Structural, Mechanical and Optical Properties of Plasma-chemical Si-C-N Films

An influence of the substrate temperature in the range of 40-400 °C on the properties of the Si-C-N films deposited by plasma enhanced chemical vapor deposition (PECVD) technique using hexamethyldisilazane is analyzed. Study of the structure, chemical bonding, surface morphology, mechanical properti...

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Main Authors: A.O. Kozak, V.I. Ivashchenko, O.K. Porada, L.A. Ivashchenko, T.V. Tomila
Format: Article
Language:English
Published: Sumy State University 2014-11-01
Series:Журнал нано- та електронної фізики
Subjects:
Online Access:http://jnep.sumdu.edu.ua/download/numbers/2014/4/articles/jnep_2014_V6_04047.pdf
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author A.O. Kozak
V.I. Ivashchenko
O.K. Porada
L.A. Ivashchenko
T.V. Tomila
author_facet A.O. Kozak
V.I. Ivashchenko
O.K. Porada
L.A. Ivashchenko
T.V. Tomila
author_sort A.O. Kozak
collection DOAJ
description An influence of the substrate temperature in the range of 40-400 °C on the properties of the Si-C-N films deposited by plasma enhanced chemical vapor deposition (PECVD) technique using hexamethyldisilazane is analyzed. Study of the structure, chemical bonding, surface morphology, mechanical properties and energy gap of the obtained films was carried out using X-ray diffraction, infrared spectroscopy, X-ray photoelectron spectroscopy, atomic force microscopy, optical measurements and nanoindentation. It was established that all the films were X-ray amorphous and had low surface roughness. Intensive hydrogen effusion from the films takes place, when substrate temperature increases up to 400 °C, which promotes a decrease of roughness and an increase in hardness and Young modules more than twice.
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publisher Sumy State University
record_format Article
series Журнал нано- та електронної фізики
spelling doaj-art-2f97cd15f4f74c889a10e3fe4deda4eb2025-08-20T02:01:47ZengSumy State UniversityЖурнал нано- та електронної фізики2077-67722014-11-016404047-104047-5Structural, Mechanical and Optical Properties of Plasma-chemical Si-C-N FilmsA.O. Kozak0V.I. Ivashchenko1O.K. Porada2L.A. Ivashchenko3T.V. Tomila4Institute for Problems of Materials Sciences, NAS of Ukraine, 3, Krzhyzhanovsky Str., 03142 Kyiv, UkraineInstitute for Problems of Materials Sciences, NAS of Ukraine, 3, Krzhyzhanovsky Str., 03142 Kyiv, UkraineInstitute for Problems of Materials Sciences, NAS of Ukraine, 3, Krzhyzhanovsky Str., 03142 Kyiv, UkraineInstitute for Problems of Materials Sciences, NAS of Ukraine, 3, Krzhyzhanovsky Str., 03142 Kyiv, UkraineInstitute for Problems of Materials Sciences, NAS of Ukraine, 3, Krzhyzhanovsky Str., 03142 Kyiv, UkraineAn influence of the substrate temperature in the range of 40-400 °C on the properties of the Si-C-N films deposited by plasma enhanced chemical vapor deposition (PECVD) technique using hexamethyldisilazane is analyzed. Study of the structure, chemical bonding, surface morphology, mechanical properties and energy gap of the obtained films was carried out using X-ray diffraction, infrared spectroscopy, X-ray photoelectron spectroscopy, atomic force microscopy, optical measurements and nanoindentation. It was established that all the films were X-ray amorphous and had low surface roughness. Intensive hydrogen effusion from the films takes place, when substrate temperature increases up to 400 °C, which promotes a decrease of roughness and an increase in hardness and Young modules more than twice.http://jnep.sumdu.edu.ua/download/numbers/2014/4/articles/jnep_2014_V6_04047.pdfPECVDHexamethyldisilazaneSi-C-N filmsFTIRNanoindentatio
spellingShingle A.O. Kozak
V.I. Ivashchenko
O.K. Porada
L.A. Ivashchenko
T.V. Tomila
Structural, Mechanical and Optical Properties of Plasma-chemical Si-C-N Films
Журнал нано- та електронної фізики
PECVD
Hexamethyldisilazane
Si-C-N films
FTIR
Nanoindentatio
title Structural, Mechanical and Optical Properties of Plasma-chemical Si-C-N Films
title_full Structural, Mechanical and Optical Properties of Plasma-chemical Si-C-N Films
title_fullStr Structural, Mechanical and Optical Properties of Plasma-chemical Si-C-N Films
title_full_unstemmed Structural, Mechanical and Optical Properties of Plasma-chemical Si-C-N Films
title_short Structural, Mechanical and Optical Properties of Plasma-chemical Si-C-N Films
title_sort structural mechanical and optical properties of plasma chemical si c n films
topic PECVD
Hexamethyldisilazane
Si-C-N films
FTIR
Nanoindentatio
url http://jnep.sumdu.edu.ua/download/numbers/2014/4/articles/jnep_2014_V6_04047.pdf
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