Synthesis, Biological, Spectral, and Thermal Investigations of Cobalt(II) and Nickel(II) Complexes of N-Isonicotinamido-2′,4′-Dichlorobenzalaldimine
A new series of 12 complexes of cobalt(II) and nickel(II) with N-isonicotinamido-2′,4′-dichlorobenzalaldimine (INH-DCB) with the general composition MX2⋅n(INH-DCB) [M = Co(II) or Ni(II), X = Cl−, Br−, NO3−, NCS−, or CH3COO−, n = 2; X = ClO4−, n = 3] have been synthesized. The nature of bonding and...
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| Format: | Article |
| Language: | English |
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Wiley
2006-01-01
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| Series: | Bioinorganic Chemistry and Applications |
| Online Access: | http://dx.doi.org/10.1155/BCA/2006/29234 |
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| author | Ram K. Agarwal Deepak Sharma Lakshman Singh Himanshu Agarwal |
| author_facet | Ram K. Agarwal Deepak Sharma Lakshman Singh Himanshu Agarwal |
| author_sort | Ram K. Agarwal |
| collection | DOAJ |
| description | A new series of 12 complexes of cobalt(II) and nickel(II) with N-isonicotinamido-2′,4′-dichlorobenzalaldimine (INH-DCB) with the general composition MX2⋅n(INH-DCB) [M = Co(II) or Ni(II), X = Cl−, Br−, NO3−, NCS−, or CH3COO−, n = 2; X = ClO4−, n = 3] have been synthesized. The nature of bonding and the stereochemistry of the complexes have been deduced from elemental analyses, infrared, electronic spectra, magnetic susceptibility, and conductivity measurements. An
octahedral geometry has been suggested for all the complexes. The metal complexes were screened for their antifungal and antibacterial activities on different species of pathogenic fungi and bacteria and their biopotency has been discussed. |
| format | Article |
| id | doaj-art-2a726e3dae5e4209868dc6bc07da0410 |
| institution | OA Journals |
| issn | 1565-3633 1687-479X |
| language | English |
| publishDate | 2006-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Bioinorganic Chemistry and Applications |
| spelling | doaj-art-2a726e3dae5e4209868dc6bc07da04102025-08-20T02:04:10ZengWileyBioinorganic Chemistry and Applications1565-36331687-479X2006-01-01200610.1155/BCA/2006/2923429234Synthesis, Biological, Spectral, and Thermal Investigations of Cobalt(II) and Nickel(II) Complexes of N-Isonicotinamido-2′,4′-DichlorobenzalaldimineRam K. Agarwal0Deepak Sharma1Lakshman Singh2Himanshu Agarwal3Department of Chemistry, School of Pure and Applied Sciences, The University of the South Pacific, PO Box 1168, Suva, FijiDepartment of Chemistry, Lajpat Rai Postgraduate College, Sahibabad 201005, IndiaDepartment of Chemistry, Lajpat Rai Postgraduate College, Sahibabad 201005, IndiaDepartment of Chemistry, Lajpat Rai Postgraduate College, Sahibabad 201005, IndiaA new series of 12 complexes of cobalt(II) and nickel(II) with N-isonicotinamido-2′,4′-dichlorobenzalaldimine (INH-DCB) with the general composition MX2⋅n(INH-DCB) [M = Co(II) or Ni(II), X = Cl−, Br−, NO3−, NCS−, or CH3COO−, n = 2; X = ClO4−, n = 3] have been synthesized. The nature of bonding and the stereochemistry of the complexes have been deduced from elemental analyses, infrared, electronic spectra, magnetic susceptibility, and conductivity measurements. An octahedral geometry has been suggested for all the complexes. The metal complexes were screened for their antifungal and antibacterial activities on different species of pathogenic fungi and bacteria and their biopotency has been discussed.http://dx.doi.org/10.1155/BCA/2006/29234 |
| spellingShingle | Ram K. Agarwal Deepak Sharma Lakshman Singh Himanshu Agarwal Synthesis, Biological, Spectral, and Thermal Investigations of Cobalt(II) and Nickel(II) Complexes of N-Isonicotinamido-2′,4′-Dichlorobenzalaldimine Bioinorganic Chemistry and Applications |
| title | Synthesis, Biological, Spectral, and Thermal Investigations of Cobalt(II) and Nickel(II) Complexes of N-Isonicotinamido-2′,4′-Dichlorobenzalaldimine |
| title_full | Synthesis, Biological, Spectral, and Thermal Investigations of Cobalt(II) and Nickel(II) Complexes of N-Isonicotinamido-2′,4′-Dichlorobenzalaldimine |
| title_fullStr | Synthesis, Biological, Spectral, and Thermal Investigations of Cobalt(II) and Nickel(II) Complexes of N-Isonicotinamido-2′,4′-Dichlorobenzalaldimine |
| title_full_unstemmed | Synthesis, Biological, Spectral, and Thermal Investigations of Cobalt(II) and Nickel(II) Complexes of N-Isonicotinamido-2′,4′-Dichlorobenzalaldimine |
| title_short | Synthesis, Biological, Spectral, and Thermal Investigations of Cobalt(II) and Nickel(II) Complexes of N-Isonicotinamido-2′,4′-Dichlorobenzalaldimine |
| title_sort | synthesis biological spectral and thermal investigations of cobalt ii and nickel ii complexes of n isonicotinamido 2 4 dichlorobenzalaldimine |
| url | http://dx.doi.org/10.1155/BCA/2006/29234 |
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