Synthesis and Application of Bis[1,2-(4-aryl-2-alkyl-1H- inden-1-yl)]Ethane as an Efficient`Ligand for Preparation of Olefin Polymerization Catalysts
In this study, a class of bis-1,2-(4-aryl-2-alkyl-1H- inden-1-yl) ethane was synthesized and characterized by spectroscopic methods such as 1HNMR, 13CNMR, melting point and FTIR. bis-1,2-(4-aryl-2-alkyl-1H- inden-1-yl) ethane was synthesized by the reaction of butyllithium, arylindenes and dibromoe...
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University of Tehran
2019-04-01
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| Series: | Journal of Sciences, Islamic Republic of Iran |
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| Online Access: | https://jsciences.ut.ac.ir/article_71749_b93b48fa58d212e0abfc55b6fe67d295.pdf |
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| author | v. Lotfi B. Emamgholi S. T. Bahrami E. poorakbar |
| author_facet | v. Lotfi B. Emamgholi S. T. Bahrami E. poorakbar |
| author_sort | v. Lotfi |
| collection | DOAJ |
| description | In this study, a class of bis-1,2-(4-aryl-2-alkyl-1H- inden-1-yl) ethane was synthesized and characterized by spectroscopic methods such as 1HNMR, 13CNMR, melting point and FTIR. bis-1,2-(4-aryl-2-alkyl-1H- inden-1-yl) ethane was synthesized by the reaction of butyllithium, arylindenes and dibromoethane in a facile, one-pot strategy. It’s shown that these methods have a wide scope to afford libraries of aryl-substituted indenes. The prepared compounds was then applied as a ligand for the fabrication of a number of metal complexes which can be used as catalyst for the polymerization of the olefins. |
| format | Article |
| id | doaj-art-2e06cf17f73e4c9b88508e14bbf6d366 |
| institution | OA Journals |
| issn | 1016-1104 2345-6914 |
| language | English |
| publishDate | 2019-04-01 |
| publisher | University of Tehran |
| record_format | Article |
| series | Journal of Sciences, Islamic Republic of Iran |
| spelling | doaj-art-2e06cf17f73e4c9b88508e14bbf6d3662025-08-20T02:25:54ZengUniversity of TehranJournal of Sciences, Islamic Republic of Iran1016-11042345-69142019-04-0130213514210.22059/jsciences.2019.7174971749Synthesis and Application of Bis[1,2-(4-aryl-2-alkyl-1H- inden-1-yl)]Ethane as an Efficient`Ligand for Preparation of Olefin Polymerization Catalystsv. Lotfi0B. Emamgholi1S. T. Bahrami2E. poorakbar3Department of Chemistry, Faculty of Sciences, University of Tehran, Tehran, Islamic Republic of IranDepartment of Chemistry, Faculty of Sciences, Imam Khomeini International University, Qazvin, Islamic Republic of IranDepartment of Chemistry, Faculty of Sciences, Islamic Azad University, Qaemshahr Branch, Qaemshahr, Islamic Republic of IranDepartment of Biology, Faculty of Sciences,University of Payame Noor, Tehran, Islamic Republic of IranIn this study, a class of bis-1,2-(4-aryl-2-alkyl-1H- inden-1-yl) ethane was synthesized and characterized by spectroscopic methods such as 1HNMR, 13CNMR, melting point and FTIR. bis-1,2-(4-aryl-2-alkyl-1H- inden-1-yl) ethane was synthesized by the reaction of butyllithium, arylindenes and dibromoethane in a facile, one-pot strategy. It’s shown that these methods have a wide scope to afford libraries of aryl-substituted indenes. The prepared compounds was then applied as a ligand for the fabrication of a number of metal complexes which can be used as catalyst for the polymerization of the olefins.https://jsciences.ut.ac.ir/article_71749_b93b48fa58d212e0abfc55b6fe67d295.pdforganometallic compoundmetallocenebis-arylalkyl ethane ligandcatalysis |
| spellingShingle | v. Lotfi B. Emamgholi S. T. Bahrami E. poorakbar Synthesis and Application of Bis[1,2-(4-aryl-2-alkyl-1H- inden-1-yl)]Ethane as an Efficient`Ligand for Preparation of Olefin Polymerization Catalysts Journal of Sciences, Islamic Republic of Iran organometallic compound metallocene bis-arylalkyl ethane ligand catalysis |
| title | Synthesis and Application of Bis[1,2-(4-aryl-2-alkyl-1H- inden-1-yl)]Ethane as an Efficient`Ligand for Preparation of Olefin Polymerization Catalysts |
| title_full | Synthesis and Application of Bis[1,2-(4-aryl-2-alkyl-1H- inden-1-yl)]Ethane as an Efficient`Ligand for Preparation of Olefin Polymerization Catalysts |
| title_fullStr | Synthesis and Application of Bis[1,2-(4-aryl-2-alkyl-1H- inden-1-yl)]Ethane as an Efficient`Ligand for Preparation of Olefin Polymerization Catalysts |
| title_full_unstemmed | Synthesis and Application of Bis[1,2-(4-aryl-2-alkyl-1H- inden-1-yl)]Ethane as an Efficient`Ligand for Preparation of Olefin Polymerization Catalysts |
| title_short | Synthesis and Application of Bis[1,2-(4-aryl-2-alkyl-1H- inden-1-yl)]Ethane as an Efficient`Ligand for Preparation of Olefin Polymerization Catalysts |
| title_sort | synthesis and application of bis 1 2 4 aryl 2 alkyl 1h inden 1 yl ethane as an efficient ligand for preparation of olefin polymerization catalysts |
| topic | organometallic compound metallocene bis-arylalkyl ethane ligand catalysis |
| url | https://jsciences.ut.ac.ir/article_71749_b93b48fa58d212e0abfc55b6fe67d295.pdf |
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