Development of Ecofriendly Corrosion Inhibitors for Application in Acidization of Petroleum Oil Well

In the present investigation the protective ability of 1-(2-aminoethyl)-2-octadecylimidazoline (AEODI) and 1-(2-octadecylamidoethyl)-2-octadecylimidazoline (ODAEODI) as corrosion inhibitors for N80 steel in 15% hydrochloric acid has been studied, which may find application as ecofriendly corrosion i...

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Main Authors: M. Yadav, Sumit Kumar, P. N. Yadav
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2013/618684
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author M. Yadav
Sumit Kumar
P. N. Yadav
author_facet M. Yadav
Sumit Kumar
P. N. Yadav
author_sort M. Yadav
collection DOAJ
description In the present investigation the protective ability of 1-(2-aminoethyl)-2-octadecylimidazoline (AEODI) and 1-(2-octadecylamidoethyl)-2-octadecylimidazoline (ODAEODI) as corrosion inhibitors for N80 steel in 15% hydrochloric acid has been studied, which may find application as ecofriendly corrosion inhibitors in acidizing processes in petroleum industry. Different concentration of synthesized inhibitors AEODI and ODAEODI was added to test solution (15% HCl), and corrosion inhibition of N80 steel was tested by weight loss, potentiodynamic polarization, and AC impedance measurements. Influence of temperature (298 to 323 K) on the inhibition behaviour was studied. Surface studies were performed by using SEM. It was found that both the inhibitors were effective inhibitors, and their inhibition efficiency was significantly increased with increasing their concentration. Polarization curves revealed that the used inhibitors represent mixed-type inhibitors. The adsorption of used inhibitors led to a reduction in the double-layer capacitance and an increase in the charge transfer resistance. The adsorption of used compounds was found to obey Langmuir isotherm. The adsorption of the corrosion inhibitors at the surface of N80 steel is the root cause of corrosion inhibition.
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spelling doaj-art-2efae461ad25453794e098b1c41315bf2025-02-03T01:01:18ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/618684618684Development of Ecofriendly Corrosion Inhibitors for Application in Acidization of Petroleum Oil WellM. Yadav0Sumit Kumar1P. N. Yadav2Department of Applied Chemistry, Indian School of Mines, Dhanbad 826004, IndiaDepartment of Applied Chemistry, Indian School of Mines, Dhanbad 826004, IndiaDepartment of Physics Post Graduate College, Ghazipur 233001, IndiaIn the present investigation the protective ability of 1-(2-aminoethyl)-2-octadecylimidazoline (AEODI) and 1-(2-octadecylamidoethyl)-2-octadecylimidazoline (ODAEODI) as corrosion inhibitors for N80 steel in 15% hydrochloric acid has been studied, which may find application as ecofriendly corrosion inhibitors in acidizing processes in petroleum industry. Different concentration of synthesized inhibitors AEODI and ODAEODI was added to test solution (15% HCl), and corrosion inhibition of N80 steel was tested by weight loss, potentiodynamic polarization, and AC impedance measurements. Influence of temperature (298 to 323 K) on the inhibition behaviour was studied. Surface studies were performed by using SEM. It was found that both the inhibitors were effective inhibitors, and their inhibition efficiency was significantly increased with increasing their concentration. Polarization curves revealed that the used inhibitors represent mixed-type inhibitors. The adsorption of used inhibitors led to a reduction in the double-layer capacitance and an increase in the charge transfer resistance. The adsorption of used compounds was found to obey Langmuir isotherm. The adsorption of the corrosion inhibitors at the surface of N80 steel is the root cause of corrosion inhibition.http://dx.doi.org/10.1155/2013/618684
spellingShingle M. Yadav
Sumit Kumar
P. N. Yadav
Development of Ecofriendly Corrosion Inhibitors for Application in Acidization of Petroleum Oil Well
Journal of Chemistry
title Development of Ecofriendly Corrosion Inhibitors for Application in Acidization of Petroleum Oil Well
title_full Development of Ecofriendly Corrosion Inhibitors for Application in Acidization of Petroleum Oil Well
title_fullStr Development of Ecofriendly Corrosion Inhibitors for Application in Acidization of Petroleum Oil Well
title_full_unstemmed Development of Ecofriendly Corrosion Inhibitors for Application in Acidization of Petroleum Oil Well
title_short Development of Ecofriendly Corrosion Inhibitors for Application in Acidization of Petroleum Oil Well
title_sort development of ecofriendly corrosion inhibitors for application in acidization of petroleum oil well
url http://dx.doi.org/10.1155/2013/618684
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