Studies of Hydrogen Bonding Between N, N-Dimethylacetamide and Primary Alcohols
Hydrogen bonding between N, N-dimethylacetamide (DMA) and alcohols has been studied in carbon tetrachloride solution by an X-band Microwave bench at 936GHz. The dielectric relaxation time (τ) of the binary system are obtained by both Higasi's method and Gopalakrishna method. The most likely ass...
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| Format: | Article |
| Language: | English |
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Wiley
2009-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2009/120362 |
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| author | M. S. Manjunath P. Sivagurunathan J. Sannappa |
| author_facet | M. S. Manjunath P. Sivagurunathan J. Sannappa |
| author_sort | M. S. Manjunath |
| collection | DOAJ |
| description | Hydrogen bonding between N, N-dimethylacetamide (DMA) and alcohols has been studied in carbon tetrachloride solution by an X-band Microwave bench at 936GHz. The dielectric relaxation time (τ) of the binary system are obtained by both Higasi's method and Gopalakrishna method. The most likely association complex between alcohol and DMA is 1:1 stoichiometric complex through the hydroxyl group of the alcohol and the carbonyl group of amide. The results show that the interaction between alcohols and amides is 1:1 complex through the free hydroxyl group of the alcohol and the carbonyl group of amide and the alkyl chain-length of both the alcohols and amide plays an important role in the determination of the strength of hydrogen bond (O-H: C=O) formed and suggests that the proton donating ability of alcohols is in the order: 1-propanol < 1-butanol < 1-pentanol and the accepting ability of DMA. |
| format | Article |
| id | doaj-art-2c94528592b0449e87bb4fa76ff591cb |
| institution | OA Journals |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2009-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-2c94528592b0449e87bb4fa76ff591cb2025-08-20T02:24:04ZengWileyE-Journal of Chemistry0973-49452090-98102009-01-016S1S143S14610.1155/2009/120362Studies of Hydrogen Bonding Between N, N-Dimethylacetamide and Primary AlcoholsM. S. Manjunath0P. Sivagurunathan1J. Sannappa2Department of Physics, Yuvaraja's College, University of Mysore, Mysore, Karnataka, IndiaDepartment of physics, Annamalai University, Annamalai Nagar, Tamilnadu-608002, IndiaDepartment of Physics, Yuvaraja's College, University of Mysore, Mysore, Karnataka, IndiaHydrogen bonding between N, N-dimethylacetamide (DMA) and alcohols has been studied in carbon tetrachloride solution by an X-band Microwave bench at 936GHz. The dielectric relaxation time (τ) of the binary system are obtained by both Higasi's method and Gopalakrishna method. The most likely association complex between alcohol and DMA is 1:1 stoichiometric complex through the hydroxyl group of the alcohol and the carbonyl group of amide. The results show that the interaction between alcohols and amides is 1:1 complex through the free hydroxyl group of the alcohol and the carbonyl group of amide and the alkyl chain-length of both the alcohols and amide plays an important role in the determination of the strength of hydrogen bond (O-H: C=O) formed and suggests that the proton donating ability of alcohols is in the order: 1-propanol < 1-butanol < 1-pentanol and the accepting ability of DMA.http://dx.doi.org/10.1155/2009/120362 |
| spellingShingle | M. S. Manjunath P. Sivagurunathan J. Sannappa Studies of Hydrogen Bonding Between N, N-Dimethylacetamide and Primary Alcohols E-Journal of Chemistry |
| title | Studies of Hydrogen Bonding Between N, N-Dimethylacetamide and Primary Alcohols |
| title_full | Studies of Hydrogen Bonding Between N, N-Dimethylacetamide and Primary Alcohols |
| title_fullStr | Studies of Hydrogen Bonding Between N, N-Dimethylacetamide and Primary Alcohols |
| title_full_unstemmed | Studies of Hydrogen Bonding Between N, N-Dimethylacetamide and Primary Alcohols |
| title_short | Studies of Hydrogen Bonding Between N, N-Dimethylacetamide and Primary Alcohols |
| title_sort | studies of hydrogen bonding between n n dimethylacetamide and primary alcohols |
| url | http://dx.doi.org/10.1155/2009/120362 |
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