Anticandidal activity of Clinopodium chilense essential oil

The antifungal activity of the essential oil of Clinopodium chilense (Benth.) Govaerts was investigated against several strains of Candida spp. including clinical isolates and reference strains. Antifungal efficacy was evaluated by determining minimum inhibitory concentration (MIC) and minimum fungi...

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Main Authors: Iván Montenegro, Constanza Villarroel, Evelyn Muñoz, Karel Mena-Ulecia, Valentina Silva, Alejandro Madrid
Format: Article
Language:English
Published: Frontiers Media S.A. 2025-07-01
Series:Frontiers in Pharmacology
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Online Access:https://www.frontiersin.org/articles/10.3389/fphar.2025.1634250/full
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author Iván Montenegro
Iván Montenegro
Iván Montenegro
Constanza Villarroel
Evelyn Muñoz
Karel Mena-Ulecia
Karel Mena-Ulecia
Valentina Silva
Alejandro Madrid
Alejandro Madrid
author_facet Iván Montenegro
Iván Montenegro
Iván Montenegro
Constanza Villarroel
Evelyn Muñoz
Karel Mena-Ulecia
Karel Mena-Ulecia
Valentina Silva
Alejandro Madrid
Alejandro Madrid
author_sort Iván Montenegro
collection DOAJ
description The antifungal activity of the essential oil of Clinopodium chilense (Benth.) Govaerts was investigated against several strains of Candida spp. including clinical isolates and reference strains. Antifungal efficacy was evaluated by determining minimum inhibitory concentration (MIC) and minimum fungicidal concentration (MFC). The chemical composition of the essential oil, characterized by gas chromatography-mass spectrometry (GC/MS), revealed pulegone (18.5%), thymol (11.0%), and isomenthone (10.0%) as the primary constituents. Clinopodium chilense essential oil (EO) demonstrated broad-spectrum anticandidal activity against all tested Candida spp., with MIC values ranging from 16 to 64 μg/mL and MFC values from 16 to 128 μg/mL. The EO exhibited potent fungicidal activity (MFC/MIC ratio ≤2) against several strains, notably Candida tropicalis (MIC and MFC of 16 μg/mL), and also showed efficacy against C. guilliermondii and C. lusitaniae. Among the major components, thymol generally displayed the lowest MIC values (32–64 μg/mL). Molecular docking studies further suggested thymol as a key contributor to the oil’s antifungal effect, showing strong binding affinities to C. albicans virulence proteins Als9-2 and the enzyme CYP51. Significantly, the essential oil outperformed amphotericin B against all tested clinical isolates. Overall, C. chilense EO exhibits significant fungistatic and fungicidal activity against pathogenic Candida species without affecting normal cell viability. These findings, supported by chemical characterization and in silico analysis of its major components like thymol, highlight its potential as a source of novel natural antifungal agents.
