A review on the synergism between corrosion and fatigue of magnesium alloys: Mechanisms and processes on the micro-scale

Understanding the interaction between cyclic stresses and corrosion of magnesium (Mg) and its alloys is increasingly in demand due to the continuous expansion of structural applications of these materials. This review is dedicated to exploring the corrosion-fatigue mechanisms of these materials, wit...

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Main Authors: Mara Cristina Lopes de Oliveira, Rejane Maria Pereira da Silva, Ricardo M. Souto, Renato Altobelli Antunes
Format: Article
Language:English
Published: KeAi Communications Co., Ltd. 2024-08-01
Series:Journal of Magnesium and Alloys
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Online Access:http://www.sciencedirect.com/science/article/pii/S2213956724002780
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author Mara Cristina Lopes de Oliveira
Rejane Maria Pereira da Silva
Ricardo M. Souto
Renato Altobelli Antunes
author_facet Mara Cristina Lopes de Oliveira
Rejane Maria Pereira da Silva
Ricardo M. Souto
Renato Altobelli Antunes
author_sort Mara Cristina Lopes de Oliveira
collection DOAJ
description Understanding the interaction between cyclic stresses and corrosion of magnesium (Mg) and its alloys is increasingly in demand due to the continuous expansion of structural applications of these materials. This review is dedicated to exploring the corrosion-fatigue mechanisms of these materials, with an emphasis on microscale processes, and the possibility of expanding current knowledge on this topic using scanning electrochemical techniques. The interaction between fatigue and corrosion of Mg alloys is analyzed by considering the microstructural aspects (grain size, precipitates, deformation twins), as well as the formation of pits. Furthermore, in the case of coated alloys, the role of coating defects in these phenomena is also described. In this context, the feasibility of using scanning electrochemical microscopy (SECM), scanning vibrating electrode technique (SVET), scanning ion-selective electrode technique (SIET), localized electrochemical impedance spectroscopy (LEIS) and scanning Kelvin probe (SKP) methods to study the corrosion-fatigue interaction of Mg alloys is examined. A comprehensive review of the current literature in this field is presented, and the opportunities and limitations of consolidating the use of these techniques to study the microscale processes involved in Mg corrosion-fatigue are discussed.
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spelling doaj-art-26fafa83c8a7440fb80d8bd84d0a2a482025-08-20T01:54:45ZengKeAi Communications Co., Ltd.Journal of Magnesium and Alloys2213-95672024-08-011283062309310.1016/j.jma.2024.07.030A review on the synergism between corrosion and fatigue of magnesium alloys: Mechanisms and processes on the micro-scaleMara Cristina Lopes de Oliveira0Rejane Maria Pereira da Silva1Ricardo M. Souto2Renato Altobelli Antunes3Federal University of the ABC, Center for Engineering, Modeling and Applied Social Sciences, Av. Dos Estados, 5001, 09280-560 Santo André, SP, BrazilDepartment of Chemistry-PPGQ, State University of Piauí, UESPI, Campus Poeta Torquato Neto, Pirajá, Teresina 64002-150 PI, BrazilInstitute of Material Science and Nanotechnology, University of La Laguna, P.O. Box 456, 38200 La Laguna, Tenerife, SpainFederal University of the ABC, Center for Engineering, Modeling and Applied Social Sciences, Av. Dos Estados, 5001, 09280-560 Santo André, SP, Brazil; Corresponding author.Understanding the interaction between cyclic stresses and corrosion of magnesium (Mg) and its alloys is increasingly in demand due to the continuous expansion of structural applications of these materials. This review is dedicated to exploring the corrosion-fatigue mechanisms of these materials, with an emphasis on microscale processes, and the possibility of expanding current knowledge on this topic using scanning electrochemical techniques. The interaction between fatigue and corrosion of Mg alloys is analyzed by considering the microstructural aspects (grain size, precipitates, deformation twins), as well as the formation of pits. Furthermore, in the case of coated alloys, the role of coating defects in these phenomena is also described. In this context, the feasibility of using scanning electrochemical microscopy (SECM), scanning vibrating electrode technique (SVET), scanning ion-selective electrode technique (SIET), localized electrochemical impedance spectroscopy (LEIS) and scanning Kelvin probe (SKP) methods to study the corrosion-fatigue interaction of Mg alloys is examined. A comprehensive review of the current literature in this field is presented, and the opportunities and limitations of consolidating the use of these techniques to study the microscale processes involved in Mg corrosion-fatigue are discussed.http://www.sciencedirect.com/science/article/pii/S2213956724002780Magnesium alloysLocalized corrosion and protectionFatigueScanning electrochemical microscopyScanning vibrating electrode techniqueScanning ion-selective electrode technique
spellingShingle Mara Cristina Lopes de Oliveira
Rejane Maria Pereira da Silva
Ricardo M. Souto
Renato Altobelli Antunes
A review on the synergism between corrosion and fatigue of magnesium alloys: Mechanisms and processes on the micro-scale
Journal of Magnesium and Alloys
Magnesium alloys
Localized corrosion and protection
Fatigue
Scanning electrochemical microscopy
Scanning vibrating electrode technique
Scanning ion-selective electrode technique
title A review on the synergism between corrosion and fatigue of magnesium alloys: Mechanisms and processes on the micro-scale
title_full A review on the synergism between corrosion and fatigue of magnesium alloys: Mechanisms and processes on the micro-scale
title_fullStr A review on the synergism between corrosion and fatigue of magnesium alloys: Mechanisms and processes on the micro-scale
title_full_unstemmed A review on the synergism between corrosion and fatigue of magnesium alloys: Mechanisms and processes on the micro-scale
title_short A review on the synergism between corrosion and fatigue of magnesium alloys: Mechanisms and processes on the micro-scale
title_sort review on the synergism between corrosion and fatigue of magnesium alloys mechanisms and processes on the micro scale
topic Magnesium alloys
Localized corrosion and protection
Fatigue
Scanning electrochemical microscopy
Scanning vibrating electrode technique
Scanning ion-selective electrode technique
url http://www.sciencedirect.com/science/article/pii/S2213956724002780
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