Physico-chemical characteristics of Composites material Based on Sulfonated Cyclone Fibre Cellulose and Benzotriazole
Composites material based on sulfonated cyclone fibre cellulose (SCFC) and benzotriazole (Btri) have been prepared. Cyclone fibre cellulose (CFC) was sulfonated with trimethylsilyl chlorosulfonate (TMSCS), with high degree of sulfonation (150%). The composites material, SCFC-Btri were prepared by do...
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| Format: | Article |
| Language: | English |
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Syiah Kuala University
2017-08-01
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| Series: | Aceh International Journal of Science and Technology |
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| Online Access: | https://jurnal.usk.ac.id/AIJST/article/view/8438 |
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| author | Irfan Gustian Eka Angasa Ghufira Ghufira |
| author_facet | Irfan Gustian Eka Angasa Ghufira Ghufira |
| author_sort | Irfan Gustian |
| collection | DOAJ |
| description | Composites material based on sulfonated cyclone fibre cellulose (SCFC) and benzotriazole (Btri) have been prepared. Cyclone fibre cellulose (CFC) was sulfonated with trimethylsilyl chlorosulfonate (TMSCS), with high degree of sulfonation (150%). The composites material, SCFC-Btri were prepared by doping of benzotriazole in various mole ratios (0.125, 0.25 and 0.5). FTIR spectrum has confirmed the ionic interaction between sulfonic acid from sulfonated cyclone fibre cellulose and benzotriazole units. Thermogravimetric analysis (TGA) showed that the composites material was thermally stable up to 150 °C. The results showed that methanol permeability of the composite material was lower than pristine Nafion112. Activation energy obtained for the materials are 0. 106 eV, 0.144 eV and 0.137 eV for SCFC-Btri mole ratios 0.125, 0.25 and 0.5 respectively, composites material was expected to be used as raw material in the fuel cell. |
| format | Article |
| id | doaj-art-2b9bd541c5894b0abfacf338f86982bd |
| institution | Kabale University |
| issn | 2088-9860 |
| language | English |
| publishDate | 2017-08-01 |
| publisher | Syiah Kuala University |
| record_format | Article |
| series | Aceh International Journal of Science and Technology |
| spelling | doaj-art-2b9bd541c5894b0abfacf338f86982bd2025-08-20T03:38:39ZengSyiah Kuala UniversityAceh International Journal of Science and Technology2088-98602017-08-0162525810.13170/aijst.6.2.84386739Physico-chemical characteristics of Composites material Based on Sulfonated Cyclone Fibre Cellulose and BenzotriazoleIrfan Gustian0Eka AngasaGhufira GhufiraChemistry Department, Faculty of Mathematics and Natural Sciences Universitas BengkuluComposites material based on sulfonated cyclone fibre cellulose (SCFC) and benzotriazole (Btri) have been prepared. Cyclone fibre cellulose (CFC) was sulfonated with trimethylsilyl chlorosulfonate (TMSCS), with high degree of sulfonation (150%). The composites material, SCFC-Btri were prepared by doping of benzotriazole in various mole ratios (0.125, 0.25 and 0.5). FTIR spectrum has confirmed the ionic interaction between sulfonic acid from sulfonated cyclone fibre cellulose and benzotriazole units. Thermogravimetric analysis (TGA) showed that the composites material was thermally stable up to 150 °C. The results showed that methanol permeability of the composite material was lower than pristine Nafion112. Activation energy obtained for the materials are 0. 106 eV, 0.144 eV and 0.137 eV for SCFC-Btri mole ratios 0.125, 0.25 and 0.5 respectively, composites material was expected to be used as raw material in the fuel cell.https://jurnal.usk.ac.id/AIJST/article/view/8438benzotriazolesulfonationcomposites materialcyclone fibre cellulose |
| spellingShingle | Irfan Gustian Eka Angasa Ghufira Ghufira Physico-chemical characteristics of Composites material Based on Sulfonated Cyclone Fibre Cellulose and Benzotriazole Aceh International Journal of Science and Technology benzotriazole sulfonation composites material cyclone fibre cellulose |
| title | Physico-chemical characteristics of Composites material Based on Sulfonated Cyclone Fibre Cellulose and Benzotriazole |
| title_full | Physico-chemical characteristics of Composites material Based on Sulfonated Cyclone Fibre Cellulose and Benzotriazole |
| title_fullStr | Physico-chemical characteristics of Composites material Based on Sulfonated Cyclone Fibre Cellulose and Benzotriazole |
| title_full_unstemmed | Physico-chemical characteristics of Composites material Based on Sulfonated Cyclone Fibre Cellulose and Benzotriazole |
| title_short | Physico-chemical characteristics of Composites material Based on Sulfonated Cyclone Fibre Cellulose and Benzotriazole |
| title_sort | physico chemical characteristics of composites material based on sulfonated cyclone fibre cellulose and benzotriazole |
| topic | benzotriazole sulfonation composites material cyclone fibre cellulose |
| url | https://jurnal.usk.ac.id/AIJST/article/view/8438 |
| work_keys_str_mv | AT irfangustian physicochemicalcharacteristicsofcompositesmaterialbasedonsulfonatedcyclonefibrecelluloseandbenzotriazole AT ekaangasa physicochemicalcharacteristicsofcompositesmaterialbasedonsulfonatedcyclonefibrecelluloseandbenzotriazole AT ghufiraghufira physicochemicalcharacteristicsofcompositesmaterialbasedonsulfonatedcyclonefibrecelluloseandbenzotriazole |