Chemical composition of Egyptian propolis and studying its antimicrobial activity and synergistic action with honey against some multidrug-resistant uropathogens

Abstract Urinary tract infection (UTI) is one of the most common infections worldwide, increasing the incidence of antibiotic resistance and creating demand for alternative antimicrobial agents. Propolis, a natural antimicrobial agent, has been used in ancient folk medicine. This study evaluates the...

Full description

Saved in:
Bibliographic Details
Main Authors: Asmaa K. Helmy, Nagwa M. Sidkey, Marwa M. Abdel-Aziz, Atef A. El-Hela
Format: Article
Language:English
Published: Nature Portfolio 2025-05-01
Series:Scientific Reports
Subjects:
Online Access:https://doi.org/10.1038/s41598-025-00773-1
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1849731100989980672
author Asmaa K. Helmy
Nagwa M. Sidkey
Marwa M. Abdel-Aziz
Atef A. El-Hela
author_facet Asmaa K. Helmy
Nagwa M. Sidkey
Marwa M. Abdel-Aziz
Atef A. El-Hela
author_sort Asmaa K. Helmy
collection DOAJ
description Abstract Urinary tract infection (UTI) is one of the most common infections worldwide, increasing the incidence of antibiotic resistance and creating demand for alternative antimicrobial agents. Propolis, a natural antimicrobial agent, has been used in ancient folk medicine. This study evaluates the effectiveness of ethanolic extract of propolis (EEP) alone and in combination with honey against multidrug-resistant (MDR) uropathogens and also investigates the chemical composition of Egyptian propolis, which may be a potential therapeutic approach against MDR uropathogens. EEP was prepared, followed by column chromatographic fractionation using four different solvent systems. The ethyl acetate fraction was further fractionated through vacuum liquid chromatography (VLC). The antimicrobial activity of the EEP, propolis fractions, honey, and EEP-Honey mixture was studied, and the fraction with the best antimicrobial activity was analyzed by GC-MS and HPLC. The results indicated that EEP showed antimicrobial activity against the five MDR uropathogens with varying potential, while honey showed no activity against these pathogens. In comparison, the EEP-Honey mixture exhibited good antimicrobial synergy, with the MIC value decreasing by approximately 4–8 folds. In propolis fractionation, ethyl acetate was the best solvent for extracting antimicrobial substances from EEP, and fraction 5 (F5) was the most active fraction, with inhibition zone diameters of 30.33, 29.00, 21.58, 25.33, and 27.67 mm against MDR P. aeruginosa, E. coli, K. pneumoniae, S. saprophyticus, and C. albicans, respectively. GC-MS analysis of the F5 fraction revealed the presence of phenolics, flavonoids, terpenoids, acids, and alkaloids. In addition, HPLC polyphenol analysis identified 14 phenolic acids and flavonoid compounds with concentrations ranging from 117.36 to 5657.66 µg/g. Overall, the current findings highlighted the promising antimicrobial synergy of the EEP-Honey mixture against MDR urinary pathogens. The phytochemical analysis of propolis also identified potential bioactive compounds responsible for its biological and pharmaceutical properties.
format Article
id doaj-art-2ecb8bcd50864fe7a96378ce687d7b11
institution DOAJ
issn 2045-2322
language English
publishDate 2025-05-01
publisher Nature Portfolio
record_format Article
series Scientific Reports
spelling doaj-art-2ecb8bcd50864fe7a96378ce687d7b112025-08-20T03:08:40ZengNature PortfolioScientific Reports2045-23222025-05-0115111510.1038/s41598-025-00773-1Chemical composition of Egyptian propolis and studying its antimicrobial activity and synergistic action with honey against some multidrug-resistant uropathogensAsmaa K. Helmy0Nagwa M. Sidkey1Marwa M. Abdel-Aziz2Atef A. El-Hela3Botany and Microbiology Department, Faculty of Science for Girls, Al-Azhar UniversityBotany and Microbiology Department, Faculty of Science for Girls, Al-Azhar UniversityThe Regional Centre for Mycology and Biotechnology, Al-Azhar UniversityPharmacognosy and Medicinal Plants Department, Faculty of Pharmacy, Al-Azhar UniversityAbstract Urinary tract infection (UTI) is one of the most common infections worldwide, increasing the incidence of antibiotic resistance and creating demand for alternative antimicrobial