Bifunctional nanoprobe for simultaneous detection of intracellular reactive oxygen species and temperature in single cells

Abstract Living cells can rapidly adjust their metabolic activities in response to external stimuli, leading to fluctuations in intracellular temperature and reactive oxygen species (ROS) levels. Monitoring these parameters is essential for understanding cellular metabolism, particularly during dyna...

Full description

Saved in:
Bibliographic Details
Main Authors: Yanmei Ma, Weikang Hu, Jian Hu, Muyang Ruan, Jie Hu, Ming Yang, Yi Zhang, Hanhan Xie, Chengzhi Hu
Format: Article
Language:English
Published: Nature Publishing Group 2024-11-01
Series:Microsystems & Nanoengineering
Online Access:https://doi.org/10.1038/s41378-024-00814-1
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1849221138440257536
author Yanmei Ma
Weikang Hu
Jian Hu
Muyang Ruan
Jie Hu
Ming Yang
Yi Zhang
Hanhan Xie
Chengzhi Hu
author_facet Yanmei Ma
Weikang Hu
Jian Hu
Muyang Ruan
Jie Hu
Ming Yang
Yi Zhang
Hanhan Xie
Chengzhi Hu
author_sort Yanmei Ma
collection DOAJ
description Abstract Living cells can rapidly adjust their metabolic activities in response to external stimuli, leading to fluctuations in intracellular temperature and reactive oxygen species (ROS) levels. Monitoring these parameters is essential for understanding cellular metabolism, particularly during dynamic biological processes. In this study, we present a bifunctional nanoprobe capable of simultaneous measurement of ROS levels and temperature within single cells. The nanoprobe features two individually addressable nanoelectrodes, with platinum (Pt) and nickel (Ni) coatings on both sides. At the tip, these two metal layers form a nano-thermocouple, enabling precise intracellular temperature measurements, while the Pt layer facilitates selective ROS detection. This dual functionality allows for real-time monitoring of cellular responses during synergistic chemo-photothermal therapy of cancer cells and zebrafish embryos subjected to mitochondrial toxic stress. Our results demonstrate that the nanoprobe effectively measures increases in temperature and ROS levels in HeLa cells undergoing chemo-photothermal therapy, as well as in chemically stimulated zebrafish embryos. By providing detailed analysis of submicrometer-scale temperature and ROS variations within living cells, this nanoprobe offers valuable insights into cellular processes and holds promise for early disease detection and drug development.
format Article
id doaj-art-2c8a0857465e40328554569c50ca3329
institution Kabale University
issn 2055-7434
language English
publishDate 2024-11-01
publisher Nature Publishing Group
record_format Article
series Microsystems & Nanoengineering
spelling doaj-art-2c8a0857465e40328554569c50ca33292024-11-24T12:30:18ZengNature Publishing GroupMicrosystems & Nanoengineering2055-74342024-11-0110111210.1038/s41378-024-00814-1Bifunctional nanoprobe for simultaneous detection of intracellular reactive oxygen species and temperature in single cellsYanmei Ma0Weikang Hu1Jian Hu2Muyang Ruan3Jie Hu4Ming Yang5Yi Zhang6Hanhan Xie7Chengzhi Hu8Shenzhen Key Laboratory of Biomimetic Robotics and Intelligent Systems, Department of Mechanical and Energy Engineering, Southern University of Science and TechnologyShenzhen Key Laboratory of Biomimetic Robotics and Intelligent Systems, Department of Mechanical and Energy Engineering, Southern University of Science and TechnologyShenzhen Key Laboratory of Biomimetic Robotics and Intelligent Systems, Department of Mechanical and Energy Engineering, Southern University of Science and TechnologyShenzhen Key Laboratory of Biomimetic Robotics and Intelligent Systems, Department of Mechanical and Energy Engineering, Southern University of Science and TechnologyDepartment of Electrical and Electronic Engineering, Southern University of Science and TechnologyShenzhen Key Laboratory of Biomimetic Robotics and Intelligent Systems, Department of Mechanical and Energy Engineering, Southern University of Science and TechnologyShenzhen Key Laboratory of Biomimetic Robotics and Intelligent