Transformation of 3D Metal–Organic Frameworks into Nanosheets with Enhanced Memristive Behavior for Electronic Data Processing
Abstract The transition from three‐dimensional (3D) to two‐dimensional (2D) semiconducting and insulating materials for micro‐ and opto‐electronics is driven by an energy efficiency and device miniaturization. Herein, the simplicity of growth and stacking of 2D metal–organic framework (MOF) with suc...
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| Format: | Article |
| Language: | English |
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Wiley
2025-04-01
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| Series: | Advanced Science |
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| Online Access: | https://doi.org/10.1002/advs.202405989 |
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| author | Yuri A. Mezenov Semyon V. Bachinin Yuliya A. Kenzhebayeva Anastasiia S. Efimova Pavel V. Alekseevskiy Daria Poloneeva Anastasia Lubimova Svyatoslav A. Povarov Vladimir Shirobokov Mikhail S. Dunaevskiy Aleksandra S. Falchevskaya Andrei S. Potapov Alexander Novikov Artem A. Selyutin Pascal Boulet Alena N. Kulakova Valentin A. Milichko |
| author_facet | Yuri A. Mezenov Semyon V. Bachinin Yuliya A. Kenzhebayeva Anastasiia S. Efimova Pavel V. Alekseevskiy Daria Poloneeva Anastasia Lubimova Svyatoslav A. Povarov Vladimir Shirobokov Mikhail S. Dunaevskiy Aleksandra S. Falchevskaya Andrei S. Potapov Alexander Novikov Artem A. Selyutin Pascal Boulet Alena N. Kulakova Valentin A. Milichko |
| author_sort | Yuri A. Mezenov |
| collection | DOAJ |
| description | Abstract The transition from three‐dimensional (3D) to two‐dimensional (2D) semiconducting and insulating materials for micro‐ and opto‐electronics is driven by an energy efficiency and device miniaturization. Herein, the simplicity of growth and stacking of 2D metal–organic framework (MOF) with such planar devices opens up new perspectives in controlling their efficiency and operating parameters. Here, the study reports on 3D to 2D MOF’ structural transformation to achieve ultrathin nanosheets with enhanced insulating properties. Based on neutral N‐donor ligands, the study designs and solvothermally synthesizes 3D MOFs followed by their thermal and solvent treatment to implement the transformation. A set of single crystal and powder X‐ray diffraction, electron microscopy, Raman spectroscopy, numerical modeling, and mechanical exfoliation confirm the nature of the transformation. Compared with initial 3D MOF, its nanosheets demonstrate sufficient changes in electronic properties, expressed as tuning their absorption, photoluminescence, and resistivity. The latter allows to demonstrate the prototype of ultrathin memristive element based on a 4 to 32 nm MOF nanosheet with enhanced functionality (150 to 1400 ON/OFF ratio, retention time exceeding 7300 s, and 100 cycles of switching), thereby, extending the list of scalable and insulating 2D MOFs for micro‐ and opto‐electronics. |
| format | Article |
| id | doaj-art-303bb83207f745a69f6ba9eeedea6672 |
| institution | OA Journals |
| issn | 2198-3844 |
| language | English |
| publishDate | 2025-04-01 |
| publisher | Wiley |
| record_format | Article |
| series | Advanced Science |
| spelling | doaj-art-303bb83207f745a69f6ba9eeedea66722025-08-20T02:18:32ZengWileyAdvanced Science2198-38442025-04-011216n/an/a10.1002/advs.202405989Transformation of 3D Metal–Organic Frameworks into Nanosheets with Enhanced Memristive Behavior for Electronic Data ProcessingYuri A. Mezenov0Semyon V. Bachinin1Yuliya A. Kenzhebayeva2Anastasiia S. Efimova3Pavel V. Alekseevskiy4Daria Poloneeva5Anastasia Lubimova6Svyatoslav A. Povarov7Vladimir Shirobokov8Mikhail S. Dunaevskiy9Aleksandra S. Falchevskaya10Andrei S. Potapov11Alexander Novikov12Artem A. Selyutin13Pascal Boulet14Alena N. Kulakova15Valentin A. Milichko16Qingdao Innovation and Development Center Harbin Engineering University Qingdao Shandong 266000 ChinaSchool of Physics and Engineering ITMO University St. Petersburg 197101 RussiaSchool of Physics and Engineering ITMO University St. Petersburg 197101 RussiaSchool of Physics and Engineering ITMO University St. Petersburg 197101 RussiaSchool of Physics and Engineering ITMO University St. Petersburg 197101 RussiaAdvanced