Synthesis, Characterization and Thermal Analysis of a New Acetic Acid (2-Hydroxy-benzylidene)-hydrazide and its Complexes with Hg(II) and Pd(II)

The new complexes have been synthesized by the reaction of Hg(II) and Pd(II) with acetic acid(2-hydroxy-benzylidene)- hydrazide (L). These new complexes were characterized by elemental analysis, IR, H NMR spectroscopy and UV spectral techniques. The changes observed between the FT-IR, H NMR and UV-V...

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Bibliographic Details
Main Authors: Hajar Sahebalzamani, Shahriare Ghammamy, Shaghayegh Dexhkam, Alireza Hemati Moghadam, Farhod Siavoshifar
Format: Article
Language:English
Published: Wiley 2011-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2011/270304
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Summary:The new complexes have been synthesized by the reaction of Hg(II) and Pd(II) with acetic acid(2-hydroxy-benzylidene)- hydrazide (L). These new complexes were characterized by elemental analysis, IR, H NMR spectroscopy and UV spectral techniques. The changes observed between the FT-IR, H NMR and UV-Vis spectra of the ligands and of the complexes allowed us to establish the coordination mode of the metal in complexes. Thermal properties, TG-DTA of these complexes were studied. TG- DTA and other analytical methods have been applied to the investigation of the thermal behavior and structure of the compounds [M(L)2]Cl2 M= Hg, Pd. Thermal decomposition of these compounds is multi-stage processes.
ISSN:0973-4945
2090-9810