Thermodynamic properties of the liquid Hg-Tl alloys determined from vapour pressure measurements
The partial vapour pressure of mercury over liquid Hg-Tl liquid solutions were determined in the temperature range from 450 to 700 K by direct vapour pressure measurements carried out with the quartz gauge. From the measured ln pHg vs. T relationships activities of mercury were determined. Using Red...
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| Format: | Article |
| Language: | English |
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University of Belgrade, Technical Faculty, Bor
2002-01-01
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| Series: | Journal of Mining and Metallurgy. Section B: Metallurgy |
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| Online Access: | http://www.doiserbia.nb.rs/img/doi/1450-5339/2002/1450-53390204237G.pdf |
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| author | Gierlotka W. Fitzner K. Sukiennik M. |
| author_facet | Gierlotka W. Fitzner K. Sukiennik M. |
| author_sort | Gierlotka W. |
| collection | DOAJ |
| description | The partial vapour pressure of mercury over liquid Hg-Tl liquid solutions were determined in the temperature range from 450 to 700 K by direct vapour pressure measurements carried out with the quartz gauge. From the measured ln pHg vs. T relationships activities of mercury were determined. Using Redlich-Kister formulas logarithms of the activity coefficients were described with the following equations: From which all thermodynamic functions in the solutions can be derived. |
| format | Article |
| id | doaj-art-2d20957a8ac4429cb50343ba0f020ca8 |
| institution | Kabale University |
| issn | 1450-5339 |
| language | English |
| publishDate | 2002-01-01 |
| publisher | University of Belgrade, Technical Faculty, Bor |
| record_format | Article |
| series | Journal of Mining and Metallurgy. Section B: Metallurgy |
| spelling | doaj-art-2d20957a8ac4429cb50343ba0f020ca82025-02-02T06:18:49ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392002-01-01383-423724710.2298/JMMB0204237GThermodynamic properties of the liquid Hg-Tl alloys determined from vapour pressure measurementsGierlotka W.Fitzner K.Sukiennik M.The partial vapour pressure of mercury over liquid Hg-Tl liquid solutions were determined in the temperature range from 450 to 700 K by direct vapour pressure measurements carried out with the quartz gauge. From the measured ln pHg vs. T relationships activities of mercury were determined. Using Redlich-Kister formulas logarithms of the activity coefficients were described with the following equations: From which all thermodynamic functions in the solutions can be derived.http://www.doiserbia.nb.rs/img/doi/1450-5339/2002/1450-53390204237G.pdfmercurythalliumpressure measurementthermodynamic properties |
| spellingShingle | Gierlotka W. Fitzner K. Sukiennik M. Thermodynamic properties of the liquid Hg-Tl alloys determined from vapour pressure measurements Journal of Mining and Metallurgy. Section B: Metallurgy mercury thallium pressure measurement thermodynamic properties |
| title | Thermodynamic properties of the liquid Hg-Tl alloys determined from vapour pressure measurements |
| title_full | Thermodynamic properties of the liquid Hg-Tl alloys determined from vapour pressure measurements |
| title_fullStr | Thermodynamic properties of the liquid Hg-Tl alloys determined from vapour pressure measurements |
| title_full_unstemmed | Thermodynamic properties of the liquid Hg-Tl alloys determined from vapour pressure measurements |
| title_short | Thermodynamic properties of the liquid Hg-Tl alloys determined from vapour pressure measurements |
| title_sort | thermodynamic properties of the liquid hg tl alloys determined from vapour pressure measurements |
| topic | mercury thallium pressure measurement thermodynamic properties |
| url | http://www.doiserbia.nb.rs/img/doi/1450-5339/2002/1450-53390204237G.pdf |
| work_keys_str_mv | AT gierlotkaw thermodynamicpropertiesoftheliquidhgtlalloysdeterminedfromvapourpressuremeasurements AT fitznerk thermodynamicpropertiesoftheliquidhgtlalloysdeterminedfromvapourpressuremeasurements AT sukiennikm thermodynamicpropertiesoftheliquidhgtlalloysdeterminedfromvapourpressuremeasurements |