Development of Activated Carbon from Cotton Fibre Waste as Potential Mercury Adsorbent: Kinetic and Equilibrium Studies

The study attempted to develop the activated carbon of cotton fibre (ACCF) from cotton waste as a high Hg2+ adsorbent media and characterize physicochemical properties using scanning electron microscopy coupled with energy dispersive spectroscopy (SEM-EDS) and H...

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Main Authors: Jatindra N. Bhakta, Piyali Bhakta Majumdar, Yukihiro Munekage
Format: Article
Language:English
Published: Wiley 2014-01-01
Series:International Journal of Chemical Engineering
Online Access:http://dx.doi.org/10.1155/2014/176483
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author Jatindra N. Bhakta
Piyali Bhakta Majumdar
Yukihiro Munekage
author_facet Jatindra N. Bhakta
Piyali Bhakta Majumdar
Yukihiro Munekage
author_sort Jatindra N. Bhakta
collection DOAJ
description The study attempted to develop the activated carbon of cotton fibre (ACCF) from cotton waste as a high Hg2+ adsorbent media and characterize physicochemical properties using scanning electron microscopy coupled with energy dispersive spectroscopy (SEM-EDS) and Hg2+ adsorption kinetic by batch adsorption study with the function of contact time, solution pH, dosages of ACCF, and Hg concentration. The SEM-EDS study revealed that ACCF is composed of carbon (95.1%) and phosphorus pentoxide (4.9%). Obtained results of adsorption kinetics showed that 15 min of contact time is required to achieve the equilibrium state and wide range of pH (4.08–7) is favourable for maximum Hg adsorption. The Hg2+ adsorption capacity showed a decreasing trend with increasing dose of ACCF, whereas a reverse response of adsorption capacity was pronounced with increasing Hg concentration. The data was well described by Freundlich isotherm model and determined the high Hg2+ adsorption capacity of ACCF (169.2 mg/g). To our knowledge, the application of ACCF in removing Hg2+ is the first study. High Hg2+ adsorption capacity, economic feasibility, availability of cotton fibre waste, and simple preparation method concluded that it could be used as a novel low-cost and environmentally sound adsorbent media for removing high rate of Hg2+ from aqueous phase.
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issn 1687-806X
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publisher Wiley
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series International Journal of Chemical Engineering
spelling doaj-art-2cb5f67d72234690afa2182bbaa12cf42025-08-20T02:24:18ZengWileyInternational Journal of Chemical Engineering1687-806X1687-80782014-01-01201410.1155/2014/176483176483Development of Activated Carbon from Cotton Fibre Waste as Potential Mercury Adsorbent: Kinetic and Equilibrium StudiesJatindra N. Bhakta0Piyali Bhakta Majumdar1Yukihiro Munekage2International Centre for Ecological Engineering, University of Kalyani, Kalyani, West Bengal 741 235, IndiaDepartment of Environmental Engineering, Faculty of Agriculture, Kochi University, B200, Monobe, Nankoku, Kochi 783-8502, JapanDepartment of Environmental Engineering, Faculty of Agriculture, Kochi University, B200, Monobe, Nankoku, Kochi 783-8502, JapanThe study attempted to develop the activated carbon of cotton fibre (ACCF) from cotton waste as a high Hg2+ adsorbent media and characterize physicochemical properties using scanning electron microscopy coupled with energy dispersive spectroscopy (SEM-EDS) and Hg2+ adsorption kinetic by batch adsorption study with the function of contact time, solution pH, dosages of ACCF, and Hg concentration. The SEM-EDS study revealed that ACCF is composed of carbon (95.1%) and phosphorus pentoxide (4.9%). Obtained results of adsorption kinetics showed that 15 min of contact time is required to achieve the equilibrium state and wide range of pH (4.08–7) is favourable for maximum Hg adsorption. The Hg2+ adsorption capacity showed a decreasing trend with increasing dose of ACCF, whereas a reverse response of adsorption capacity was pronounced with increasing Hg concentration. The data was well described by Freundlich isotherm model and determined the high Hg2+ adsorption capacity of ACCF (169.2 mg/g). To our knowledge, the application of ACCF in removing Hg2+ is the first study. High Hg2+ adsorption capacity, economic feasibility, availability of cotton fibre waste, and simple preparation method concluded that it could be used as a novel low-cost and environmentally sound adsorbent media for removing high rate of Hg2+ from aqueous phase.http://dx.doi.org/10.1155/2014/176483
spellingShingle Jatindra N. Bhakta
Piyali Bhakta Majumdar
Yukihiro Munekage
Development of Activated Carbon from Cotton Fibre Waste as Potential Mercury Adsorbent: Kinetic and Equilibrium Studies
International Journal of Chemical Engineering
title Development of Activated Carbon from Cotton Fibre Waste as Potential Mercury Adsorbent: Kinetic and Equilibrium Studies
title_full Development of Activated Carbon from Cotton Fibre Waste as Potential Mercury Adsorbent: Kinetic and Equilibrium Studies
title_fullStr Development of Activated Carbon from Cotton Fibre Waste as Potential Mercury Adsorbent: Kinetic and Equilibrium Studies
title_full_unstemmed Development of Activated Carbon from Cotton Fibre Waste as Potential Mercury Adsorbent: Kinetic and Equilibrium Studies
title_short Development of Activated Carbon from Cotton Fibre Waste as Potential Mercury Adsorbent: Kinetic and Equilibrium Studies
title_sort development of activated carbon from cotton fibre waste as potential mercury adsorbent kinetic and equilibrium studies
url http://dx.doi.org/10.1155/2014/176483
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AT piyalibhaktamajumdar developmentofactivatedcarbonfromcottonfibrewasteaspotentialmercuryadsorbentkineticandequilibriumstudies
AT yukihiromunekage developmentofactivatedcarbonfromcottonfibrewasteaspotentialmercuryadsorbentkineticandequilibriumstudies