Construction of pH-Sensitive Multifunctional Hydrogel with Synergistic Anti-Inflammatory Effect for Treatment of Diabetic Wounds

<b>Background/Objectives:</b> A sustainable inflammatory response is a significant obstacle for diabetic wound care. In this study, the pH-sensitive multifunctional hydrogel ODex/BSA-Zn was fabricated via a Schiff base and coordination force for the first time. <b>Methods:</b>...

Full description

Saved in:
Bibliographic Details
Main Authors: Xiaoyan Sun, Yan Li, Haifeng Wang, Yanqiu Meng, Xu Dai, Lina Du, Lei Li
Format: Article
Language:English
Published: MDPI AG 2025-05-01
Series:Pharmaceutics
Subjects:
Online Access:https://www.mdpi.com/1999-4923/17/5/644
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1850126539241291776
author Xiaoyan Sun
Yan Li
Haifeng Wang
Yanqiu Meng
Xu Dai
Lina Du
Lei Li
author_facet Xiaoyan Sun
Yan Li
Haifeng Wang
Yanqiu Meng
Xu Dai
Lina Du
Lei Li
author_sort Xiaoyan Sun
collection DOAJ
description <b>Background/Objectives:</b> A sustainable inflammatory response is a significant obstacle for diabetic wound care. In this study, the pH-sensitive multifunctional hydrogel ODex/BSA-Zn was fabricated via a Schiff base and coordination force for the first time. <b>Methods:</b> The hydrogel consisted of oxidized dextran (ODex), bovine serum albumin (BSA), and zinc ions (Zn<sup>2+</sup>) in the absence of an additional crosslinking agent. <b>Results:</b> The hydrogel showed excellent mechanical stability, fast self-healing ability, and significant anti-inflammatory effects, as demonstrated by the formation of dynamic covalent bonds between the aldehyde group (-CHO) of ODex and the amino group (-NH<sub>2</sub>) of BSA via the Schiff base reaction, as well as the metal-ion coordination reaction of Zn<sup>2+</sup> with the imidazole ring of BSA. In a diabetic mouse full-thickness cutaneous defect wound model, the ODex/BSA-Zn hydrogel could effectively inhibit the inflammatory response and increase collagen deposition, thereby accelerating the transition of macrophage M1 to M2 and promoting wound closure. This study offers a promising therapeutic approach for managing long-term diabetic ulcers.
format Article
id doaj-art-2b5863ac25ce4e5ab45c74c3b6087c99
institution OA Journals
issn 1999-4923
language English
publishDate 2025-05-01
publisher MDPI AG
record_format Article
series Pharmaceutics
spelling doaj-art-2b5863ac25ce4e5ab45c74c3b6087c992025-08-20T02:33:55ZengMDPI AGPharmaceutics1999-49232025-05-0117564410.3390/pharmaceutics17050644Construction of pH-Sensitive Multifunctional Hydrogel with Synergistic Anti-Inflammatory Effect for Treatment of Diabetic WoundsXiaoyan Sun0Yan Li1Haifeng Wang2Yanqiu Meng3Xu Dai4Lina Du5Lei Li6College of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang 110142, ChinaCollege of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang 110142, ChinaCollege of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang 110142, ChinaCollege of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang 110142, ChinaCollege of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang 110142, ChinaCollege of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang 110142, ChinaCollege of Chemical Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China<b>Background/Objectives:</b> A sustainable inflammatory response is a significant obstacle for diabetic wound care. In this study, the pH-sensitive multifunctional hydrogel ODex/BSA-Zn was fabricated via a Schiff base and coordination force for the first time. <b>Methods:</b> The hydrogel consisted of oxidized dextran (ODex), bovine serum albumin (BSA), and zinc ions (Zn<sup>2+</sup>) in the absence of an additional crosslinking agent. <b>Results:</b> The hydrogel showed excellent mechanical stability, fast self-healing ability, and significant anti-inflammatory effects, as demonstrated by the formation of dynamic covalent bonds between the aldehyde group (-CHO) of ODex and the amino group (-NH<sub>2</sub>) of BSA via the Schiff base reaction, as well as the metal-ion coordination reaction of Zn<sup>2+</sup> with the imidazole ring of BSA. In a diabetic mouse full-thickness cutaneous defect wound model, the ODex/BSA-Zn hydrogel could effectively inhibit the inflammatory response and increase collagen deposition, thereby accelerating the transition of macrophage M1 to M2 and promoting wound closure. This study offers a promising therapeutic approach for managing long-term diabetic ulcers.https://www.mdpi.com/1999-4923/17/5/644diabetic woundsmacrophageshydrogelself-healinganti-inflammatory
spellingShingle Xiaoyan Sun
Yan Li
Haifeng Wang
Yanqiu Meng
Xu Dai
Lina Du
Lei Li
Construction of pH-Sensitive Multifunctional Hydrogel with Synergistic Anti-Inflammatory Effect for Treatment of Diabetic Wounds
Pharmaceutics
diabetic wounds
macrophages
hydrogel
self-healing
anti-inflammatory
title Construction of pH-Sensitive Multifunctional Hydrogel with Synergistic Anti-Inflammatory Effect for Treatment of Diabetic Wounds
title_full Construction of pH-Sensitive Multifunctional Hydrogel with Synergistic Anti-Inflammatory Effect for Treatment of Diabetic Wounds
title_fullStr Construction of pH-Sensitive Multifunctional Hydrogel with Synergistic Anti-Inflammatory Effect for Treatment of Diabetic Wounds
title_full_unstemmed Construction of pH-Sensitive Multifunctional Hydrogel with Synergistic Anti-Inflammatory Effect for Treatment of Diabetic Wounds
title_short Construction of pH-Sensitive Multifunctional Hydrogel with Synergistic Anti-Inflammatory Effect for Treatment of Diabetic Wounds
title_sort construction of ph sensitive multifunctional hydrogel with synergistic anti inflammatory effect for treatment of diabetic wounds
topic diabetic wounds
macrophages
hydrogel
self-healing
anti-inflammatory
url https://www.mdpi.com/1999-4923/17/5/644
work_keys_str_mv AT xiaoyansun constructionofphsensitivemultifunctionalhydrogelwithsynergisticantiinflammatoryeffectfortreatmentofdiabeticwounds
AT yanli constructionofphsensitivemultifunctionalhydrogelwithsynergisticantiinflammatoryeffectfortreatmentofdiabeticwounds
AT haifengwang constructionofphsensitivemultifunctionalhydrogelwithsynergisticantiinflammatoryeffectfortreatmentofdiabeticwounds
AT yanqiumeng constructionofphsensitivemultifunctionalhydrogelwithsynergisticantiinflammatoryeffectfortreatmentofdiabeticwounds
AT xudai constructionofphsensitivemultifunctionalhydrogelwithsynergisticantiinflammatoryeffectfortreatmentofdiabeticwounds
AT linadu constructionofphsensitivemultifunctionalhydrogelwithsynergisticantiinflammatoryeffectfortreatmentofdiabeticwounds
AT leili constructionofphsensitivemultifunctionalhydrogelwithsynergisticantiinflammatoryeffectfortreatmentofdiabeticwounds