The Use of Amberlite Adsorbents for Green Chromatography Determination of Volatile Organic Compounds in Air

Passive samplers have been widely used for volatile organic compounds determination. Following the green chemistry tendency of the direct determination of adsorbed compounds in membrane-based devices through using head space direct chromatography analysis, this work has evaluated the use of Amberlit...

Full description

Saved in:
Bibliographic Details
Main Authors: Luis Juan-Peiró, Anne Bernhammer, Agustin Pastor, Miguel de la Guardia
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:Journal of Analytical Methods in Chemistry
Online Access:http://dx.doi.org/10.1155/2012/728143
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1850229133365215232
author Luis Juan-Peiró
Anne Bernhammer
Agustin Pastor
Miguel de la Guardia
author_facet Luis Juan-Peiró
Anne Bernhammer
Agustin Pastor
Miguel de la Guardia
author_sort Luis Juan-Peiró
collection DOAJ
description Passive samplers have been widely used for volatile organic compounds determination. Following the green chemistry tendency of the direct determination of adsorbed compounds in membrane-based devices through using head space direct chromatography analysis, this work has evaluated the use of Amberlite XAD-2, XAD-4, and XAD-16 adsorbents as a filling material for passive samplers. Direct analysis of the membranes by HS-GC-MS involves a solvent-free method avoiding any sample treatment. For exposed membranes, recoveries ranged from 10% to 203%, depending on the compound and adsorbent used. The limit of the detection values ranged from 1 to 140 ng per sampler. Acceptable precision and sensitivity levels were obtained for the XAD resins assayed.
format Article
id doaj-art-27bc5ddee9414f2581049f9beea9ccba
institution OA Journals
issn 2090-8865
2090-8873
language English
publishDate 2012-01-01
publisher Wiley
record_format Article
series Journal of Analytical Methods in Chemistry
spelling doaj-art-27bc5ddee9414f2581049f9beea9ccba2025-08-20T02:04:20ZengWileyJournal of Analytical Methods in Chemistry2090-88652090-88732012-01-01201210.1155/2012/728143728143The Use of Amberlite Adsorbents for Green Chromatography Determination of Volatile Organic Compounds in AirLuis Juan-Peiró0Anne Bernhammer1Agustin Pastor2Miguel de la Guardia3Department of Analytical Chemistry, University of Valencia, Research Building, 50th Dr. Moliner Street, 46100 Burjassot, SpainInstitute of Inorganic and Analytical Chemistry, Johannes Gutenberg University Mainz, Duesbergweg 10-14, 55128 Mainz, GermanyDepartment of Analytical Chemistry, University of Valencia, Research Building, 50th Dr. Moliner Street, 46100 Burjassot, SpainDepartment of Analytical Chemistry, University of Valencia, Research Building, 50th Dr. Moliner Street, 46100 Burjassot, SpainPassive samplers have been widely used for volatile organic compounds determination. Following the green chemistry tendency of the direct determination of adsorbed compounds in membrane-based devices through using head space direct chromatography analysis, this work has evaluated the use of Amberlite XAD-2, XAD-4, and XAD-16 adsorbents as a filling material for passive samplers. Direct analysis of the membranes by HS-GC-MS involves a solvent-free method avoiding any sample treatment. For exposed membranes, recoveries ranged from 10% to 203%, depending on the compound and adsorbent used. The limit of the detection values ranged from 1 to 140 ng per sampler. Acceptable precision and sensitivity levels were obtained for the XAD resins assayed.http://dx.doi.org/10.1155/2012/728143
spellingShingle Luis Juan-Peiró
Anne Bernhammer
Agustin Pastor
Miguel de la Guardia
The Use of Amberlite Adsorbents for Green Chromatography Determination of Volatile Organic Compounds in Air
Journal of Analytical Methods in Chemistry
title The Use of Amberlite Adsorbents for Green Chromatography Determination of Volatile Organic Compounds in Air
title_full The Use of Amberlite Adsorbents for Green Chromatography Determination of Volatile Organic Compounds in Air
title_fullStr The Use of Amberlite Adsorbents for Green Chromatography Determination of Volatile Organic Compounds in Air
title_full_unstemmed The Use of Amberlite Adsorbents for Green Chromatography Determination of Volatile Organic Compounds in Air
title_short The Use of Amberlite Adsorbents for Green Chromatography Determination of Volatile Organic Compounds in Air
title_sort use of amberlite adsorbents for green chromatography determination of volatile organic compounds in air
url http://dx.doi.org/10.1155/2012/728143
work_keys_str_mv AT luisjuanpeiro theuseofamberliteadsorbentsforgreenchromatographydeterminationofvolatileorganiccompoundsinair
AT annebernhammer theuseofamberliteadsorbentsforgreenchromatographydeterminationofvolatileorganiccompoundsinair
AT agustinpastor theuseofamberliteadsorbentsforgreenchromatographydeterminationofvolatileorganiccompoundsinair
AT migueldelaguardia theuseofamberliteadsorbentsforgreenchromatographydeterminationofvolatileorganiccompoundsinair
AT luisjuanpeiro useofamberliteadsorbentsforgreenchromatographydeterminationofvolatileorganiccompoundsinair
AT annebernhammer useofamberliteadsorbentsforgreenchromatographydeterminationofvolatileorganiccompoundsinair
AT agustinpastor useofamberliteadsorbentsforgreenchromatographydeterminationofvolatileorganiccompoundsinair
AT migueldelaguardia useofamberliteadsorbentsforgreenchromatographydeterminationofvolatileorganiccompoundsinair