Anticorrosion Behavior of Deposited Magnetite on Galvanized Steel in Saline Water Using RF-Magnetron Sputtering

Thin films of Magnetite have been deposited on Galvanized Steel (G-S) alloy using RF-reactive magnetron sputtering technique and protection efficiency of the corrosion of G-S. A Three-Electrodes Cell was used in saline water (3.5 % NaCl) solution at different temperatures (298, 308, 318 & 328K)...

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Main Author: Baghdad Science Journal
Format: Article
Language:English
Published: University of Baghdad, College of Science for Women 2018-12-01
Series:مجلة بغداد للعلوم
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Online Access:http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/34
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author Baghdad Science Journal
author_facet Baghdad Science Journal
author_sort Baghdad Science Journal
collection DOAJ
description Thin films of Magnetite have been deposited on Galvanized Steel (G-S) alloy using RF-reactive magnetron sputtering technique and protection efficiency of the corrosion of G-S. A Three-Electrodes Cell was used in saline water (3.5 % NaCl) solution at different temperatures (298, 308, 318 & 328K) using potentiostatic techniques with. Electrochemical Impedance Spectroscopy (EIS) and fitting impedance data via Frequency Response Analysis (FRA) were applied to G-S alloy with Fe3O4 and tested in 3.5 % NaCl solution at 298K.Results taken from Nyquist and Bode plots were analyzed using software provided with the instrument. The results obtained show that the rate of corrosion of G.S alloy increased with increasing the temperatures from 298 to 323K; and showed that deposition of Fe3O4 caused protection efficiency to reach 79.76% for G-S in 318K. In addition the enthalpy & entropy of activation were evaluated. Apparent energies of activation have been calculated for the corrosion process of uncoated and coated G.S alloy by sputtering technique in saline water (3.5 % NaCl). The morphological analysis was carried out using Scanning Electron Microscopy (SEM) technique.
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publishDate 2018-12-01
publisher University of Baghdad, College of Science for Women
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series مجلة بغداد للعلوم
spelling doaj-art-29923dc033da4fe194de642d902878b92025-08-20T02:54:54ZengUniversity of Baghdad, College of Science for Womenمجلة بغداد للعلوم2078-86652411-79862018-12-0115410.21123/bsj.15.4.406-414Anticorrosion Behavior of Deposited Magnetite on Galvanized Steel in Saline Water Using RF-Magnetron SputteringBaghdad Science JournalThin films of Magnetite have been deposited on Galvanized Steel (G-S) alloy using RF-reactive magnetron sputtering technique and protection efficiency of the corrosion of G-S. A Three-Electrodes Cell was used in saline water (3.5 % NaCl) solution at different temperatures (298, 308, 318 & 328K) using potentiostatic techniques with. Electrochemical Impedance Spectroscopy (EIS) and fitting impedance data via Frequency Response Analysis (FRA) were applied to G-S alloy with Fe3O4 and tested in 3.5 % NaCl solution at 298K.Results taken from Nyquist and Bode plots were analyzed using software provided with the instrument. The results obtained show that the rate of corrosion of G.S alloy increased with increasing the temperatures from 298 to 323K; and showed that deposition of Fe3O4 caused protection efficiency to reach 79.76% for G-S in 318K. In addition the enthalpy & entropy of activation were evaluated. Apparent energies of activation have been calculated for the corrosion process of uncoated and coated G.S alloy by sputtering technique in saline water (3.5 % NaCl). The morphological analysis was carried out using Scanning Electron Microscopy (SEM) technique.http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/34Corrosion protection, Electrochemical Impedance, Magnetite Nanoparticle, Polarization, Sputtering.
spellingShingle Baghdad Science Journal
Anticorrosion Behavior of Deposited Magnetite on Galvanized Steel in Saline Water Using RF-Magnetron Sputtering
مجلة بغداد للعلوم
Corrosion protection, Electrochemical Impedance, Magnetite Nanoparticle, Polarization, Sputtering.
title Anticorrosion Behavior of Deposited Magnetite on Galvanized Steel in Saline Water Using RF-Magnetron Sputtering
title_full Anticorrosion Behavior of Deposited Magnetite on Galvanized Steel in Saline Water Using RF-Magnetron Sputtering
title_fullStr Anticorrosion Behavior of Deposited Magnetite on Galvanized Steel in Saline Water Using RF-Magnetron Sputtering
title_full_unstemmed Anticorrosion Behavior of Deposited Magnetite on Galvanized Steel in Saline Water Using RF-Magnetron Sputtering
title_short Anticorrosion Behavior of Deposited Magnetite on Galvanized Steel in Saline Water Using RF-Magnetron Sputtering
title_sort anticorrosion behavior of deposited magnetite on galvanized steel in saline water using rf magnetron sputtering
topic Corrosion protection, Electrochemical Impedance, Magnetite Nanoparticle, Polarization, Sputtering.
url http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/34
work_keys_str_mv AT baghdadsciencejournal anticorrosionbehaviorofdepositedmagnetiteongalvanizedsteelinsalinewaterusingrfmagnetronsputtering