Utilization of Zinc Dust for a Core Monomer 2-Bromo-3-hexylthien-5-ylzinc Bromide: Its Synthesis and Application for the Preparation of Regioregular Poly(3-hexylthiophene)
The oxidative insertion of readily available zinc dust into the carbon-bromine bond of 2,5-dibromo-3-hexylthiophene was efficiently achieved to provide 2-bromo-3-hexylthien-5-ylzinc bromide (I), which was utilized for the preparation of highly regioregular poly(3-hexylthiophene) (P3HT) in the presen...
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| Format: | Article |
| Language: | English |
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Wiley
2014-01-01
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| Series: | International Journal of Polymer Science |
| Online Access: | http://dx.doi.org/10.1155/2014/847309 |
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| author | Seung-Hoi Kim |
| author_facet | Seung-Hoi Kim |
| author_sort | Seung-Hoi Kim |
| collection | DOAJ |
| description | The oxidative insertion of readily available zinc dust into the carbon-bromine bond of 2,5-dibromo-3-hexylthiophene was efficiently achieved to provide 2-bromo-3-hexylthien-5-ylzinc bromide (I), which was utilized for the preparation of highly regioregular poly(3-hexylthiophene) (P3HT) in the presence of catalytic amounts of Ni-catalyst. |
| format | Article |
| id | doaj-art-29b7fa6b517a45d9a7837a7f613990fe |
| institution | Kabale University |
| issn | 1687-9422 1687-9430 |
| language | English |
| publishDate | 2014-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Polymer Science |
| spelling | doaj-art-29b7fa6b517a45d9a7837a7f613990fe2025-02-03T00:59:57ZengWileyInternational Journal of Polymer Science1687-94221687-94302014-01-01201410.1155/2014/847309847309Utilization of Zinc Dust for a Core Monomer 2-Bromo-3-hexylthien-5-ylzinc Bromide: Its Synthesis and Application for the Preparation of Regioregular Poly(3-hexylthiophene)Seung-Hoi Kim0Department of Chemistry, Dankook University, 119 Dandae-ro, Cheonan 330-714, Republic of KoreaThe oxidative insertion of readily available zinc dust into the carbon-bromine bond of 2,5-dibromo-3-hexylthiophene was efficiently achieved to provide 2-bromo-3-hexylthien-5-ylzinc bromide (I), which was utilized for the preparation of highly regioregular poly(3-hexylthiophene) (P3HT) in the presence of catalytic amounts of Ni-catalyst.http://dx.doi.org/10.1155/2014/847309 |
| spellingShingle | Seung-Hoi Kim Utilization of Zinc Dust for a Core Monomer 2-Bromo-3-hexylthien-5-ylzinc Bromide: Its Synthesis and Application for the Preparation of Regioregular Poly(3-hexylthiophene) International Journal of Polymer Science |
| title | Utilization of Zinc Dust for a Core Monomer 2-Bromo-3-hexylthien-5-ylzinc Bromide: Its Synthesis and Application for the Preparation of Regioregular Poly(3-hexylthiophene) |
| title_full | Utilization of Zinc Dust for a Core Monomer 2-Bromo-3-hexylthien-5-ylzinc Bromide: Its Synthesis and Application for the Preparation of Regioregular Poly(3-hexylthiophene) |
| title_fullStr | Utilization of Zinc Dust for a Core Monomer 2-Bromo-3-hexylthien-5-ylzinc Bromide: Its Synthesis and Application for the Preparation of Regioregular Poly(3-hexylthiophene) |
| title_full_unstemmed | Utilization of Zinc Dust for a Core Monomer 2-Bromo-3-hexylthien-5-ylzinc Bromide: Its Synthesis and Application for the Preparation of Regioregular Poly(3-hexylthiophene) |
| title_short | Utilization of Zinc Dust for a Core Monomer 2-Bromo-3-hexylthien-5-ylzinc Bromide: Its Synthesis and Application for the Preparation of Regioregular Poly(3-hexylthiophene) |
| title_sort | utilization of zinc dust for a core monomer 2 bromo 3 hexylthien 5 ylzinc bromide its synthesis and application for the preparation of regioregular poly 3 hexylthiophene |
| url | http://dx.doi.org/10.1155/2014/847309 |
| work_keys_str_mv | AT seunghoikim utilizationofzincdustforacoremonomer2bromo3hexylthien5ylzincbromideitssynthesisandapplicationforthepreparationofregioregularpoly3hexylthiophene |