Synthesis, Characterization and Thermal Analysis of a New Acetic Acid (2-Hydroxy-benzylidene)-hydrazide and its Complexes with Hg(II) and Pd(II)
The new complexes have been synthesized by the reaction of Hg(II) and Pd(II) with acetic acid(2-hydroxy-benzylidene)- hydrazide (L). These new complexes were characterized by elemental analysis, IR, H NMR spectroscopy and UV spectral techniques. The changes observed between the FT-IR, H NMR and UV-V...
Saved in:
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2011-01-01
|
| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2011/270304 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1832565082360381440 |
|---|---|
| author | Hajar Sahebalzamani Shahriare Ghammamy Shaghayegh Dexhkam Alireza Hemati Moghadam Farhod Siavoshifar |
| author_facet | Hajar Sahebalzamani Shahriare Ghammamy Shaghayegh Dexhkam Alireza Hemati Moghadam Farhod Siavoshifar |
| author_sort | Hajar Sahebalzamani |
| collection | DOAJ |
| description | The new complexes have been synthesized by the reaction of Hg(II) and Pd(II) with acetic acid(2-hydroxy-benzylidene)- hydrazide (L). These new complexes were characterized by elemental analysis, IR, H NMR spectroscopy and UV spectral techniques. The changes observed between the FT-IR, H NMR and UV-Vis spectra of the ligands and of the complexes allowed us to establish the coordination mode of the metal in complexes. Thermal properties, TG-DTA of these complexes were studied. TG- DTA and other analytical methods have been applied to the investigation of the thermal behavior and structure of the compounds [M(L)2]Cl2 M= Hg, Pd. Thermal decomposition of these compounds is multi-stage processes. |
| format | Article |
| id | doaj-art-299ca34b47a54419b145eb457da3e771 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2011-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-299ca34b47a54419b145eb457da3e7712025-02-03T01:09:23ZengWileyE-Journal of Chemistry0973-49452090-98102011-01-018S1S13S1810.1155/2011/270304Synthesis, Characterization and Thermal Analysis of a New Acetic Acid (2-Hydroxy-benzylidene)-hydrazide and its Complexes with Hg(II) and Pd(II)Hajar Sahebalzamani0Shahriare Ghammamy1Shaghayegh Dexhkam2Alireza Hemati Moghadam3Farhod Siavoshifar4Departments of Chemistry, Faculty of ScienceIslamic Azad University, Ardabil Branch, Ardabil, IranDepartments of Chemistry, Faculty of ScienceIslamic Azad University, Ardabil Branch, Ardabil, IranDepartments of Chemistry, Faculty of ScienceIslamic Azad University, Ardabil Branch, Ardabil, IranDepartments of Food IndustriesIslamic Azad University, Tabriz Branch, Tabriz, IranDepartment of Medicinal SciencesIslamic Azad University, Ardabil Branch, Ardabil, IranThe new complexes have been synthesized by the reaction of Hg(II) and Pd(II) with acetic acid(2-hydroxy-benzylidene)- hydrazide (L). These new complexes were characterized by elemental analysis, IR, H NMR spectroscopy and UV spectral techniques. The changes observed between the FT-IR, H NMR and UV-Vis spectra of the ligands and of the complexes allowed us to establish the coordination mode of the metal in complexes. Thermal properties, TG-DTA of these complexes were studied. TG- DTA and other analytical methods have been applied to the investigation of the thermal behavior and structure of the compounds [M(L)2]Cl2 M= Hg, Pd. Thermal decomposition of these compounds is multi-stage processes.http://dx.doi.org/10.1155/2011/270304 |
| spellingShingle | Hajar Sahebalzamani Shahriare Ghammamy Shaghayegh Dexhkam Alireza Hemati Moghadam Farhod Siavoshifar Synthesis, Characterization and Thermal Analysis of a New Acetic Acid (2-Hydroxy-benzylidene)-hydrazide and its Complexes with Hg(II) and Pd(II) E-Journal of Chemistry |
| title | Synthesis, Characterization and Thermal Analysis of a New Acetic Acid (2-Hydroxy-benzylidene)-hydrazide and its Complexes with Hg(II) and Pd(II) |
| title_full | Synthesis, Characterization and Thermal Analysis of a New Acetic Acid (2-Hydroxy-benzylidene)-hydrazide and its Complexes with Hg(II) and Pd(II) |
| title_fullStr | Synthesis, Characterization and Thermal Analysis of a New Acetic Acid (2-Hydroxy-benzylidene)-hydrazide and its Complexes with Hg(II) and Pd(II) |
| title_full_unstemmed | Synthesis, Characterization and Thermal Analysis of a New Acetic Acid (2-Hydroxy-benzylidene)-hydrazide and its Complexes with Hg(II) and Pd(II) |
| title_short | Synthesis, Characterization and Thermal Analysis of a New Acetic Acid (2-Hydroxy-benzylidene)-hydrazide and its Complexes with Hg(II) and Pd(II) |
| title_sort | synthesis characterization and thermal analysis of a new acetic acid 2 hydroxy benzylidene hydrazide and its complexes with hg ii and pd ii |
| url | http://dx.doi.org/10.1155/2011/270304 |
| work_keys_str_mv | AT hajarsahebalzamani synthesischaracterizationandthermalanalysisofanewaceticacid2hydroxybenzylidenehydrazideanditscomplexeswithhgiiandpdii AT shahriareghammamy synthesischaracterizationandthermalanalysisofanewaceticacid2hydroxybenzylidenehydrazideanditscomplexeswithhgiiandpdii AT shaghayeghdexhkam synthesischaracterizationandthermalanalysisofanewaceticacid2hydroxybenzylidenehydrazideanditscomplexeswithhgiiandpdii AT alirezahematimoghadam synthesischaracterizationandthermalanalysisofanewaceticacid2hydroxybenzylidenehydrazideanditscomplexeswithhgiiandpdii AT farhodsiavoshifar synthesischaracterizationandthermalanalysisofanewaceticacid2hydroxybenzylidenehydrazideanditscomplexeswithhgiiandpdii |