agents. Propolis, a natural antimicrobial agent, has been used in ancient folk medicine. This study evaluates the effectiveness of ethanolic extract of propolis (EEP) alone and in combination with honey against multidrug-resistant (MDR) uropathogens and also investigates the chemical composition of Egyptian propolis, which may be a potential therapeutic approach against MDR uropathogens. EEP was prepared, followed by column chromatographic fractionation using four different solvent systems. The ethyl acetate fraction was further fractionated through vacuum liquid chromatography (VLC). The antimicrobial activity of the EEP, propolis fractions, honey, and EEP-Honey mixture was studied, and the fraction with the best antimicrobial activity was analyzed by GC-MS and HPLC. The results indicated that EEP showed antimicrobial activity against the five MDR uropathogens with varying potential, while honey showed no activity against these pathogens. In comparison, the EEP-Honey mixture exhibited good antimicrobial synergy, with the MIC value decreasing by approximately 4–8 folds. In propolis fractionation, ethyl acetate was the best solvent for extracting antimicrobial substances from EEP, and fraction 5 (F5) was the most active fraction, with inhibition zone diameters of 30.33, 29.00, 21.58, 25.33, and 27.67 mm against MDR P. aeruginosa, E. coli, K. pneumoniae, S. saprophyticus, and C. albicans, respectively. GC-MS analysis of the F5 fraction revealed the presence of phenolics, flavonoids, terpenoids, acids, and alkaloids. In addition, HPLC polyphenol analysis identified 14 phenolic acids and flavonoid compounds with concentrations ranging from 117.36 to 5657.66 µg/g. Overall, the current findings highlighted the promising antimicrobial synergy of the EEP-Honey mixture against MDR urinary pathogens. The phytochemical analysis of propolis also identified potential bioactive compounds responsible for its biological and pharmaceutical properties.https://doi.org/10.1038/s41598-025-00773-1UropathogensPropolisAntimicrobial activityEEPEthanolic extract of propolisActive fraction
spellingShingle Asmaa K. Helmy
Nagwa M. Sidkey
Marwa M. Abdel-Aziz
Atef A. El-Hela
Chemical composition of Egyptian propolis and studying its antimicrobial activity and synergistic action with honey against some multidrug-resistant uropathogens
Scientific Reports
Uropathogens
Propolis
Antimicrobial activity
EEP
Ethanolic extract of propolis
Active fraction
title Chemical composition of Egyptian propolis and studying its antimicrobial activity and synergistic action with honey against some multidrug-resistant uropathogens
title_full Chemical composition of Egyptian propolis and studying its antimicrobial activity and synergistic action with honey against some multidrug-resistant uropathogens
title_fullStr Chemical composition of Egyptian propolis and studying its antimicrobial activity and synergistic action with honey against some multidrug-resistant uropathogens
title_full_unstemmed Chemical composition of Egyptian propolis and studying its antimicrobial activity and synergistic action with honey against some multidrug-resistant uropathogens
title_short Chemical composition of Egyptian propolis and studying its antimicrobial activity and synergistic action with honey against some multidrug-resistant uropathogens
title_sort chemical composition of egyptian propolis and studying its antimicrobial activity and synergistic action with honey against some multidrug resistant uropathogens
topic Uropathogens
Propolis
Antimicrobial activity
EEP
Ethanolic extract of propolis
Active fraction
url https://doi.org/10.1038/s41598-025-00773-1
work_keys_str_mv AT asmaakhelmy chemicalcompositionofegyptianpropolisandstudyingitsantimicrobialactivityandsynergisticactionwithhoneyagainstsomemultidrugresistanturopathogens
AT nagwamsidkey chemicalcompositionofegyptianpropolisandstudyingitsantimicrobialactivityandsynergisticactionwithhoneyagainstsomemultidrugresistanturopathogens
AT marwamabdelaziz chemicalcompositionofegyptianpropolisandstudyingitsantimicrobialactivityandsynergisticactionwithhoneyagainstsomemultidrugresistanturopathogens
AT atefaelhela chemicalcompositionofegyptianpropolisandstudyingitsantimicrobialactivityandsynergisticactionwithhoneyagainstsomemultidrugresistanturopathogens