Pouvoir discriminatoire du palladium(II) dans les réactions de substitution de ses chlorocomplexes avec les diamines

The rate constants of the substitution reactions of chloride and water by various diamines in chlorocomplexes of Pd(II) have been determined spectrophotometrically. The mechanism of substitution is associative and the comparison with the corresponding Pt(II) complexes shows that the discriminating...

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Bibliographic Details
Main Authors: R. Ernst, R. Roulet
Format: Article
Language:deu
Published: Swiss Chemical Society 1974-07-01
Series:CHIMIA
Online Access:https://www.chimia.ch/chimia/article/view/9150
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