Systematic metabolic engineering of Yarrowia lipolytica for efficient production of phytohormone abscisic acid

Abscisic acid (ABA) is an important phytohormone with diverse applications. It currently relies on the fermentation of Botrytis cinerea, which suffers from limited availability of genetic engineering tools. Here, Yarrowia lipolytica was engineered to enable de novo biosynthesis of ABA. To overcome t...

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Main Authors: Mei-Li Sun, Ziyun Zou, Lu Lin, Rodrigo Ledesma-Amaro, Kaifeng Wang, Xiao-Jun Ji
Format: Article
Language:English
Published: KeAi Communications Co., Ltd. 2025-03-01
Series:Synthetic and Systems Biotechnology
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Online Access:http://www.sciencedirect.com/science/article/pii/S2405805X24001340
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author Mei-Li Sun
Ziyun Zou
Lu Lin
Rodrigo Ledesma-Amaro
Kaifeng Wang
Xiao-Jun Ji
author_facet Mei-Li Sun
Ziyun Zou
Lu Lin
Rodrigo Ledesma-Amaro
Kaifeng Wang
Xiao-Jun Ji
author_sort Mei-Li Sun
collection DOAJ
description Abscisic acid (ABA) is an important phytohormone with diverse applications. It currently relies on the fermentation of Botrytis cinerea, which suffers from limited availability of genetic engineering tools. Here, Yarrowia lipolytica was engineered to enable de novo biosynthesis of ABA. To overcome the rate-limiting P450 enzymes, systematic engineering strategies were implemented. Firstly, the dissolved oxygen was increased to boost the activity of P450 enzymes. Secondly, the expansion of endoplasmic reticulum was implemented to improve the functional expression of P450 enzymes. Lastly, rate-limiting enzymes were assembled to facilitate substrate trafficking. Moreover, ABA production was further improved by strengthening the mevalonate pathway. Finally, the engineered strain produced 1221.45 mg/L of ABA in a 5-L bioreactor. The study provides effective approaches for alleviating rate-limiting P450 enzymes to enhance ABA production and achieve competitive industrial-level ABA production in Y. lipolytica.
format Article
id doaj-art-2b30b78b8bfb4ecf82b50f9fe4d160b9
institution DOAJ
issn 2405-805X
language English
publishDate 2025-03-01
publisher KeAi Communications Co., Ltd.
record_format Article
series Synthetic and Systems Biotechnology
spelling doaj-art-2b30b78b8bfb4ecf82b50f9fe4d160b92025-08-20T03:13:21ZengKeAi Communications Co., Ltd.Synthetic and Systems Biotechnology2405-805X2025-03-0110116517310.1016/j.synbio.2024.10.004Systematic metabolic engineering of Yarrowia lipolytica for efficient production of phytohormone abscisic acidMei-Li Sun0Ziyun Zou1Lu Lin2Rodrigo Ledesma-Amaro3Kaifeng Wang4Xiao-Jun Ji5State Key Laboratory of Materials-Oriented Chemical Engineering, College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, No. 30 South Puzhu Road, Nanjing, 211816, People's Republic of ChinaState Key Laboratory of Materials-Oriented Chemical Engineering, College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, No. 30 South Puzhu Road, Nanjing, 211816, People's Republic of ChinaState Key Laboratory of Materials-Oriented Chemical Engineering, College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, No. 30 South Puzhu Road, Nanjing, 211816, People's Republic of ChinaDepartment of Bioengineering and Imperial College Centre for Synthetic Biology, Imperial College London, London, SW7 2AZ, United KingdomState Key Laboratory of Materials-Oriented Chemical Engineering, College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, No. 30 South Puzhu Road, Nanjing, 211816, People's Republic of China; Corresponding author.State Key Laboratory of Materials-Oriented Chemical Engineering, College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, No. 30 South Puzhu Road, Nanjing, 211816, People's Republic of China; Corresponding author.Abscisic acid (ABA) is an important phytohormone with diverse applications. It currently relies on the fermentation of Botrytis cinerea, which suffers from limited availability of genetic engineering tools. Here, Yarrowia lipolytica was engineered to enable de novo biosynthesis of ABA. To overcome the rate-limiting P450 enzymes, systematic engineering strategies were implemented. Firstly, the dissolved oxygen was increased to boost the activity of P450 enzymes. Secondly, the expansion of endoplasmic reticulum was implemented to improve the functional expression of P450 enzymes. Lastly, rate-limiting enzymes were assembled to facilitate substrate trafficking. Moreover, ABA production was further improved by strengthening the mevalonate pathway. Finally, the engineered strain produced 1221.45 mg/L of ABA in a 5-L bioreactor. The study provides effective approaches for alleviating rate-limiting P450 enzymes to enhance ABA production and achieve competitive industrial-level ABA production in Y. lipolytica.http://www.sciencedirect.com/science/article/pii/S2405805X24001340Abscisic acidPhytohormoneSesquiterpeneYarrowia lipolyticaP450 enzymes
spellingShingle Mei-Li Sun
Ziyun Zou
Lu Lin
Rodrigo Ledesma-Amaro
Kaifeng Wang
Xiao-Jun Ji
Systematic metabolic engineering of Yarrowia lipolytica for efficient production of phytohormone abscisic acid
Synthetic and Systems Biotechnology
Abscisic acid
Phytohormone
Sesquiterpene
Yarrowia lipolytica
P450 enzymes
title Systematic metabolic engineering of Yarrowia lipolytica for efficient production of phytohormone abscisic acid
title_full Systematic metabolic engineering of Yarrowia lipolytica for efficient production of phytohormone abscisic acid
title_fullStr Systematic metabolic engineering of Yarrowia lipolytica for efficient production of phytohormone abscisic acid
title_full_unstemmed Systematic metabolic engineering of Yarrowia lipolytica for efficient production of phytohormone abscisic acid
title_short Systematic metabolic engineering of Yarrowia lipolytica for efficient production of phytohormone abscisic acid
title_sort systematic metabolic engineering of yarrowia lipolytica for efficient production of phytohormone abscisic acid
topic Abscisic acid
Phytohormone
Sesquiterpene
Yarrowia lipolytica
P450 enzymes
url http://www.sciencedirect.com/science/article/pii/S2405805X24001340
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