Effective preparation of low-melting solder materials for atom probe tomography

Abstract Low-melting metal alloys have gained renewed attention for additive manufacturing, energy storage and microelectronics. However, micro- and nanostructure characterisation demands highly sophisticated sample preparation. Here, we optimise the Ga-FIB preparation of atom probe tomography (APT)...

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Main Authors: Charlotte Cui, Michael Tkadletz, Michael Reisinger, Peter Imrich, Walter Hartner, Roland Brunner
Format: Article
Language:English
Published: Nature Portfolio 2024-11-01
Series:Scientific Reports
Online Access:https://doi.org/10.1038/s41598-024-79753-w
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author Charlotte Cui
Michael Tkadletz
Michael Reisinger
Peter Imrich
Walter Hartner
Roland Brunner
author_facet Charlotte Cui
Michael Tkadletz
Michael Reisinger
Peter Imrich
Walter Hartner
Roland Brunner
author_sort Charlotte Cui
collection DOAJ
description Abstract Low-melting metal alloys have gained renewed attention for additive manufacturing, energy storage and microelectronics. However, micro- and nanostructure characterisation demands highly sophisticated sample preparation. Here, we optimise the Ga-FIB preparation of atom probe tomography (APT) specimens for low melting SAC305 solder materials utilising different FESEM/FIB stage temperatures. We study the effects of FESEM/FIB stage temperature on the specimen milling behaviour during Ga-FIB preparation and compare the extent of Ga implantation and precipitate coarsening during the preparation utilising energy dispersive X-ray spectroscopy and APT. We show that cooling the sample to −60 °C during FIB milling utilising a Peltier cooling stage improves the behaviour of the specimen during the final low-keV milling step significantly. We conclude that performing all Ga-FIB-sample interactions at −60 °C with a Pt-protection layer allows for effective and reproducible APT specimen preparation for low-melting alloys, such as SAC305.
format Article
id doaj-art-2b7cac0d20b2404185ef3ca9f438de4b
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issn 2045-2322
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publishDate 2024-11-01
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spelling doaj-art-2b7cac0d20b2404185ef3ca9f438de4b2025-08-20T02:49:17ZengNature PortfolioScientific Reports2045-23222024-11-0114111110.1038/s41598-024-79753-wEffective preparation of low-melting solder materials for atom probe tomographyCharlotte Cui0Michael Tkadletz1Michael Reisinger2Peter Imrich3Walter Hartner4Roland Brunner5Materials Center Leoben Forschung GmbHMontanuniversität Leoben, Chair of Functional Materials at the Department Materials ScienceKompetenzzentrum für Automobil- und Industrieelektronik GmbHKompetenzzentrum für Automobil- und Industrieelektronik GmbHInfineon Technologies AGMaterials Center Leoben Forschung GmbHAbstract Low-melting metal alloys have gained renewed attention for additive manufacturing, energy storage and microelectronics. However, micro- and nanostructure characterisation demands highly sophisticated sample preparation. Here, we optimise the Ga-FIB preparation of atom probe tomography (APT) specimens for low melting SAC305 solder materials utilising different FESEM/FIB stage temperatures. We study the effects of FESEM/FIB stage temperature on the specimen milling behaviour during Ga-FIB preparation and compare the extent of Ga implantation and precipitate coarsening during the preparation utilising energy dispersive X-ray spectroscopy and APT. We show that cooling the sample to −60 °C during FIB milling utilising a Peltier cooling stage improves the behaviour of the specimen during the final low-keV milling step significantly. We conclude that performing all Ga-FIB-sample interactions at −60 °C with a Pt-protection layer allows for effective and reproducible APT specimen preparation for low-melting alloys, such as SAC305.https://doi.org/10.1038/s41598-024-79753-w
spellingShingle Charlotte Cui
Michael Tkadletz
Michael Reisinger
Peter Imrich
Walter Hartner
Roland Brunner
Effective preparation of low-melting solder materials for atom probe tomography
Scientific Reports
title Effective preparation of low-melting solder materials for atom probe tomography
title_full Effective preparation of low-melting solder materials for atom probe tomography
title_fullStr Effective preparation of low-melting solder materials for atom probe tomography
title_full_unstemmed Effective preparation of low-melting solder materials for atom probe tomography
title_short Effective preparation of low-melting solder materials for atom probe tomography
title_sort effective preparation of low melting solder materials for atom probe tomography
url https://doi.org/10.1038/s41598-024-79753-w
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