin A (OTA) in stored rice and maize using ethanolic leaf extracts of Moringa oleifera and Vernonia amygdalina. High Performance Liquid Chromatography coupled with Ultraviolet/Visible detector (HPLC-UV/Vis spectroscopy) was employed in the determination of the detoxification levels of the OTA in the samples. Phytochemical constituents in the plant extracts were quantified using standard methods. Phytochemical concentrations ranged from 27.83 ± 1.53 – 184.73 ± 0.06 mg/g and 23.00 ± 1.00 – 171.67 ± 3.06 mg/g in the leaf extracts of Moringa oleifera and Vernonia amygdalina respectively. The levels of phytochemicals in Moringa oleifera extract were statistically (p ≤ 0.05) higher than in Vernonia amygdalina extract. OTA was present in all the samples with residual concentrations of 32.93 ± 2.02 and 39.23 ± 5.68 µg/kg in the stored rice and maize samples respectively. Detoxification using 1 – 5 mg/cm3 of Vernonia amygdalina leaf extract ranged from 34.80 (21.47 ± 1.76 µg/kg) to 56.67 % (14.27 ± 1.09 µg/kg) in rice and 38.87 (23.98 ± 0.95 µg/kg) to 58.45 % (16.30 ± 3.18 µg/kg) in maize while, detoxification using 1 – 5 mg/cm3 of Moringa oleifera leaf extract were ranged from 57.18 (14.10 ± 0.85 µg/kg) to 72.12 % (9.18 ± 0.30 µg/kg) in rice and 53.28 (18.33 ± 0.58 µg/kg) to 70.89 % (11.42 ± 1.52 µg/kg) in maize respectively. Detoxification efficiency of ethanolic leaf extracts of Vernonia amygdalina and Moringa oleifera on OTA increased with increasing concentrations of the extracts. Phytochemical detoxification of OTA in the stored rice and maize samples were observed to be efficient and promising with a detoxification order Moringa oleifera > Vernonia amygdalina.
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spelling doaj-art-304cc973800147a596c55ed05f5efdce2025-08-24T00:01:04ZengNigerian Society of Physical SciencesAfrican Scientific Reports2955-16252955-16172025-08-014210.46481/asr.2025.4.2.294Detoxification of Ochratoxin A in Rice and Maize using ethanolic leaf extracts of  Moringa oleifera and Vernonia amygdalinaOLUWAGBENGA ANIFOWOSEBitrus W TukuraObaje D Opaluwa The non-availability of research data in North-central Nigeria coupled with the toxic and prevalent nature of ochratoxin A makes it necessary to quantity and identify possible remediative techniques that are effective, less toxic, locally available, cost friendly and easy to deploy. This research was aimed at evaluating the potency of phytochemical remediation on ochratoxin A (OTA) in stored rice and maize using ethanolic leaf extracts of Moringa oleifera and Vernonia amygdalina. High Performance Liquid Chromatography coupled with Ultraviolet/Visible detector (HPLC-UV/Vis spectroscopy) was employed in the determination of the detoxification levels of the OTA in the samples. Phytochemical constituents in the plant extracts were quantified using standard methods. Phytochemical concentrations ranged from 27.83 ± 1.53 – 184.73 ± 0.06 mg/g and 23.00 ± 1.00 – 171.67 ± 3.06 mg/g in the leaf extracts of Moringa oleifera and Vernonia amygdalina respectively. The levels of phytochemicals in Moringa oleifera extract were statistically (p ≤ 0.05) higher than in Vernonia amygdalina extract. OTA was present in all the samples with residual concentrations of 32.93 ± 2.02 and 39.23 ± 5.68 µg/kg in the stored rice and maize samples respectively. Detoxification using 1 – 5 mg/cm3 of Vernonia amygdalina leaf extract ranged from 34.80 (21.47 ± 1.76 µg/kg) to 56.67 % (14.27 ± 1.09 µg/kg) in rice and 38.87 (23.98 ± 0.95 µg/kg) to 58.45 % (16.30 ± 3.18 µg/kg) in maize while, detoxification using 1 – 5 mg/cm3 of Moringa oleifera leaf extract were ranged from 57.18 (14.10 ± 0.85 µg/kg) to 72.12 % (9.18 ± 0.30 µg/kg) in rice and 53.28 (18.33 ± 0.58 µg/kg) to 70.89 % (11.42 ± 1.52 µg/kg) in maize respectively. Detoxification efficiency of ethanolic leaf extracts of Vernonia amygdalina and Moringa oleifera on OTA increased with increasing concentrations of the extracts. Phytochemical detoxification of OTA in the stored rice and maize samples were observed to be efficient and promising with a detoxification order Moringa oleifera > Vernonia amygdalina. https://asr.nsps.org.ng/index.php/asr/article/view/294MycotoxinsOchratoxin ADetoxificationPhytochemicals
spellingShingle OLUWAGBENGA ANIFOWOSE
Bitrus W Tukura
Obaje D Opaluwa
Detoxification of Ochratoxin A in Rice and Maize using ethanolic leaf extracts of  Moringa oleifera and Vernonia amygdalina
African Scientific Reports
Mycotoxins
Ochratoxin A
Detoxification
Phytochemicals
title Detoxification of Ochratoxin A in Rice and Maize using ethanolic leaf extracts of  Moringa oleifera and Vernonia amygdalina
title_full Detoxification of Ochratoxin A in Rice and Maize using ethanolic leaf extracts of  Moringa oleifera and Vernonia amygdalina
title_fullStr Detoxification of Ochratoxin A in Rice and Maize using ethanolic leaf extracts of  Moringa oleifera and Vernonia amygdalina
title_full_unstemmed Detoxification of Ochratoxin A in Rice and Maize using ethanolic leaf extracts of  Moringa oleifera and Vernonia amygdalina
title_short Detoxification of Ochratoxin A in Rice and Maize using ethanolic leaf extracts of  Moringa oleifera and Vernonia amygdalina
title_sort detoxification of ochratoxin a in rice and maize using ethanolic leaf extracts of moringa oleifera and vernonia amygdalina
topic Mycotoxins
Ochratoxin A
Detoxification
Phytochemicals
url https://asr.nsps.org.ng/index.php/asr/article/view/294
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AT obajedopaluwa detoxificationofochratoxinainriceandmaizeusingethanolicleafextractsofmoringaoleiferaandvernoniaamygdalina