Phenol and 4-nitrophenol (4-NP) are hazardous, recalcitrant, and biorefractory contaminants found in wastewater generated from process industries. Even in low concentrations, they are highly poisonous. The degradation of these pollutants in wastewater is imperative due to their solubility in water a...
Saved in:
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Académie des sciences
2025-03-01
|
| Series: | Comptes Rendus. Chimie |
| Subjects: | |
| Online Access: | https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.385/ |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1849247146295951360 |
|---|---|
| author | Adeoye, Deborah Oluwatomilola Gano, Zaharaddeen Sani Ahmed, Omar Umar Shuwa, Suleiman Mohammed Atta, Abdulazeez Yusuf Jibril, Baba Yakubu |
| author_facet | Adeoye, Deborah Oluwatomilola Gano, Zaharaddeen Sani Ahmed, Omar Umar Shuwa, Suleiman Mohammed Atta, Abdulazeez Yusuf Jibril, Baba Yakubu |
| author_sort | Adeoye, Deborah Oluwatomilola |
| collection | DOAJ |
| description | Phenol and 4-nitrophenol (4-NP) are hazardous, recalcitrant, and biorefractory contaminants found in wastewater generated from process industries. Even in low concentrations, they are highly poisonous. The degradation of these pollutants in wastewater is imperative due to their solubility in water and their toxicity to the biosphere. In this study, two long-chain, organic acid based hydrophobic deep eutectic solvents (HDESs) were prepared, characterized, and used in synergy with hydrogen peroxide for the ultrasonic degradation of these pollutants in wastewater. These HDESs are menthol–decanoic acid (MC10) and menthol–dodecanoic acid (MC12). The HDESs were used in synergy with hydrogen peroxide for the degradation of phenol and 4-NP. The effects of different process variables such as pH, oxidant dose, temperature, and time on phenol and 4-NP degradation efficiency in simulated wastewater were studied. For phenol degradation, pH 4 provided the best result while for 4-NP, pH 5 provided the best result. For the MC10-HDES/H2O2 system, an oxidant dose of 15% v/v and temperature 60 °C yielded the best degradation efficiency of 76% for phenol and 94.46% for 4-NP while for the MC12-HDES/H2O2 system, an oxidant dose of 17% v/v and temperature 60 °C yielded the best degradation efficiency of 58.98% for phenol and 61.08% for 4-NP. The process parameters with the best results were then used to treat refinery wastewater. The percentage reductions in total organic compounds (TOC) were 88.75 and 67.08% for MC10- and MC12-HDES/H2O2 systems respectively. The recyclability of the HDESs was also investigated for three runs. The percentage of TOC reduced from 88.75 to 33.33% for MC10 and from 67.08 to 11.25% for MC12. These results prove this process to be effective for the treatment of wastewater contaminated with phenol and 4-NP. |
| format | Article |
| id | doaj-art-29bc48eb262f4f999d7f32a82cec2693 |
| institution | Kabale University |
| issn | 1878-1543 |
| language | English |
| publishDate | 2025-03-01 |
| publisher | Académie des sciences |
| record_format | Article |
| series | Comptes Rendus. Chimie |
| spelling | doaj-art-29bc48eb262f4f999d7f32a82cec26932025-08-20T03:58:18ZengAcadémie des sciencesComptes Rendus. Chimie1878-15432025-03-0128G132733810.5802/crchim.38510.5802/crchim.385Adeoye, Deborah Oluwatomilola0https://orcid.org/0000-0002-9201-7891Gano, Zaharaddeen Sani1https://orcid.org/0000-0002-7334-5531Ahmed, Omar Umar2Shuwa, Suleiman Mohammed3Atta, Abdulazeez Yusuf4https://orcid.org/0000-0001-8515-6300Jibril, Baba Yakubu5Department of Chemical Engineering, Ahmadu Bello University, Zaria, Kaduna State, Nigeria; Directorate of Research and Development, Nigerian Institute of Leather and Science Technology, Zaria, Kaduna State, NigeriaDepartment of Petrochemical and Allied Products, National Research Institute for Chemical Technology, Zaria, Kaduna State, NigeriaDepartment of Chemical and Petroleum Engineering, Bayero University, Kano, Kano State, NigeriaDepartment of Chemical Engineering, Ahmadu Bello University, Zaria, Kaduna State, NigeriaDepartment of Chemical Engineering, Ahmadu Bello University, Zaria, Kaduna State, NigeriaDepartment of Chemical Engineering, Ahmadu Bello University, Zaria, Kaduna State, NigeriaPhenol and 4-nitrophenol (4-NP) are hazardous, recalcitrant, and biorefractory contaminants found in wastewater generated from process industries. Even in low concentrations, they are highly poisonous. The degradation of these pollutants in wastewater is imperative due to their solubility in water and their toxicity to the biosphere. In this study, two long-chain, organic acid based hydrophobic deep eutectic solvents (HDESs) were prepared, characterized, and used in synergy with hydrogen peroxide for the ultrasonic degradation of these pollutants in wastewater. These HDESs are menthol–decanoic acid (MC10) and menthol–dodecanoic acid (MC12). The HDESs were used in synergy with hydrogen peroxide for the degradation of phenol and 4-NP. The effects of different process variables such as pH, oxidant dose, temperature, and time on phenol and 4-NP degradation efficiency in simulated wastewater were studied. For phenol degradation, pH 4 provided the best result while for 4-NP, pH 5 provided the best result. For the MC10-HDES/H2O2 system, an oxidant dose of 15% v/v and temperature 60 °C yielded the best degradation efficiency of 76% for phenol and 94.46% for 4-NP while for the MC12-HDES/H2O2 system, an oxidant dose of 17% v/v and temperature 60 °C yielded the best degradation efficiency of 58.98% for phenol and 61.08% for 4-NP. The process parameters with the best results were then used to treat refinery wastewater. The percentage reductions in total organic compounds (TOC) were 88.75 and 67.08% for MC10- and MC12-HDES/H2O2 systems respectively. The recyclability of the HDESs was also investigated for three runs. The percentage of TOC reduced from 88.75 to 33.33% for MC10 and from 67.08 to 11.25% for MC12. These results prove this process to be effective for the treatment of wastewater contaminated with phenol and 4-NP.https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.385/4-NitrophenolDecanoic acidDegradationDodecanoic acidHydrophobic deep eutectic solventMentholPhenol |
| spellingShingle | Adeoye, Deborah Oluwatomilola Gano, Zaharaddeen Sani Ahmed, Omar Umar Shuwa, Suleiman Mohammed Atta, Abdulazeez Yusuf Jibril, Baba Yakubu Comptes Rendus. Chimie 4-Nitrophenol Decanoic acid Degradation Dodecanoic acid Hydrophobic deep eutectic solvent Menthol Phenol |
| topic | 4-Nitrophenol Decanoic acid Degradation Dodecanoic acid Hydrophobic deep eutectic solvent Menthol Phenol |
| url | https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.385/ |