{α,α′-Bis[(tert-butyl)(6-methoxypyridin-2-yl)phosphino]-o-xylene}(η2-N-methylmaleinimide)palladium(0) toluene hemisolvate
The solvated title compound, [Pd(C5H5NO2)(C28H38N2O2P2)]·0.5C7H8, consists of a palladium(0) atom coordinated by a chelating α,α′-bis[(tert-butyl)(6-methoxypyridin-2-yl)phosphino]o-xylene ligand and an η2-coordinating N-methylmaleinimide molecule to generate a 16 electron complex in which the metal...
Saved in:
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2025-06-01
|
| Series: | IUCrData |
| Subjects: | |
| Online Access: | https://journals.iucr.org/paper?S2414314625005085 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1849320108218908672 |
|---|---|
| author | Stefan Müller Anke Spannenberg Helfried Neumann Robert Franke Matthias Beller |
| author_facet | Stefan Müller Anke Spannenberg Helfried Neumann Robert Franke Matthias Beller |
| author_sort | Stefan Müller |
| collection | DOAJ |
| description | The solvated title compound, [Pd(C5H5NO2)(C28H38N2O2P2)]·0.5C7H8, consists of a palladium(0) atom coordinated by a chelating α,α′-bis[(tert-butyl)(6-methoxypyridin-2-yl)phosphino]o-xylene ligand and an η2-coordinating N-methylmaleinimide molecule to generate a 16 electron complex in which the metal atom has a pseudo-square-planar coordination environment. The co-crystallized toluene solvent molecule is disordered about an inversion centre by symmetry. Weak C—H...O and C—H...N hydrogen bonds connect the components in the extended structure. |
| format | Article |
| id | doaj-art-2f4e705f2d524fb989a1ac6dfd6793a4 |
| institution | Kabale University |
| issn | 2414-3146 |
| language | English |
| publishDate | 2025-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj-art-2f4e705f2d524fb989a1ac6dfd6793a42025-08-20T03:50:12ZengInternational Union of CrystallographyIUCrData2414-31462025-06-01106x25050810.1107/S2414314625005085hb4516{α,α′-Bis[(tert-butyl)(6-methoxypyridin-2-yl)phosphino]-o-xylene}(η2-N-methylmaleinimide)palladium(0) toluene hemisolvateStefan Müller0Anke Spannenberg1Helfried Neumann2Robert Franke3Matthias Beller4Evonik Oxeno GmbH, Paul-Baumann-Str. 1, 45772 Marl, GermanyLeibniz-Institut für Katalyse e. V., Albert-Einstein-Str. 29a, 18059 Rostock, GermanyLeibniz-Institut für Katalyse e. V., Albert-Einstein-Str. 29a, 18059 Rostock, GermanyEvonik Oxeno GmbH, Paul-Baumann-Str. 1, 45772 Marl, GermanyLeibniz-Institut für Katalyse e. V., Albert-Einstein-Str. 29a, 18059 Rostock, GermanyThe solvated title compound, [Pd(C5H5NO2)(C28H38N2O2P2)]·0.5C7H8, consists of a palladium(0) atom coordinated by a chelating α,α′-bis[(tert-butyl)(6-methoxypyridin-2-yl)phosphino]o-xylene ligand and an η2-coordinating N-methylmaleinimide molecule to generate a 16 electron complex in which the metal atom has a pseudo-square-planar coordination environment. The co-crystallized toluene solvent molecule is disordered about an inversion centre by symmetry. Weak C—H...O and C—H...N hydrogen bonds connect the components in the extended structure.https://journals.iucr.org/paper?S2414314625005085crystal structurechelating ligandpalladium(0) complexdiphosphine ligand |
| spellingShingle | Stefan Müller Anke Spannenberg Helfried Neumann Robert Franke Matthias Beller {α,α′-Bis[(tert-butyl)(6-methoxypyridin-2-yl)phosphino]-o-xylene}(η2-N-methylmaleinimide)palladium(0) toluene hemisolvate IUCrData crystal structure chelating ligand palladium(0) complex diphosphine ligand |
| title | {α,α′-Bis[(tert-butyl)(6-methoxypyridin-2-yl)phosphino]-o-xylene}(η2-N-methylmaleinimide)palladium(0) toluene hemisolvate |
| title_full | {α,α′-Bis[(tert-butyl)(6-methoxypyridin-2-yl)phosphino]-o-xylene}(η2-N-methylmaleinimide)palladium(0) toluene hemisolvate |
| title_fullStr | {α,α′-Bis[(tert-butyl)(6-methoxypyridin-2-yl)phosphino]-o-xylene}(η2-N-methylmaleinimide)palladium(0) toluene hemisolvate |
| title_full_unstemmed | {α,α′-Bis[(tert-butyl)(6-methoxypyridin-2-yl)phosphino]-o-xylene}(η2-N-methylmaleinimide)palladium(0) toluene hemisolvate |
| title_short | {α,α′-Bis[(tert-butyl)(6-methoxypyridin-2-yl)phosphino]-o-xylene}(η2-N-methylmaleinimide)palladium(0) toluene hemisolvate |
| title_sort | α α bis tert butyl 6 methoxypyridin 2 yl phosphino o xylene η2 n methylmaleinimide palladium 0 toluene hemisolvate |
| topic | crystal structure chelating ligand palladium(0) complex diphosphine ligand |
| url | https://journals.iucr.org/paper?S2414314625005085 |
| work_keys_str_mv | AT stefanmuller aabistertbutyl6methoxypyridin2ylphosphinooxyleneē2nmethylmaleinimidepalladium0toluenehemisolvate AT ankespannenberg aabistertbutyl6methoxypyridin2ylphosphinooxyleneē2nmethylmaleinimidepalladium0toluenehemisolvate AT helfriedneumann aabistertbutyl6methoxypyridin2ylphosphinooxyleneē2nmethylmaleinimidepalladium0toluenehemisolvate AT robertfranke aabistertbutyl6methoxypyridin2ylphosphinooxyleneē2nmethylmaleinimidepalladium0toluenehemisolvate AT matthiasbeller aabistertbutyl6methoxypyridin2ylphosphinooxyleneē2nmethylmaleinimidepalladium0toluenehemisolvate |