X-ray diffraction studies of the growth process of thin films of high-entropy TiNbZrTaHfCu alloy in situ using synchrotron radiation

High-entropy alloys based on refractory metals, possessing an unusual combination of physical, mechanical, tribological, electrophysical, etc. properties, can be recommended for use in various fields of industry and medicine. The aim of the work is to study the growth process of high-entropy alloys...

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Main Authors: Yu.F. Ivanov, Yu.Kh. Akhmadeev, A.A. Klopotov, N.A. Prokopenko, E.A. Petrikova, O.V. Krysina, V.V. Shugurov, A.N. Shmakov, V.Yu. Lavrov
Format: Article
Language:Russian
Published: Tver State University 2024-12-01
Series:Физико-химические аспекты изучения кластеров, наноструктур и наноматериалов
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Online Access:https://physchemaspects.ru/2024/doi-10-26456-pcascnn-2024-16-140/?lang=en
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author Yu.F. Ivanov
Yu.Kh. Akhmadeev
A.A. Klopotov
N.A. Prokopenko
E.A. Petrikova
O.V. Krysina
V.V. Shugurov
A.N. Shmakov
V.Yu. Lavrov
author_facet Yu.F. Ivanov
Yu.Kh. Akhmadeev
A.A. Klopotov
N.A. Prokopenko
E.A. Petrikova
O.V. Krysina
V.V. Shugurov
A.N. Shmakov
V.Yu. Lavrov
author_sort Yu.F. Ivanov
collection DOAJ
description High-entropy alloys based on refractory metals, possessing an unusual combination of physical, mechanical, tribological, electrophysical, etc. properties, can be recommended for use in various fields of industry and medicine. The aim of the work is to study the growth process of high-entropy alloys films of the Ti-Nb-Zr-Ta-Hf-Cu system in real time by X-ray phase analysis using synchrotron radiation. Experiments on the deposition of multielement metal films were carried out on the VEIPS-1 setup developed at the Institute of high current electronics Siberian branch of the Russian academy of sciences for studying the processes of the film and coating formation on a synchrotron radiation source. The process of in situ thin film structure formation with high time resolution was studied using a synchrotron radiation source – the VEPP-3 electron storage ring, the Institute of nuclear physics, Siberian branch of the Russian academy of sciences. It is shown that the deposition of Ti-Nb-Zr-Ta-Hf-Cu plasma on a HG40 substrate is accompanied by the formation of an amorphous-crystalline state represented by phases of the composition (presumably) Ti-Nb-Zr-Ta-Hf-Cu, TiZr, NbZr, and CuTiZr, formed at different stages of film deposition. The main phase is the Ti-Nb-Zr-Ta-Hf-Cu composition.
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institution Kabale University
issn 2226-4442
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language Russian
publishDate 2024-12-01
publisher Tver State University
record_format Article
series Физико-химические аспекты изучения кластеров, наноструктур и наноматериалов
spelling doaj-art-2e209ca5d427424293fcc112e10a3ff72024-12-25T15:44:48ZrusTver State UniversityФизико-химические аспекты изучения кластеров, наноструктур и наноматериалов2226-44422658-43602024-12-011614015310.26456/pcascnn/2024.16.140X-ray diffraction studies of the growth process of thin films of high-entropy TiNbZrTaHfCu alloy in situ using synchrotron radiationYu.F. Ivanov0Yu.Kh. Akhmadeev1A.A. Klopotov2N.A. Prokopenko3E.A. Petrikova4O.V. Krysina5V.V. Shugurov6A.N. Shmakov7V.Yu. Lavrov8Institute of High- Current Electronics of the Siberian Branch of the RASInstitute of High- Current Electronics of the Siberian Branch of the RASTomsk State University of Architecture and BuildingInstitute of High- Current Electronics of the Siberian Branch of the RASInstitute of High- Current Electronics of the Siberian Branch of the RASInstitute of High- Current Electronics of the Siberian Branch of the RASInstitute of High- Current Electronics of the Siberian Branch of the RASInstitute of High- Current Electronics of the Siberian Branch of the RASTomsk State University of Architecture and BuildingHigh-entropy alloys based on refractory metals, possessing an unusual combination of physical, mechanical, tribological, electrophysical, etc. properties, can be recommended for use in various fields of industry and medicine. The aim of the work is to study the growth process of high-entropy alloys films of the Ti-Nb-Zr-Ta-Hf-Cu system in real time by X-ray phase analysis using synchrotron radiation. Experiments on the deposition of multielement metal films were carried out on the VEIPS-1 setup developed at the Institute of high current electronics Siberian branch of the Russian academy of sciences for studying the processes of the film and coating formation on a synchrotron radiation source. The process of in situ thin film structure formation with high time resolution was studied using a synchrotron radiation source – the VEPP-3 electron storage ring, the Institute of nuclear physics, Siberian branch of the Russian academy of sciences. It is shown that the deposition of Ti-Nb-Zr-Ta-Hf-Cu plasma on a HG40 substrate is accompanied by the formation of an amorphous-crystalline state represented by phases of the composition (presumably) Ti-Nb-Zr-Ta-Hf-Cu, TiZr, NbZr, and CuTiZr, formed at different stages of film deposition. The main phase is the Ti-Nb-Zr-Ta-Hf-Cu composition. https://physchemaspects.ru/2024/doi-10-26456-pcascnn-2024-16-140/?lang=enhigh-entropy alloyrefractory metalssynchrotron radiationphase compositioncopper alloying
spellingShingle Yu.F. Ivanov
Yu.Kh. Akhmadeev
A.A. Klopotov
N.A. Prokopenko
E.A. Petrikova
O.V. Krysina
V.V. Shugurov
A.N. Shmakov
V.Yu. Lavrov
X-ray diffraction studies of the growth process of thin films of high-entropy TiNbZrTaHfCu alloy in situ using synchrotron radiation
Физико-химические аспекты изучения кластеров, наноструктур и наноматериалов
high-entropy alloy
refractory metals
synchrotron radiation
phase composition
copper alloying
title X-ray diffraction studies of the growth process of thin films of high-entropy TiNbZrTaHfCu alloy in situ using synchrotron radiation
title_full X-ray diffraction studies of the growth process of thin films of high-entropy TiNbZrTaHfCu alloy in situ using synchrotron radiation
title_fullStr X-ray diffraction studies of the growth process of thin films of high-entropy TiNbZrTaHfCu alloy in situ using synchrotron radiation
title_full_unstemmed X-ray diffraction studies of the growth process of thin films of high-entropy TiNbZrTaHfCu alloy in situ using synchrotron radiation
title_short X-ray diffraction studies of the growth process of thin films of high-entropy TiNbZrTaHfCu alloy in situ using synchrotron radiation
title_sort x ray diffraction studies of the growth process of thin films of high entropy tinbzrtahfcu alloy in situ using synchrotron radiation
topic high-entropy alloy
refractory metals
synchrotron radiation
phase composition
copper alloying
url https://physchemaspects.ru/2024/doi-10-26456-pcascnn-2024-16-140/?lang=en
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