Surface-bound FXIII enhances deposition and straightness of fibrin fibers

Cross-linked fibrous networks are central to maintaining the structural integrity and functional relevance of many biological and engineered materials. Fibrin networks are the building blocks of blood clots, mediators of tissue injury and repair, and synthetic wound sealants. Cross-linking of fibrin...

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Main Authors: Myra Awan, Maya Papez, Ankita P. Walvekar, Sang-Joon J. Lee, Kinjal Dasbiswas, Anand K. Ramasubramanian
Format: Article
Language:English
Published: Elsevier 2025-06-01
Series:Biophysical Reports
Online Access:http://www.sciencedirect.com/science/article/pii/S2667074725000126
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author Myra Awan
Maya Papez
Ankita P. Walvekar
Sang-Joon J. Lee
Kinjal Dasbiswas
Anand K. Ramasubramanian
author_facet Myra Awan
Maya Papez
Ankita P. Walvekar
Sang-Joon J. Lee
Kinjal Dasbiswas
Anand K. Ramasubramanian
author_sort Myra Awan
collection DOAJ
description Cross-linked fibrous networks are central to maintaining the structural integrity and functional relevance of many biological and engineered materials. Fibrin networks are the building blocks of blood clots, mediators of tissue injury and repair, and synthetic wound sealants. Cross-linking of fibrin fibers is catalyzed by the activated form of transglutaminase enzyme FXIIIa, which becomes available in plasma but is also readily presented on the surface of activated platelets and macrophages. The contribution of surface-bound FXIIIa to fibrin structure has not been well understood. In this work, we investigated the role of surface-bound FXIIIa on the formation and structure of fibrin fibers from FXIII-deficient plasma by confining the cross-linking reactions to the surface of microspheres. Quantitative microscopy revealed that cross-linking on FXIIIa-coated surfaces facilitates fibrin deposition following a sigmoidal kinetics, and that these fibers were straighter, longer, and more numerous compared with uncross-linked fibers bound to surfaces coated with anti-fibrin antibody. Our results suggest that, by modifying local fibrin density and structure, surface-bound FXIIIa may play a significant role in the mechanobiology of hemostasis and inflammation.
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issn 2667-0747
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publishDate 2025-06-01
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spelling doaj-art-2c92fef4f7c8469693a8958fd7f530a82025-08-20T03:07:58ZengElsevierBiophysical Reports2667-07472025-06-015210020710.1016/j.bpr.2025.100207Surface-bound FXIII enhances deposition and straightness of fibrin fibersMyra Awan0Maya Papez1Ankita P. Walvekar2Sang-Joon J. Lee3Kinjal Dasbiswas4Anand K. Ramasubramanian5Department of Chemical and Materials Engineering, San José State University, San José, CaliforniaDepartment of Chemical and Materials Engineering, San José State University, San José, CaliforniaDepartment of Chemical and Materials Engineering, San José State University, San José, CaliforniaDepartment of Mechanical Engineering, San José State University, San José, CaliforniaDepartment of Physics, University of California, Merced, Merced, CaliforniaDepartment of Chemical and Materials Engineering, San José State University, San José, California; Corresponding authorCross-linked fibrous networks are central to maintaining the structural integrity and functional relevance of many biological and engineered materials. Fibrin networks are the building blocks of blood clots, mediators of tissue injury and repair, and synthetic wound sealants. Cross-linking of fibrin fibers is catalyzed by the activated form of transglutaminase enzyme FXIIIa, which becomes available in plasma but is also readily presented on the surface of activated platelets and macrophages. The contribution of surface-bound FXIIIa to fibrin structure has not been well understood. In this work, we investigated the role of surface-bound FXIIIa on the formation and structure of fibrin fibers from FXIII-deficient plasma by confining the cross-linking reactions to the surface of microspheres. Quantitative microscopy revealed that cross-linking on FXIIIa-coated surfaces facilitates fibrin deposition following a sigmoidal kinetics, and that these fibers were straighter, longer, and more numerous compared with uncross-linked fibers bound to surfaces coated with anti-fibrin antibody. Our results suggest that, by modifying local fibrin density and structure, surface-bound FXIIIa may play a significant role in the mechanobiology of hemostasis and inflammation.http://www.sciencedirect.com/science/article/pii/S2667074725000126
spellingShingle Myra Awan
Maya Papez
Ankita P. Walvekar
Sang-Joon J. Lee
Kinjal Dasbiswas
Anand K. Ramasubramanian
Surface-bound FXIII enhances deposition and straightness of fibrin fibers
Biophysical Reports
title Surface-bound FXIII enhances deposition and straightness of fibrin fibers
title_full Surface-bound FXIII enhances deposition and straightness of fibrin fibers
title_fullStr Surface-bound FXIII enhances deposition and straightness of fibrin fibers
title_full_unstemmed Surface-bound FXIII enhances deposition and straightness of fibrin fibers
title_short Surface-bound FXIII enhances deposition and straightness of fibrin fibers
title_sort surface bound fxiii enhances deposition and straightness of fibrin fibers
url http://www.sciencedirect.com/science/article/pii/S2667074725000126
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