Fabrication a sustainable adsorbent nanocellulose-mesoporous hectorite bead for methylene blue adsorption
In this study, fabrication of mesoporous nanocellulose-hectorite-alginate bead (B-NcH) composites and their application for adsorption of MB from water was carried out. The synthesis of nanocellulose (NC) was conducted from mangosteen waste peel (Garcinia mangostana L.). Garcinia mangostana L. peel...
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Elsevier
2024-12-01
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| Series: | Case Studies in Chemical and Environmental Engineering |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2666016424002445 |
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| author | Holilah Asranudin Noureddine El Messaoudi Maria Ulfa Amir Hamzah Zuratul Ain Abdul Hamid Dini Viandi Ramadhani Lisman Suryanegara Melbi Mahardika Alvina Tata Melenia Agus Wedi Pratama Didik Prasetyoko |
| author_facet | Holilah Asranudin Noureddine El Messaoudi Maria Ulfa Amir Hamzah Zuratul Ain Abdul Hamid Dini Viandi Ramadhani Lisman Suryanegara Melbi Mahardika Alvina Tata Melenia Agus Wedi Pratama Didik Prasetyoko |
| author_sort | Holilah |
| collection | DOAJ |
| description | In this study, fabrication of mesoporous nanocellulose-hectorite-alginate bead (B-NcH) composites and their application for adsorption of MB from water was carried out. The synthesis of nanocellulose (NC) was conducted from mangosteen waste peel (Garcinia mangostana L.). Garcinia mangostana L. peel had 58.9 ± 0,41 % content of cellulose. NCs was successfully isolated using the acid hydrolysis method. NC from Garcinia mangostana L. peel had a diameter of 24.5 ± 0.2 nm and a length of 381.2 ± 10.4 nm. The superabsorbent was composed of nanocrystalline cellulose, mesoporous hectorite, and alginate. The functional group, phase, and morphology of composite was investigated. The composite with 5 % NC had excellent mechanical strength. The B-NcH5 showed a high adsorption capacity of methylene blue (MB), reaching 98.64 % at an adsorbent dose of 30 mg for 90 min. The presence of hectorite can increase the adsorption ability compared to NCs-alginate. The equilibrium adsorption data followed the Freundlich isotherm; however, the kinetics of adsorption showed the usefulness of adopting the PSO kinetic model. The highest adsorption capacity of B-NcH5 for MB was determined to be 57.59 mg/g. For thermodynamic studies, it was revealed that the adsorption of MB on BNcH-5 is a spontaneous and endothermic process. The removal efficiency was observed in six consecutive cycles, indicating at the favorable reusability of this adsorbent. These results validate the potential use of this B-NcH5 adsorbent for water treatment applications. |
| format | Article |
| id | doaj-art-2ea7c4dedc80499fa117c8a1e320f549 |
| institution | OA Journals |
| issn | 2666-0164 |
| language | English |
| publishDate | 2024-12-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Case Studies in Chemical and Environmental Engineering |
| spelling | doaj-art-2ea7c4dedc80499fa117c8a1e320f5492025-08-20T02:38:58ZengElsevierCase Studies in Chemical and Environmental Engineering2666-01642024-12-011010085010.1016/j.cscee.2024.100850Fabrication a sustainable adsorbent nanocellulose-mesoporous hectorite bead for methylene blue adsorption Holilah0 Asranudin1Noureddine El Messaoudi2Maria Ulfa3Amir Hamzah4Zuratul Ain Abdul Hamid5Dini Viandi Ramadhani6Lisman Suryanegara7Melbi Mahardika8Alvina Tata Melenia9Agus Wedi Pratama10Didik Prasetyoko11Research Center for Biomass and Bioproducts, National Research and Innovation Agency of Indonesia (BRIN), Cibinong, 16911, Indonesia; Research Collaboration Center for Nanocellulose, BRIN-Andalas University, Padang, 25163, Indonesia; Research Collaboration Center for Biomass and Biorefinery Between BRIN and Universitas Padjadjaran, Jatinangor, 45363, Indonesia; Corresponding author. Research Center for Biomass and Bioproducts, National Research and Innovation Agency of Indonesia (BRIN), Cibinong, 16911, Indonesia.Research Center for Biomass and Bioproducts, National Research and Innovation Agency of Indonesia (BRIN), Cibinong, 16911, IndonesiaLaboratory of Applied Chemistry and Environment, Faculty of Sciences, Ibn Zohr University, Agadir, 80000, Morocco; Corresponding