Extraction of Phosphate from Polluted Waters Using Calcium Alginate Beads Doped with Active Carbon Derived from A. aspera Plant as Adsorbent

An adsorbent prepared by entrapping active carbon derived from the stems of Achyranthes aspera plant in the calcium alginate beads (CABAA) has been investigated for its adsorption nature towards the removal of phosphate by varying various physicochemical parameters. Surface morphological studies are...

Full description

Saved in:
Bibliographic Details
Main Authors: Ravulapalli Sujitha, Kunta Ravindhranath
Format: Article
Language:English
Published: Wiley 2017-01-01
Series:Journal of Analytical Methods in Chemistry
Online Access:http://dx.doi.org/10.1155/2017/3610878
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1832564317431529472
author Ravulapalli Sujitha
Kunta Ravindhranath
author_facet Ravulapalli Sujitha
Kunta Ravindhranath
author_sort Ravulapalli Sujitha
collection DOAJ
description An adsorbent prepared by entrapping active carbon derived from the stems of Achyranthes aspera plant in the calcium alginate beads (CABAA) has been investigated for its adsorption nature towards the removal of phosphate by varying various physicochemical parameters. Surface morphological studies are made using FTIR, XRD, FESEM, and EDX. The sorption mechanism is analyzed using Freundlich, Langmuir, Dubinin-Radushkevich, and Temkin adsorption isotherms. The adsorption kinetics is found to follow the pseudo-second-order model. Thermodynamic parameters are analyzed and found that the adsorption is endothermic and nonspontaneous in nature. The maximum amount of phosphate adsorbed onto CABAA is found to be 133.3 mg/g of active carbon and, furthermore, the adsorbent is highly selective. The methodology developed is successfully applied to polluted water samples.
format Article
id doaj-art-2ba9f04686fd47349aecb4950f3c3df8
institution Kabale University
issn 2090-8865
2090-8873
language English
publishDate 2017-01-01
publisher Wiley
record_format Article
series Journal of Analytical Methods in Chemistry
spelling doaj-art-2ba9f04686fd47349aecb4950f3c3df82025-02-03T01:11:20ZengWileyJournal of Analytical Methods in Chemistry2090-88652090-88732017-01-01201710.1155/2017/36108783610878Extraction of Phosphate from Polluted Waters Using Calcium Alginate Beads Doped with Active Carbon Derived from A. aspera Plant as AdsorbentRavulapalli Sujitha0Kunta Ravindhranath1Department of Chemistry, K L University, Green Fields, Vaddeswaram, Guntur District 522 502, IndiaDepartment of Chemistry, K L University, Green Fields, Vaddeswaram, Guntur District 522 502, IndiaAn adsorbent prepared by entrapping active carbon derived from the stems of Achyranthes aspera plant in the calcium alginate beads (CABAA) has been investigated for its adsorption nature towards the removal of phosphate by varying various physicochemical parameters. Surface morphological studies are made using FTIR, XRD, FESEM, and EDX. The sorption mechanism is analyzed using Freundlich, Langmuir, Dubinin-Radushkevich, and Temkin adsorption isotherms. The adsorption kinetics is found to follow the pseudo-second-order model. Thermodynamic parameters are analyzed and found that the adsorption is endothermic and nonspontaneous in nature. The maximum amount of phosphate adsorbed onto CABAA is found to be 133.3 mg/g of active carbon and, furthermore, the adsorbent is highly selective. The methodology developed is successfully applied to polluted water samples.http://dx.doi.org/10.1155/2017/3610878
spellingShingle Ravulapalli Sujitha
Kunta Ravindhranath
Extraction of Phosphate from Polluted Waters Using Calcium Alginate Beads Doped with Active Carbon Derived from A. aspera Plant as Adsorbent
Journal of Analytical Methods in Chemistry
title Extraction of Phosphate from Polluted Waters Using Calcium Alginate Beads Doped with Active Carbon Derived from A. aspera Plant as Adsorbent
title_full Extraction of Phosphate from Polluted Waters Using Calcium Alginate Beads Doped with Active Carbon Derived from A. aspera Plant as Adsorbent
title_fullStr Extraction of Phosphate from Polluted Waters Using Calcium Alginate Beads Doped with Active Carbon Derived from A. aspera Plant as Adsorbent
title_full_unstemmed Extraction of Phosphate from Polluted Waters Using Calcium Alginate Beads Doped with Active Carbon Derived from A. aspera Plant as Adsorbent
title_short Extraction of Phosphate from Polluted Waters Using Calcium Alginate Beads Doped with Active Carbon Derived from A. aspera Plant as Adsorbent
title_sort extraction of phosphate from polluted waters using calcium alginate beads doped with active carbon derived from a aspera plant as adsorbent
url http://dx.doi.org/10.1155/2017/3610878
work_keys_str_mv AT ravulapallisujitha extractionofphosphatefrompollutedwatersusingcalciumalginatebeadsdopedwithactivecarbonderivedfromaasperaplantasadsorbent
AT kuntaravindhranath extractionofphosphatefrompollutedwatersusingcalciumalginatebeadsdopedwithactivecarbonderivedfromaasperaplantasadsorbent