Synthesis and characterization of mesoporous zinc layered hydroxide-isoprocarb nanocomposite
The ion exchange method was used to intercalate a poor water-soluble insecticide, isoprocarb into zinc layered hydroxide (ZLH). PXRD analysis indicated the successful intercalation with good crystallinity for the resulting nanocomposite, with a basal spacing of 33.1 Å. FTIR analyses showing the rese...
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| Format: | Article |
| Language: | English |
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Springer
2019-05-01
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| Series: | Journal of Saudi Chemical Society |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S1319610318301078 |
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| author | Zuhailimuna Muda Norhayati Hashim Illyas Md Isa Suriani Abu Bakar Noorshida Mohd Ali Mohd Zobir Hussein Mazidah Mamat Siti Munirah Sidik |
| author_facet | Zuhailimuna Muda Norhayati Hashim Illyas Md Isa Suriani Abu Bakar Noorshida Mohd Ali Mohd Zobir Hussein Mazidah Mamat Siti Munirah Sidik |
| author_sort | Zuhailimuna Muda |
| collection | DOAJ |
| description | The ion exchange method was used to intercalate a poor water-soluble insecticide, isoprocarb into zinc layered hydroxide (ZLH). PXRD analysis indicated the successful intercalation with good crystallinity for the resulting nanocomposite, with a basal spacing of 33.1 Å. FTIR analyses showing the resemblance of an absorption peak of the nanocomposite with the host and the guest anion. The thermal analysis confirmed that the nanocomposite had better thermal stability compared to the pristine isoprocarb. The nanocomposite also characterized by elemental and surface morphology analysis. The surface analyses of the host and nanocomposite showed mesoporous-type material characteristics. On the whole, the intercalation process decreased the pore size of the nanocomposite compared to the pristine host, layered zinc layered hydroxide-sodium dodecyl sulphate (ZLH-SDS). The obtained material is believed has a great potential as an environmentally friendly insecticide. Keywords: Intercalation, Characterization, Zinc layered hydroxide, Isoprocarb, Mesoporous |
| format | Article |
| id | doaj-art-2bbc0d14006b49edbb7e9f0fc5eecfdf |
| institution | Kabale University |
| issn | 1319-6103 |
| language | English |
| publishDate | 2019-05-01 |
| publisher | Springer |
| record_format | Article |
| series | Journal of Saudi Chemical Society |
| spelling | doaj-art-2bbc0d14006b49edbb7e9f0fc5eecfdf2025-08-20T03:54:56ZengSpringerJournal of Saudi Chemical Society1319-61032019-05-0123448649310.1016/j.jscs.2018.08.012Synthesis and characterization of mesoporous zinc layered hydroxide-isoprocarb nanocompositeZuhailimuna Muda0Norhayati Hashim1Illyas Md Isa2Suriani Abu Bakar3Noorshida Mohd Ali4Mohd Zobir Hussein5Mazidah Mamat6Siti Munirah Sidik7Department of Chemistry, Faculty of Science and Mathematics, Universiti Pendidikan Sultan Idris, 35900 Tanjong Malim, Perak, MalaysiaDepartment of Chemistry, Faculty of Science and Mathematics, Universiti Pendidikan Sultan Idris, 35900 Tanjong Malim, Perak, Malaysia; Nanotechnology Research Centre, Faculty of Science and Mathematics, Universiti Pendidikan Sultan Idris, 35900 Tanjong Malim, Perak, Malaysia; Corresponding author at: Department of Chemistry, Faculty of Science and Mathematics, Universiti Pendidikan Sultan Idris, 35900 Tanjong Malim, Perak, Malaysia.Department of Chemistry, Faculty of Science and Mathematics, Universiti Pendidikan Sultan Idris, 35900 Tanjong Malim, Perak, Malaysia; Nanotechnology Research Centre, Faculty of Science and Mathematics, Universiti Pendidikan Sultan Idris, 35900 Tanjong Malim, Perak, MalaysiaNanotechnology Research Centre, Faculty of Science and Mathematics, Universiti Pendidikan Sultan Idris, 35900 Tanjong Malim, Perak, Malaysia; Department of Physics, Faculty of Science and Mathematics, Universiti Pendidikan Sultan Idris, 35900 Tanjong Malim, Perak, MalaysiaDepartment of Chemistry, Faculty of Science and Mathematics, Universiti Pendidikan Sultan Idris, 35900 Tanjong Malim, Perak, MalaysiaMaterials Synthesis and Characterization Laboratory, Institute of Advanced Technology, Universiti Putra Malaysia, 43400 Serdang, Selangor, MalaysiaPusat Pengajian Sains Asas, Universiti Malaysia Terengganu, 21030 Kuala Terengganu, Terengganu, MalaysiaDepartment of Chemistry, Faculty of Science and Mathematics, Universiti Pendidikan Sultan Idris, 35900 Tanjong Malim, Perak, MalaysiaThe ion exchange method was used to intercalate a poor water-soluble insecticide, isoprocarb into zinc layered hydroxide (ZLH). PXRD analysis indicated the successful intercalation with good crystallinity for the resulting nanocomposite, with a basal spacing of 33.1 Å. FTIR analyses showing the resemblance of an absorption peak of the nanocomposite with the host and the guest anion. The thermal analysis confirmed that the nanocomposite had better thermal stability compared to the pristine isoprocarb. The nanocomposite also characterized by elemental and surface morphology analysis. The surface analyses of the host and nanocomposite showed mesoporous-type material characteristics. On the whole, the intercalation process decreased the pore size of the nanocomposite compared to the pristine host, layered zinc layered hydroxide-sodium dodecyl sulphate (ZLH-SDS). The obtained material is believed has a great potential as an environmentally friendly insecticide. Keywords: Intercalation, Characterization, Zinc layered hydroxide, Isoprocarb, Mesoporoushttp://www.sciencedirect.com/science/article/pii/S1319610318301078 |
| spellingShingle | Zuhailimuna Muda Norhayati Hashim Illyas Md Isa Suriani Abu Bakar Noorshida Mohd Ali Mohd Zobir Hussein Mazidah Mamat Siti Munirah Sidik Synthesis and characterization of mesoporous zinc layered hydroxide-isoprocarb nanocomposite Journal of Saudi Chemical Society |
| title | Synthesis and characterization of mesoporous zinc layered hydroxide-isoprocarb nanocomposite |
| title_full | Synthesis and characterization of mesoporous zinc layered hydroxide-isoprocarb nanocomposite |
| title_fullStr | Synthesis and characterization of mesoporous zinc layered hydroxide-isoprocarb nanocomposite |
| title_full_unstemmed | Synthesis and characterization of mesoporous zinc layered hydroxide-isoprocarb nanocomposite |
| title_short | Synthesis and characterization of mesoporous zinc layered hydroxide-isoprocarb nanocomposite |
| title_sort | synthesis and characterization of mesoporous zinc layered hydroxide isoprocarb nanocomposite |
| url | http://www.sciencedirect.com/science/article/pii/S1319610318301078 |
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