author.Chemistry Education Study Program, Faculty of Teacher Training and Education, Sebelas Maret University, Surakarta, 57126, Central Java, IndonesiaDeputy for Infrastructure Research and Innovation, National Research and Innovation Agency of Indonesia (BRIN), Cibinong, 16911, IndonesiaSchool of Materials & Mineral Resources Engineering, Universiti Sains Malaysia, 14300, Nibong Tebal Pulau Pinang, MalaysiaDepartment of Biology, Faculty of Science and Data Analytics, Institut Teknologi Sepuluh Nopember, Surabaya, IndonesiaResearch Center for Biomass and Bioproducts, National Research and Innovation Agency of Indonesia (BRIN), Cibinong, 16911, IndonesiaResearch Center for Biomass and Bioproducts, National Research and Innovation Agency of Indonesia (BRIN), Cibinong, 16911, IndonesiaDepartment of Chemistry, Faculty of Science and Data Analytics, Institut Teknologi Sepuluh Nopember (ITS), Kampus ITS Sukolilo, Surabaya, 60111, IndonesiaDepartment of Chemistry, Faculty of Science and Data Analytics, Institut Teknologi Sepuluh Nopember (ITS), Kampus ITS Sukolilo, Surabaya, 60111, IndonesiaDepartment of Chemistry, Faculty of Science and Data Analytics, Institut Teknologi Sepuluh Nopember (ITS), Kampus ITS Sukolilo, Surabaya, 60111, IndonesiaIn this study, fabrication of mesoporous nanocellulose-hectorite-alginate bead (B-NcH) composites and their application for adsorption of MB from water was carried out. The synthesis of nanocellulose (NC) was conducted from mangosteen waste peel (Garcinia mangostana L.). Garcinia mangostana L. peel had 58.9 ± 0,41 % content of cellulose. NCs was successfully isolated using the acid hydrolysis method. NC from Garcinia mangostana L. peel had a diameter of 24.5 ± 0.2 nm and a length of 381.2 ± 10.4 nm. The superabsorbent was composed of nanocrystalline cellulose, mesoporous hectorite, and alginate. The functional group, phase, and morphology of composite was investigated. The composite with 5 % NC had excellent mechanical strength. The B-NcH5 showed a high adsorption capacity of methylene blue (MB), reaching 98.64 % at an adsorbent dose of 30 mg for 90 min. The presence of hectorite can increase the adsorption ability compared to NCs-alginate. The equilibrium adsorption data followed the Freundlich isotherm; however, the kinetics of adsorption showed the usefulness of adopting the PSO kinetic model. The highest adsorption capacity of B-NcH5 for MB was determined to be 57.59 mg/g. For thermodynamic studies, it was revealed that the adsorption of MB on BNcH-5 is a spontaneous and endothermic process. The removal efficiency was observed in six consecutive cycles, indicating at the favorable reusability of this adsorbent. These results validate the potential use of this B-NcH5 adsorbent for water treatment applications.http://www.sciencedirect.com/science/article/pii/S2666016424002445NanocelluloseWater treatmentHectoriteBeadMethylene blueAdsorption |
| spellingShingle | Holilah Asranudin Noureddine El Messaoudi Maria Ulfa Amir Hamzah Zuratul Ain Abdul Hamid Dini Viandi Ramadhani Lisman Suryanegara Melbi Mahardika Alvina Tata Melenia Agus Wedi Pratama Didik Prasetyoko Fabrication a sustainable adsorbent nanocellulose-mesoporous hectorite bead for methylene blue adsorption Case Studies in Chemical and Environmental Engineering Nanocellulose Water treatment Hectorite Bead Methylene blue Adsorption |
| title | Fabrication a sustainable adsorbent nanocellulose-mesoporous hectorite bead for methylene blue adsorption |
| title_full | Fabrication a sustainable adsorbent nanocellulose-mesoporous hectorite bead for methylene blue adsorption |
| title_fullStr | Fabrication a sustainable adsorbent nanocellulose-mesoporous hectorite bead for methylene blue adsorption |
| title_full_unstemmed | Fabrication a sustainable adsorbent nanocellulose-mesoporous hectorite bead for methylene blue adsorption |
| title_short | Fabrication a sustainable adsorbent nanocellulose-mesoporous hectorite bead for methylene blue adsorption |
| title_sort | fabrication a sustainable adsorbent nanocellulose mesoporous hectorite bead for methylene blue adsorption |
| topic | Nanocellulose Water treatment Hectorite Bead Methylene blue Adsorption |
| url | http://www.sciencedirect.com/science/article/pii/S2666016424002445 |
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