Ag anchored mesoporous carbon hollow sphere in Cellulose nanofibers/MXene composite films for high-performance electromagnetic interference shielding

The increasingly serious electromagnetic (EM) radiation and related pollution effects have gradually attracted people's attention in the information age. Hence, it's crucial to develop adaptive shielding materials with minimum EM waves (EMW) reflection. In this paper, Ag nanoparticles load...

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Main Authors: Wenting Tao, Wenqin Shao, Meng Ma, Si Chen, Yanqin Shi, Huiwen He, Yulu Zhu, Xu Wang
Format: Article
Language:English
Published: KeAi Communications Co., Ltd. 2025-02-01
Series:Nano Materials Science
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Online Access:http://www.sciencedirect.com/science/article/pii/S2589965124000126
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author Wenting Tao
Wenqin Shao
Meng Ma
Si Chen
Yanqin Shi
Huiwen He
Yulu Zhu
Xu Wang
author_facet Wenting Tao
Wenqin Shao
Meng Ma
Si Chen
Yanqin Shi
Huiwen He
Yulu Zhu
Xu Wang
author_sort Wenting Tao
collection DOAJ
description The increasingly serious electromagnetic (EM) radiation and related pollution effects have gradually attracted people's attention in the information age. Hence, it's crucial to develop adaptive shielding materials with minimum EM waves (EMW) reflection. In this paper, Ag nanoparticles loaded mesoporous carbon hollow spheres (MCHS@Ag) were synthesized by chemical reduction method, and cellulose nanofibers (CNF)/MXene/MCHS@Ag homogeneous composites were prepared. The total EM interference shielding efficiency (SET) of CNF/MXene/MCHS@Ag composite film was 32.83 ​dB (at 12.4 ​GHz), and the absorption effectiveness (SEA) was improved to 26.6 ​dB, which was 63.1% and 195.5% higher than that of CNF/MXene/MCHS composite film. The low dielectric property of MCHS effectively optimized the impedance matching between the composites and air. The hollow porous structure prolonged the transmission path of EMW and increased the absorption loss of the composites. At the same time, Ag nanoparticles located the MCHS were helpful to construct the internal conductive path overcoming the damage of the conductive property caused by the low dielectric of MCHS. This research adopts a straightforward method to construct a lightweight, pliable, and mesoporous composites for EMI shielding, which serves a crucial role in the current era of severe EM pollution.
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institution OA Journals
issn 2589-9651
language English
publishDate 2025-02-01
publisher KeAi Communications Co., Ltd.
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series Nano Materials Science
spelling doaj-art-28807cb9eca243f6acca0cb2e3f444e12025-08-20T02:16:01ZengKeAi Communications Co., Ltd.Nano Materials Science2589-96512025-02-0171657310.1016/j.nanoms.2024.02.001Ag anchored mesoporous carbon hollow sphere in Cellulose nanofibers/MXene composite films for high-performance electromagnetic interference shieldingWenting Tao0Wenqin Shao1Meng Ma2Si Chen3Yanqin Shi4Huiwen He5Yulu Zhu6Xu Wang7College of Materials Science and Engineering, Zhejiang Key Laboratory of Plastic Modification and Processing Technology, Zhejiang University of Technology, Hangzhou, 310014, PR ChinaCollege of Materials Science and Engineering, Zhejiang Key Laboratory of Plastic Modification and Processing Technology, Zhejiang University of Technology, Hangzhou, 310014, PR ChinaCollege of Materials Science and Engineering, Zhejiang Key Laboratory of Plastic Modification and Processing Technology, Zhejiang University of Technology, Hangzhou, 310014, PR China; State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu, 610065, PR China; Corresponding author. College of Materials Science and Engineering, Zhejiang Key Laboratory of Plastic Modification and Processing Technology, Zhejiang University of Technology, Hangzhou, 310014, PR China.College of Materials Science and Engineering, Zhejiang Key Laboratory of Plastic Modification and Processing Technology, Zhejiang University of Technology, Hangzhou, 310014, PR ChinaCollege of Materials Science and Engineering, Zhejiang Key Laboratory of Plastic Modification and Processing Technology, Zhejiang University of Technology, Hangzhou, 310014, PR ChinaCollege of Materials Science and Engineering, Zhejiang Key Laboratory of Plastic Modification and Processing Technology, Zhejiang University of Technology, Hangzhou, 310014, PR ChinaCollege of Materials Science and Engineering, Zhejiang Key Laboratory of Plastic Modification and Processing Technology, Zhejiang University of Technology, Hangzhou, 310014, PR ChinaCollege of Materials Science and Engineering, Zhejiang Key Laboratory of Plastic Modification and Processing Technology, Zhejiang University of Technology, Hangzhou, 310014, PR ChinaThe increasingly serious electromagnetic (EM) radiation and related pollution effects have gradually attracted people's attention in the information age. Hence, it's crucial to develop adaptive shielding materials with minimum EM waves (EMW) reflection. In this paper, Ag nanoparticles loaded mesoporous carbon hollow spheres (MCHS@Ag) were synthesized by chemical reduction method, and cellulose nanofibers (CNF)/MXene/MCHS@Ag homogeneous composites were prepared. The total EM interference shielding efficiency (SET) of CNF/MXene/MCHS@Ag composite film was 32.83 ​dB (at 12.4 ​GHz), and the absorption effectiveness (SEA) was improved to 26.6 ​dB, which was 63.1% and 195.5% higher than that of CNF/MXene/MCHS composite film. The low dielectric property of MCHS effectively optimized the impedance matching between the composites and air. The hollow porous structure prolonged the transmission path of EMW and increased the absorption loss of the composites. At the same time, Ag nanoparticles located the MCHS were helpful to construct the internal conductive path overcoming the damage of the conductive property caused by the low dielectric of MCHS. This research adopts a straightforward method to construct a lightweight, pliable, and mesoporous composites for EMI shielding, which serves a crucial role in the current era of severe EM pollution.http://www.sciencedirect.com/science/article/pii/S2589965124000126EMI shieldingPorous structureLow reflectionFilmAg anchored
spellingShingle Wenting Tao
Wenqin Shao
Meng Ma
Si Chen
Yanqin Shi
Huiwen He
Yulu Zhu
Xu Wang
Ag anchored mesoporous carbon hollow sphere in Cellulose nanofibers/MXene composite films for high-performance electromagnetic interference shielding
Nano Materials Science
EMI shielding
Porous structure
Low reflection
Film
Ag anchored
title Ag anchored mesoporous carbon hollow sphere in Cellulose nanofibers/MXene composite films for high-performance electromagnetic interference shielding
title_full Ag anchored mesoporous carbon hollow sphere in Cellulose nanofibers/MXene composite films for high-performance electromagnetic interference shielding
title_fullStr Ag anchored mesoporous carbon hollow sphere in Cellulose nanofibers/MXene composite films for high-performance electromagnetic interference shielding
title_full_unstemmed Ag anchored mesoporous carbon hollow sphere in Cellulose nanofibers/MXene composite films for high-performance electromagnetic interference shielding
title_short Ag anchored mesoporous carbon hollow sphere in Cellulose nanofibers/MXene composite films for high-performance electromagnetic interference shielding
title_sort ag anchored mesoporous carbon hollow sphere in cellulose nanofibers mxene composite films for high performance electromagnetic interference shielding
topic EMI shielding
Porous structure
Low reflection
Film
Ag anchored
url http://www.sciencedirect.com/science/article/pii/S2589965124000126
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