Decoration of silver and silver oxide nanoparticles on a magnetic albumin modified Chitosan support and its catalytic efficiency investigation
Abstract In the present study, the magnetic chitosan cross-linked with oxidized chitosan biopolymer was modified with bovine serum albumin protein. Then, the prepared magnetic biosupport was treated with AgNO3 solution under ultrasonic irradiation. After that Ag decoration on the magnetic BSA-modifi...
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2025-07-01
|
| Series: | Scientific Reports |
| Subjects: | |
| Online Access: | https://doi.org/10.1038/s41598-025-09389-x |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1849766726298763264 |
|---|---|
| author | Nazi Salekmokhtari Fatemeh Rafiee |
| author_facet | Nazi Salekmokhtari Fatemeh Rafiee |
| author_sort | Nazi Salekmokhtari |
| collection | DOAJ |
| description | Abstract In the present study, the magnetic chitosan cross-linked with oxidized chitosan biopolymer was modified with bovine serum albumin protein. Then, the prepared magnetic biosupport was treated with AgNO3 solution under ultrasonic irradiation. After that Ag decoration on the magnetic BSA-modified chitosan support surface, the obtained Fe3O4@BSA-CS@Ag/Ag2O nanocomposite was characterized by various techniques including FT-IR, FE-SEM, TEM, EDS, XRD, VSM, BET and ICP. This nanocatalyst showed excellent efficiency in the reduction reaction of nitroarenes and organic dyes containing methylene blue, methyl orange, and rhodamine B. The advantages of this catalytic system is high conversion at short reaction times using a small amount of silver-based catalyst, easy separation of the catalyst from the reaction mixture with an external magnet and its reusability in the reduction reaction. |
| format | Article |
| id | doaj-art-2ea30e1c0e4942599e8f35a13529ac86 |
| institution | DOAJ |
| issn | 2045-2322 |
| language | English |
| publishDate | 2025-07-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Scientific Reports |
| spelling | doaj-art-2ea30e1c0e4942599e8f35a13529ac862025-08-20T03:04:29ZengNature PortfolioScientific Reports2045-23222025-07-0115111610.1038/s41598-025-09389-xDecoration of silver and silver oxide nanoparticles on a magnetic albumin modified Chitosan support and its catalytic efficiency investigationNazi Salekmokhtari0Fatemeh Rafiee1Department of Organic Chemistry, Faculty of Chemistry, Alzahra UniversityDepartment of Organic Chemistry, Faculty of Chemistry, Alzahra UniversityAbstract In the present study, the magnetic chitosan cross-linked with oxidized chitosan biopolymer was modified with bovine serum albumin protein. Then, the prepared magnetic biosupport was treated with AgNO3 solution under ultrasonic irradiation. After that Ag decoration on the magnetic BSA-modified chitosan support surface, the obtained Fe3O4@BSA-CS@Ag/Ag2O nanocomposite was characterized by various techniques including FT-IR, FE-SEM, TEM, EDS, XRD, VSM, BET and ICP. This nanocatalyst showed excellent efficiency in the reduction reaction of nitroarenes and organic dyes containing methylene blue, methyl orange, and rhodamine B. The advantages of this catalytic system is high conversion at short reaction times using a small amount of silver-based catalyst, easy separation of the catalyst from the reaction mixture with an external magnet and its reusability in the reduction reaction.https://doi.org/10.1038/s41598-025-09389-xSilver catalyzedProtein supportMagnetic catalystChitosanNitroarene reductionOrganic dyes reduction |
| spellingShingle | Nazi Salekmokhtari Fatemeh Rafiee Decoration of silver and silver oxide nanoparticles on a magnetic albumin modified Chitosan support and its catalytic efficiency investigation Scientific Reports Silver catalyzed Protein support Magnetic catalyst Chitosan Nitroarene reduction Organic dyes reduction |
| title | Decoration of silver and silver oxide nanoparticles on a magnetic albumin modified Chitosan support and its catalytic efficiency investigation |
| title_full | Decoration of silver and silver oxide nanoparticles on a magnetic albumin modified Chitosan support and its catalytic efficiency investigation |
| title_fullStr | Decoration of silver and silver oxide nanoparticles on a magnetic albumin modified Chitosan support and its catalytic efficiency investigation |
| title_full_unstemmed | Decoration of silver and silver oxide nanoparticles on a magnetic albumin modified Chitosan support and its catalytic efficiency investigation |
| title_short | Decoration of silver and silver oxide nanoparticles on a magnetic albumin modified Chitosan support and its catalytic efficiency investigation |
| title_sort | decoration of silver and silver oxide nanoparticles on a magnetic albumin modified chitosan support and its catalytic efficiency investigation |
| topic | Silver catalyzed Protein support Magnetic catalyst Chitosan Nitroarene reduction Organic dyes reduction |
| url | https://doi.org/10.1038/s41598-025-09389-x |
| work_keys_str_mv | AT nazisalekmokhtari decorationofsilverandsilveroxidenanoparticlesonamagneticalbuminmodifiedchitosansupportanditscatalyticefficiencyinvestigation AT fatemehrafiee decorationofsilverandsilveroxidenanoparticlesonamagneticalbuminmodifiedchitosansupportanditscatalyticefficiencyinvestigation |