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spelling doaj-art-2c61bb6a06e24296821102c5ed93caee2025-08-20T03:50:26ZengFrontiers Media S.A.Frontiers in Pharmacology1663-98122025-07-011610.3389/fphar.2025.16342501634250Anticandidal activity of Clinopodium chilense essential oilIván Montenegro0Iván Montenegro1Iván Montenegro2Constanza Villarroel3Evelyn Muñoz4Karel Mena-Ulecia5Karel Mena-Ulecia6Valentina Silva7Alejandro Madrid8Alejandro Madrid9Center of Interdisciplinary Biomedical and Engineering Research for Health (MEDING), Escuela de Obstetricia y Puericultura, Facultad de Medicina, Universidad de Valparaíso, Viña del Mar, ChileLaboratorio de Productos Naturales y Síntesis Orgánica (LPNSO), Facultad de Ciencias Naturales y Exactas, Universidad de Playa Ancha, Valparaíso, ChileMillennium Nucleus Bioproducts, Genomics and Environmental Microbiology (BioGEM), Valparaíso, ChileCenter of Interdisciplinary Biomedical and Engineering Research for Health (MEDING), Escuela de Obstetricia y Puericultura, Facultad de Medicina, Universidad de Valparaíso, Viña del Mar, ChileLaboratorio de Productos Naturales y Síntesis Orgánica (LPNSO), Facultad de Ciencias Naturales y Exactas, Universidad de Playa Ancha, Valparaíso, ChileDepartamento de Ciencias Biológicas y Químicas, Facultad de Recursos Naturales, Universidad Católica de Temuco, Temuco, ChileNúcleo de Investigación en Bioproductos y Materiales Avanzados (BIOMA), Vicerectoría de Investigación y Postgtado, Universidad Católica de Temuco, Temuco, ChileLaboratorio de Productos Naturales y Síntesis Orgánica (LPNSO), Facultad de Ciencias Naturales y Exactas, Universidad de Playa Ancha, Valparaíso, ChileLaboratorio de Productos Naturales y Síntesis Orgánica (LPNSO), Facultad de Ciencias Naturales y Exactas, Universidad de Playa Ancha, Valparaíso, ChileMillennium Nucleus Bioproducts, Genomics and Environmental Microbiology (BioGEM), Valparaíso, ChileThe antifungal activity of the essential oil of Clinopodium chilense (Benth.) Govaerts was investigated against several strains of Candida spp. including clinical isolates and reference strains. Antifungal efficacy was evaluated by determining minimum inhibitory concentration (MIC) and minimum fungicidal concentration (MFC). The chemical composition of the essential oil, characterized by gas chromatography-mass spectrometry (GC/MS), revealed pulegone (18.5%), thymol (11.0%), and isomenthone (10.0%) as the primary constituents. Clinopodium chilense essential oil (EO) demonstrated broad-spectrum anticandidal activity against all tested Candida spp., with MIC values ranging from 16 to 64 μg/mL and MFC values from 16 to 128 μg/mL. The EO exhibited potent fungicidal activity (MFC/MIC ratio ≤2) against several strains, notably Candida tropicalis (MIC and MFC of 16 μg/mL), and also showed efficacy against C. guilliermondii and C. lusitaniae. Among the major components, thymol generally displayed the lowest MIC values (32–64 μg/mL). Molecular docking studies further suggested thymol as a key contributor to the oil’s antifungal effect, showing strong binding affinities to C. albicans virulence proteins Als9-2 and the enzyme CYP51. Significantly, the essential oil outperformed amphotericin B against all tested clinical isolates. Overall, C. chilense EO exhibits significant fungistatic and fungicidal activity against pathogenic Candida species without affecting normal cell viability. These findings, supported by chemical characterization and in silico analysis of its major components like thymol, highlight its potential as a source of novel natural antifungal agents.https://www.frontiersin.org/articles/10.3389/fphar.2025.1634250/fullClinopodium chilenseessential oilpulegonethymolCandida spp
spellingShingle Iván Montenegro
Iván Montenegro
Iván Montenegro
Constanza Villarroel
Evelyn Muñoz
Karel Mena-Ulecia
Karel Mena-Ulecia
Valentina Silva
Alejandro Madrid
Alejandro Madrid
Anticandidal activity of Clinopodium chilense essential oil
Frontiers in Pharmacology
Clinopodium chilense
essential oil
pulegone
thymol
Candida spp
title Anticandidal activity of Clinopodium chilense essential oil
title_full Anticandidal activity of Clinopodium chilense essential oil
title_fullStr Anticandidal activity of Clinopodium chilense essential oil
title_full_unstemmed Anticandidal activity of Clinopodium chilense essential oil
title_short Anticandidal activity of Clinopodium chilense essential oil
title_sort anticandidal activity of clinopodium chilense essential oil
topic Clinopodium chilense
essential oil
pulegone
thymol
Candida spp
url https://www.frontiersin.org/articles/10.3389/fphar.2025.1634250/full
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