Revisit of Thiele’s acid synthesis from CO2 and cyclopentadiene and use for TCD-amine preparation with all-endo specific stereochemistry
ABSTRACT: This study provides a mild procedure using CO2, cyclopentadiene, and sodium tert-butoxide for Thiele’s acid in good yields and high purity. The product distribution of Thiele's acid and other isomeric forms can be tuned by utilizing different metal cations. Among the bases we have tri...
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| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2025-10-01
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| Series: | Journal of CO2 Utilization |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2212982025001611 |
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