Evaluation of Advanced Biofuels in Internal Combustion Engines: Diesel/Fusel Oil/Vegetable Oil Triple Blends

In this research work, the feasibility of using fusel oil, a by-product of the sugar–alcohol industry, as an LVLC solvent in blends with straight vegetable oils (SVOs) and diesel was investigated. Concretely, diesel/fusel oil/sunflower oil (D/FO/SO) and diesel/fusel oil/castor oil (D/FO/CO) triple b...

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Main Authors: Rafael Estevez, Francisco J. López-Tenllado, Laura Aguado-Deblas, Felipa M. Bautista, Antonio A. Romero, Diego Luna
Format: Article
Language:English
Published: MDPI AG 2024-10-01
Series:Fuels
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Online Access:https://www.mdpi.com/2673-3994/5/4/36
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author Rafael Estevez
Francisco J. López-Tenllado
Laura Aguado-Deblas
Felipa M. Bautista
Antonio A. Romero
Diego Luna
author_facet Rafael Estevez
Francisco J. López-Tenllado
Laura Aguado-Deblas
Felipa M. Bautista
Antonio A. Romero
Diego Luna
author_sort Rafael Estevez
collection DOAJ
description In this research work, the feasibility of using fusel oil, a by-product of the sugar–alcohol industry, as an LVLC solvent in blends with straight vegetable oils (SVOs) and diesel was investigated. Concretely, diesel/fusel oil/sunflower oil (D/FO/SO) and diesel/fusel oil/castor oil (D/FO/CO) triple blends were prepared and characterized by measuring the most important physicochemical properties, i.e., viscosity, density, cold flow properties, flash point and cetane number. An appreciable improvement in cold flow values has been achieved with triple blends, without compromising properties such as calorific value and cetane number. Likewise, the triple blends meet the viscosity and density requirements specified by the European quality standard EN 14214 and the American standard ASTM D6751. After characterization, the triple blends were used on a diesel engine, evaluating different parameters such as power output, opacity, exhaust emissions (CO and NO<sub>x</sub>) and consumption at different engine loads. The results indicate that as the biofuel content in the blend increases, engine power decreases while fuel consumption rises. Nevertheless, the values obtained with D/FO/CO are better than those for D/FO/SO and are also very similar to those of fossil diesel. Regarding opacity values and NO<sub>x</sub> emissions obtained with the utilization of the triple blends, they are lower than those produced by diesel. However, in the case of CO emissions, it depends on the type of oil used, with the samples prepared with castor oil exhibiting the best results.
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institution Kabale University
issn 2673-3994
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publishDate 2024-10-01
publisher MDPI AG
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series Fuels
spelling doaj-art-27aea8228cb340a9a2219929a6c1fe202024-12-27T14:27:13ZengMDPI AGFuels2673-39942024-10-015466067210.3390/fuels5040036Evaluation of Advanced Biofuels in Internal Combustion Engines: Diesel/Fusel Oil/Vegetable Oil Triple BlendsRafael Estevez0Francisco J. López-Tenllado1Laura Aguado-Deblas2Felipa M. Bautista3Antonio A. Romero4Diego Luna5Departamento de Química Orgánica, Instituto Químico para la Energía y el Medioambiente (IQUEMA), Universidad de Córdoba, E-14071 Córdoba, SpainDepartamento de Química Orgánica, Instituto Químico para la Energía y el Medioambiente (IQUEMA), Universidad de Córdoba, E-14071 Córdoba, SpainDepartamento de Química Orgánica, Instituto Químico para la Energía y el Medioambiente (IQUEMA), Universidad de Córdoba, E-14071 Córdoba, SpainDepartamento de Química Orgánica, Instituto Químico para la Energía y el Medioambiente (IQUEMA), Universidad de Córdoba, E-14071 Córdoba, SpainDepartamento de Química Orgánica, Instituto Químico para la Energía y el Medioambiente (IQUEMA), Universidad de Córdoba, E-14071 Córdoba, SpainDepartamento de Química Orgánica, Instituto Químico para la Energía y el Medioambiente (IQUEMA), Universidad de Córdoba, E-14071 Córdoba, SpainIn this research work, the feasibility of using fusel oil, a by-product of the sugar–alcohol industry, as an LVLC solvent in blends with straight vegetable oils (SVOs) and diesel was investigated. Concretely, diesel/fusel oil/sunflower oil (D/FO/SO) and diesel/fusel oil/castor oil (D/FO/CO) triple blends were prepared and characterized by measuring the most important physicochemical properties, i.e., viscosity, density, cold flow properties, flash point and cetane number. An appreciable improvement in cold flow values has been achieved with triple blends, without compromising properties such as calorific value and cetane number. Likewise, the triple blends meet the viscosity and density requirements specified by the European quality standard EN 14214 and the American standard ASTM D6751. After characterization, the triple blends were used on a diesel engine, evaluating different parameters such as power output, opacity, exhaust emissions (CO and NO<sub>x</sub>) and consumption at different engine loads. The results indicate that as the biofuel content in the blend increases, engine power decreases while fuel consumption rises. Nevertheless, the values obtained with D/FO/CO are better than those for D/FO/SO and are also very similar to those of fossil diesel. Regarding opacity values and NO<sub>x</sub> emissions obtained with the utilization of the triple blends, they are lower than those produced by diesel. However, in the case of CO emissions, it depends on the type of oil used, with the samples prepared with castor oil exhibiting the best results.https://www.mdpi.com/2673-3994/5/4/36fusel oilstraight vegetable oilcastor oilsunflower oilbiofueldiesel engine
spellingShingle Rafael Estevez
Francisco J. López-Tenllado
Laura Aguado-Deblas
Felipa M. Bautista
Antonio A. Romero
Diego Luna
Evaluation of Advanced Biofuels in Internal Combustion Engines: Diesel/Fusel Oil/Vegetable Oil Triple Blends
Fuels
fusel oil
straight vegetable oil
castor oil
sunflower oil
biofuel
diesel engine
title Evaluation of Advanced Biofuels in Internal Combustion Engines: Diesel/Fusel Oil/Vegetable Oil Triple Blends
title_full Evaluation of Advanced Biofuels in Internal Combustion Engines: Diesel/Fusel Oil/Vegetable Oil Triple Blends
title_fullStr Evaluation of Advanced Biofuels in Internal Combustion Engines: Diesel/Fusel Oil/Vegetable Oil Triple Blends
title_full_unstemmed Evaluation of Advanced Biofuels in Internal Combustion Engines: Diesel/Fusel Oil/Vegetable Oil Triple Blends
title_short Evaluation of Advanced Biofuels in Internal Combustion Engines: Diesel/Fusel Oil/Vegetable Oil Triple Blends
title_sort evaluation of advanced biofuels in internal combustion engines diesel fusel oil vegetable oil triple blends
topic fusel oil
straight vegetable oil
castor oil
sunflower oil
biofuel
diesel engine
url https://www.mdpi.com/2673-3994/5/4/36
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