Systems, Department of Mechanical and Energy Engineering, Southern University of Science and TechnologyShenzhen Key Laboratory of Biomimetic Robotics and Intelligent Systems, Department of Mechanical and Energy Engineering, Southern University of Science and TechnologyShenzhen Key Laboratory of Biomimetic Robotics and Intelligent Systems, Department of Mechanical and Energy Engineering, Southern University of Science and TechnologyAbstract Living cells can rapidly adjust their metabolic activities in response to external stimuli, leading to fluctuations in intracellular temperature and reactive oxygen species (ROS) levels. Monitoring these parameters is essential for understanding cellular metabolism, particularly during dynamic biological processes. In this study, we present a bifunctional nanoprobe capable of simultaneous measurement of ROS levels and temperature within single cells. The nanoprobe features two individually addressable nanoelectrodes, with platinum (Pt) and nickel (Ni) coatings on both sides. At the tip, these two metal layers form a nano-thermocouple, enabling precise intracellular temperature measurements, while the Pt layer facilitates selective ROS detection. This dual functionality allows for real-time monitoring of cellular responses during synergistic chemo-photothermal therapy of cancer cells and zebrafish embryos subjected to mitochondrial toxic stress. Our results demonstrate that the nanoprobe effectively measures increases in temperature and ROS levels in HeLa cells undergoing chemo-photothermal therapy, as well as in chemically stimulated zebrafish embryos. By providing detailed analysis of submicrometer-scale temperature and ROS variations within living cells, this nanoprobe offers valuable insights into cellular processes and holds promise for early disease detection and drug development.https://doi.org/10.1038/s41378-024-00814-1
spellingShingle Yanmei Ma
Weikang Hu
Jian Hu
Muyang Ruan
Jie Hu
Ming Yang
Yi Zhang
Hanhan Xie
Chengzhi Hu
Bifunctional nanoprobe for simultaneous detection of intracellular reactive oxygen species and temperature in single cells
Microsystems & Nanoengineering
title Bifunctional nanoprobe for simultaneous detection of intracellular reactive oxygen species and temperature in single cells
title_full Bifunctional nanoprobe for simultaneous detection of intracellular reactive oxygen species and temperature in single cells
title_fullStr Bifunctional nanoprobe for simultaneous detection of intracellular reactive oxygen species and temperature in single cells
title_full_unstemmed Bifunctional nanoprobe for simultaneous detection of intracellular reactive oxygen species and temperature in single cells
title_short Bifunctional nanoprobe for simultaneous detection of intracellular reactive oxygen species and temperature in single cells
title_sort bifunctional nanoprobe for simultaneous detection of intracellular reactive oxygen species and temperature in single cells
url https://doi.org/10.1038/s41378-024-00814-1
work_keys_str_mv AT yanmeima bifunctionalnanoprobeforsimultaneousdetectionofintracellularreactiveoxygenspeciesandtemperatureinsinglecells
AT weikanghu bifunctionalnanoprobeforsimultaneousdetectionofintracellularreactiveoxygenspeciesandtemperatureinsinglecells
AT jianhu bifunctionalnanoprobeforsimultaneousdetectionofintracellularreactiveoxygenspeciesandtemperatureinsinglecells
AT muyangruan bifunctionalnanoprobeforsimultaneousdetectionofintracellularreactiveoxygenspeciesandtemperatureinsinglecells
AT jiehu bifunctionalnanoprobeforsimultaneousdetectionofintracellularreactiveoxygenspeciesandtemperatureinsinglecells
AT mingyang bifunctionalnanoprobeforsimultaneousdetectionofintracellularreactiveoxygenspeciesandtemperatureinsinglecells
AT yizhang bifunctionalnanoprobeforsimultaneousdetectionofintracellularreactiveoxygenspeciesandtemperatureinsinglecells
AT hanhanxie bifunctionalnanoprobeforsimultaneousdetectionofintracellularreactiveoxygenspeciesandtemperatureinsinglecells
AT chengzhihu bifunctionalnanoprobeforsimultaneousdetectionofintracellularreactiveoxygenspeciesandtemperatureinsinglecells