Extraction of Phosphate from Polluted Waters Using Calcium Alginate Beads Doped with Active Carbon Derived from A. aspera Plant as Adsorbent
An adsorbent prepared by entrapping active carbon derived from the stems of Achyranthes aspera plant in the calcium alginate beads (CABAA) has been investigated for its adsorption nature towards the removal of phosphate by varying various physicochemical parameters. Surface morphological studies are...
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Wiley
2017-01-01
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Series: | Journal of Analytical Methods in Chemistry |
Online Access: | http://dx.doi.org/10.1155/2017/3610878 |
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author | Ravulapalli Sujitha Kunta Ravindhranath |
author_facet | Ravulapalli Sujitha Kunta Ravindhranath |
author_sort | Ravulapalli Sujitha |
collection | DOAJ |
description | An adsorbent prepared by entrapping active carbon derived from the stems of Achyranthes aspera plant in the calcium alginate beads (CABAA) has been investigated for its adsorption nature towards the removal of phosphate by varying various physicochemical parameters. Surface morphological studies are made using FTIR, XRD, FESEM, and EDX. The sorption mechanism is analyzed using Freundlich, Langmuir, Dubinin-Radushkevich, and Temkin adsorption isotherms. The adsorption kinetics is found to follow the pseudo-second-order model. Thermodynamic parameters are analyzed and found that the adsorption is endothermic and nonspontaneous in nature. The maximum amount of phosphate adsorbed onto CABAA is found to be 133.3 mg/g of active carbon and, furthermore, the adsorbent is highly selective. The methodology developed is successfully applied to polluted water samples. |
format | Article |
id | doaj-art-2ba9f04686fd47349aecb4950f3c3df8 |
institution | Kabale University |
issn | 2090-8865 2090-8873 |
language | English |
publishDate | 2017-01-01 |
publisher | Wiley |
record_format | Article |
series | Journal of Analytical Methods in Chemistry |
spelling | doaj-art-2ba9f04686fd47349aecb4950f3c3df82025-02-03T01:11:20ZengWileyJournal of Analytical Methods in Chemistry2090-88652090-88732017-01-01201710.1155/2017/36108783610878Extraction of Phosphate from Polluted Waters Using Calcium Alginate Beads Doped with Active Carbon Derived from A. aspera Plant as AdsorbentRavulapalli Sujitha0Kunta Ravindhranath1Department of Chemistry, K L University, Green Fields, Vaddeswaram, Guntur District 522 502, IndiaDepartment of Chemistry, K L University, Green Fields, Vaddeswaram, Guntur District 522 502, IndiaAn adsorbent prepared by entrapping active carbon derived from the stems of Achyranthes aspera plant in the calcium alginate beads (CABAA) has been investigated for its adsorption nature towards the removal of phosphate by varying various physicochemical parameters. Surface morphological studies are made using FTIR, XRD, FESEM, and EDX. The sorption mechanism is analyzed using Freundlich, Langmuir, Dubinin-Radushkevich, and Temkin adsorption isotherms. The adsorption kinetics is found to follow the pseudo-second-order model. Thermodynamic parameters are analyzed and found that the adsorption is endothermic and nonspontaneous in nature. The maximum amount of phosphate adsorbed onto CABAA is found to be 133.3 mg/g of active carbon and, furthermore, the adsorbent is highly selective. The methodology developed is successfully applied to polluted water samples.http://dx.doi.org/10.1155/2017/3610878 |
spellingShingle | Ravulapalli Sujitha Kunta Ravindhranath Extraction of Phosphate from Polluted Waters Using Calcium Alginate Beads Doped with Active Carbon Derived from A. aspera Plant as Adsorbent Journal of Analytical Methods in Chemistry |
title | Extraction of Phosphate from Polluted Waters Using Calcium Alginate Beads Doped with Active Carbon Derived from A. aspera Plant as Adsorbent |
title_full | Extraction of Phosphate from Polluted Waters Using Calcium Alginate Beads Doped with Active Carbon Derived from A. aspera Plant as Adsorbent |
title_fullStr | Extraction of Phosphate from Polluted Waters Using Calcium Alginate Beads Doped with Active Carbon Derived from A. aspera Plant as Adsorbent |
title_full_unstemmed | Extraction of Phosphate from Polluted Waters Using Calcium Alginate Beads Doped with Active Carbon Derived from A. aspera Plant as Adsorbent |
title_short | Extraction of Phosphate from Polluted Waters Using Calcium Alginate Beads Doped with Active Carbon Derived from A. aspera Plant as Adsorbent |
title_sort | extraction of phosphate from polluted waters using calcium alginate beads doped with active carbon derived from a aspera plant as adsorbent |
url | http://dx.doi.org/10.1155/2017/3610878 |
work_keys_str_mv | AT ravulapallisujitha extractionofphosphatefrompollutedwatersusingcalciumalginatebeadsdopedwithactivecarbonderivedfromaasperaplantasadsorbent AT kuntaravindhranath extractionofphosphatefrompollutedwatersusingcalciumalginatebeadsdopedwithactivecarbonderivedfromaasperaplantasadsorbent |