Multi-functional enhancement of P(VDF-HFP) nanocomposites through MWCNTs loading for piezoelectric sensing
This study presents the development of flexible piezoelectric nanocomposite films by incorporating multiwalled carbon nanotubes (MWCNTs) into poly(vinylidene fluoride-hexafluoropropylene) [P(VDF-HFP)] via solution casting. The addition of MWCNTs significantly enhanced the electroactive β-phase conte...
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| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2025-05-01
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| Series: | Journal of Materials Research and Technology |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2238785425012669 |
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| Summary: | This study presents the development of flexible piezoelectric nanocomposite films by incorporating multiwalled carbon nanotubes (MWCNTs) into poly(vinylidene fluoride-hexafluoropropylene) [P(VDF-HFP)] via solution casting. The addition of MWCNTs significantly enhanced the electroactive β-phase content, increasing crystallinity from 50.04 % to 54.83 % and tensile strength from 14.56 MPa to 45.13 MPa. Morphological analyses confirmed improved surface roughness and hydrophobicity, with water contact angles rising to 117.07°. Dielectric constant increased nearly fivefold (from 5.5 to 26.2 at 10 Hz), while thermal stability improved with decomposition onset shifting to 468.03 °C. Notably, the composite with 0.75 wt% MWCNTs exhibited the highest piezoelectric sensitivity, achieving a peak voltage output of 16.58 V under mechanical stress. These results demonstrate the strong potential of MWCNTs/P(VDF-HFP) composites for high-performance piezoelectric sensing applications. |
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| ISSN: | 2238-7854 |