Catalytic Materials (ACM) KAUST Catalysis Center (KCC) Division of Physical Sciences and Engineering King Abdullah University of Science and Technology Thuwal 23955 Saudi ArabiaSchool of Physics and Engineering ITMO University St. Petersburg 197101 RussiaSchool of Physics and Engineering ITMO University St. Petersburg 197101 RussiaSchool of Physics and Engineering ITMO University St. Petersburg 197101 RussiaSchool of Physics and Engineering ITMO University St. Petersburg 197101 RussiaITMO University “Solution Chemistry of Advanced Materials and Technologies” (SCAMT) International Institute Saint Petersburg 191002 RussiaNikolaev Institute of Inorganic Chemistry Siberian Branch of the Russian Academy of Sciences Laboratory of Metal‐Organic Coordination Polymers Novosibirsk 630090 RussiaSaint Petersburg State University Saint Petersburg 199034 RussiaSaint Petersburg State University Saint Petersburg 199034 RussiaInstitut Jean Lamour Universit de Lorraine UMR CNRS 7198 Nancy 54011 FranceSchool of Physics and Engineering ITMO University St. Petersburg 197101 RussiaSchool of Physics and Engineering ITMO University St. Petersburg 197101 RussiaAbstract The transition from three‐dimensional (3D) to two‐dimensional (2D) semiconducting and insulating materials for micro‐ and opto‐electronics is driven by an energy efficiency and device miniaturization. Herein, the simplicity of growth and stacking of 2D metal–organic framework (MOF) with such planar devices opens up new perspectives in controlling their efficiency and operating parameters. Here, the study reports on 3D to 2D MOF’ structural transformation to achieve ultrathin nanosheets with enhanced insulating properties. Based on neutral N‐donor ligands, the study designs and solvothermally synthesizes 3D MOFs followed by their thermal and solvent treatment to implement the transformation. A set of single crystal and powder X‐ray diffraction, electron microscopy, Raman spectroscopy, numerical modeling, and mechanical exfoliation confirm the nature of the transformation. Compared with initial 3D MOF, its nanosheets demonstrate sufficient changes in electronic properties, expressed as tuning their absorption, photoluminescence, and resistivity. The latter allows to demonstrate the prototype of ultrathin memristive element based on a 4 to 32 nm MOF nanosheet with enhanced functionality (150 to 1400 ON/OFF ratio, retention time exceeding 7300 s, and 100 cycles of switching), thereby, extending the list of scalable and insulating 2D MOFs for micro‐ and opto‐electronics.https://doi.org/10.1002/advs.202405989memristive behaviormetal–organic frameworksnanosheetsstructural transformation |
| spellingShingle | Yuri A. Mezenov Semyon V. Bachinin Yuliya A. Kenzhebayeva Anastasiia S. Efimova Pavel V. Alekseevskiy Daria Poloneeva Anastasia Lubimova Svyatoslav A. Povarov Vladimir Shirobokov Mikhail S. Dunaevskiy Aleksandra S. Falchevskaya Andrei S. Potapov Alexander Novikov Artem A. Selyutin Pascal Boulet Alena N. Kulakova Valentin A. Milichko Transformation of 3D Metal–Organic Frameworks into Nanosheets with Enhanced Memristive Behavior for Electronic Data Processing Advanced Science memristive behavior metal–organic frameworks nanosheets structural transformation |
| title | Transformation of 3D Metal–Organic Frameworks into Nanosheets with Enhanced Memristive Behavior for Electronic Data Processing |
| title_full | Transformation of 3D Metal–Organic Frameworks into Nanosheets with Enhanced Memristive Behavior for Electronic Data Processing |
| title_fullStr | Transformation of 3D Metal–Organic Frameworks into Nanosheets with Enhanced Memristive Behavior for Electronic Data Processing |
| title_full_unstemmed | Transformation of 3D Metal–Organic Frameworks into Nanosheets with Enhanced Memristive Behavior for Electronic Data Processing |
| title_short | Transformation of 3D Metal–Organic Frameworks into Nanosheets with Enhanced Memristive Behavior for Electronic Data Processing |
| title_sort | transformation of 3d metal organic frameworks into nanosheets with enhanced memristive behavior for electronic data processing |
| topic | memristive behavior metal–organic frameworks nanosheets structural transformation |
| url | https://doi.org/10.1002/advs.202405989 |
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