Characterization of Calcium Fluoride Prepared by Chemical Precipitation Method

Calcium fluoride (CaF2) was precipitated using chemical precipitation method. The quantity was divided into three samples. The X-ray diffraction of samples was clear. The peaks were displaced from each other towards the lower diffraction angles. This is due to an expansion of crystal lattice due to...

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Main Author: Imad Kadhim Khudhair
Format: Article
Language:English
Published: Tikrit University 2023-12-01
Series:Tikrit Journal of Pure Science
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Online Access:https://tjpsj.org/index.php/tjps/article/view/1513
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author Imad Kadhim Khudhair
author_facet Imad Kadhim Khudhair
author_sort Imad Kadhim Khudhair
collection DOAJ
description Calcium fluoride (CaF2) was precipitated using chemical precipitation method. The quantity was divided into three samples. The X-ray diffraction of samples was clear. The peaks were displaced from each other towards the lower diffraction angles. This is due to an expansion of crystal lattice due to an increase in the formation of atom voids in crystalline structure of compound CaF2. The results of absorption were clear. The energy gap for direct transmission is (3.7) eV and for indirect transmission is (2.9 and 3.1) eV. Evidence for the existence of atom voids. From the results of photoluminescence spectrum at excitation with a wavelength of (300) nm for the first and third samples and for second sample with (400) nm, a shift was observed in peaks as a result of change in density of atom voids and their displacement. The fluorescence spectrum also shifts towards longer wavelengths with increasing exposure to X-ray diffraction.
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issn 1813-1662
2415-1726
language English
publishDate 2023-12-01
publisher Tikrit University
record_format Article
series Tikrit Journal of Pure Science
spelling doaj-art-29b7e24ea48e4aca8a4cdb9302e8a6972025-08-20T02:36:34ZengTikrit UniversityTikrit Journal of Pure Science1813-16622415-17262023-12-0128610.25130/tjps.v28i6.1513Characterization of Calcium Fluoride Prepared by Chemical Precipitation MethodImad Kadhim Khudhair0Ministry of Education, Baghdad Education Directorate of Al- Karkh /2, Iraq Calcium fluoride (CaF2) was precipitated using chemical precipitation method. The quantity was divided into three samples. The X-ray diffraction of samples was clear. The peaks were displaced from each other towards the lower diffraction angles. This is due to an expansion of crystal lattice due to an increase in the formation of atom voids in crystalline structure of compound CaF2. The results of absorption were clear. The energy gap for direct transmission is (3.7) eV and for indirect transmission is (2.9 and 3.1) eV. Evidence for the existence of atom voids. From the results of photoluminescence spectrum at excitation with a wavelength of (300) nm for the first and third samples and for second sample with (400) nm, a shift was observed in peaks as a result of change in density of atom voids and their displacement. The fluorescence spectrum also shifts towards longer wavelengths with increasing exposure to X-ray diffraction. https://tjpsj.org/index.php/tjps/article/view/1513CaF2Chemical precipitation methodXRDPhotoluminescence spectrumAbsorption
spellingShingle Imad Kadhim Khudhair
Characterization of Calcium Fluoride Prepared by Chemical Precipitation Method
Tikrit Journal of Pure Science
CaF2
Chemical precipitation method
XRD
Photoluminescence spectrum
Absorption
title Characterization of Calcium Fluoride Prepared by Chemical Precipitation Method
title_full Characterization of Calcium Fluoride Prepared by Chemical Precipitation Method
title_fullStr Characterization of Calcium Fluoride Prepared by Chemical Precipitation Method
title_full_unstemmed Characterization of Calcium Fluoride Prepared by Chemical Precipitation Method
title_short Characterization of Calcium Fluoride Prepared by Chemical Precipitation Method
title_sort characterization of calcium fluoride prepared by chemical precipitation method
topic CaF2
Chemical precipitation method
XRD
Photoluminescence spectrum
Absorption
url https://tjpsj.org/index.php/tjps/article/view/1513
work_keys_str_mv AT imadkadhimkhudhair characterizationofcalciumfluoridepreparedbychemicalprecipitationmethod