2,4-Dichloro-6-{N-[2-(trifluoromethyl)phenyl]carboximidoyl}phenol
The title compound, C14H8Cl2F3NO, was synthesized by the condensation between trifluoromethylaniline and dichlorosalicylaldehyde by nucleophilic addition, forming a hemiaminal, followed by a dehydration to generate an imine. The compound crystallizes in an orthorhombic Pbca (Z = 8) space group with...
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| Language: | English |
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International Union of Crystallography
2024-11-01
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| Online Access: | https://journals.iucr.org/paper?S2414314624010745 |
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| author | Zizipho Xantini Alfred Muller Koop Lammertsma |
| author_facet | Zizipho Xantini Alfred Muller Koop Lammertsma |
| author_sort | Zizipho Xantini |
| collection | DOAJ |
| description | The title compound, C14H8Cl2F3NO, was synthesized by the condensation between trifluoromethylaniline and dichlorosalicylaldehyde by nucleophilic addition, forming a hemiaminal, followed by a dehydration to generate an imine. The compound crystallizes in an orthorhombic Pbca (Z = 8) space group with a dihedral angle of 44.70 (5)° between the two aromatic rings. In the crystal, the molecules pack together to form a zigzag pattern along the c axis. |
| format | Article |
| id | doaj-art-2aee819d4c82458ba4ed8d6dd67c3b55 |
| institution | OA Journals |
| issn | 2414-3146 |
| language | English |
| publishDate | 2024-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj-art-2aee819d4c82458ba4ed8d6dd67c3b552025-08-20T02:35:59ZengInternational Union of CrystallographyIUCrData2414-31462024-11-01911x24107410.1107/S2414314624010745pk40452,4-Dichloro-6-{N-[2-(trifluoromethyl)phenyl]carboximidoyl}phenolZizipho Xantini0Alfred Muller1Koop Lammertsma2Department of Chemical Sciences, University of Johannesburg, 2006, South AfricaDepartment of Chemical Sciences, University of Johannesburg, 2006, South AfricaDepartment of Chemical Sciences, University of Johannesburg, 2006, South AfricaThe title compound, C14H8Cl2F3NO, was synthesized by the condensation between trifluoromethylaniline and dichlorosalicylaldehyde by nucleophilic addition, forming a hemiaminal, followed by a dehydration to generate an imine. The compound crystallizes in an orthorhombic Pbca (Z = 8) space group with a dihedral angle of 44.70 (5)° between the two aromatic rings. In the crystal, the molecules pack together to form a zigzag pattern along the c axis.https://journals.iucr.org/paper?S2414314624010745crystal structureschiff basetrifluoromethylanilinedichlorosalicylaldehydeorthorhombic |
| spellingShingle | Zizipho Xantini Alfred Muller Koop Lammertsma 2,4-Dichloro-6-{N-[2-(trifluoromethyl)phenyl]carboximidoyl}phenol IUCrData crystal structure schiff base trifluoromethylaniline dichlorosalicylaldehyde orthorhombic |
| title | 2,4-Dichloro-6-{N-[2-(trifluoromethyl)phenyl]carboximidoyl}phenol |
| title_full | 2,4-Dichloro-6-{N-[2-(trifluoromethyl)phenyl]carboximidoyl}phenol |
| title_fullStr | 2,4-Dichloro-6-{N-[2-(trifluoromethyl)phenyl]carboximidoyl}phenol |
| title_full_unstemmed | 2,4-Dichloro-6-{N-[2-(trifluoromethyl)phenyl]carboximidoyl}phenol |
| title_short | 2,4-Dichloro-6-{N-[2-(trifluoromethyl)phenyl]carboximidoyl}phenol |
| title_sort | 2 4 dichloro 6 n 2 trifluoromethyl phenyl carboximidoyl phenol |
| topic | crystal structure schiff base trifluoromethylaniline dichlorosalicylaldehyde orthorhombic |
| url | https://journals.iucr.org/paper?S2414314624010745 |
| work_keys_str_mv | AT ziziphoxantini 24dichloro6n2trifluoromethylphenylcarboximidoylphenol AT alfredmuller 24dichloro6n2trifluoromethylphenylcarboximidoylphenol AT kooplammertsma 24dichloro6n2trifluoromethylphenylcarboximidoylphenol |