Fast and Efficient Method for Imination of N-Aminorhodanine Using Inorganic Solid Support under Microwave Irradiation and Classical Heating
Reaction of N-aminorhodanine with various aldehydes under classical heating (in various solvents, using hydrochloric acid or acetic acid as catalyst) or by using Al2O3 under microwave irradiation in solventless system led to the corresponding imines (2 or 3). All the compounds have been characterize...
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| Format: | Article |
| Language: | English |
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Wiley
2011-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2011/351203 |
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| author | Masoumeh Tabatabaee Majid M. Heravi Mahboubeh Sharif Fatemeh Esfandiyari |
| author_facet | Masoumeh Tabatabaee Majid M. Heravi Mahboubeh Sharif Fatemeh Esfandiyari |
| author_sort | Masoumeh Tabatabaee |
| collection | DOAJ |
| description | Reaction of N-aminorhodanine with various aldehydes under classical heating (in various solvents, using hydrochloric acid or acetic acid as catalyst) or by using Al2O3 under microwave irradiation in solventless system led to the corresponding imines (2 or 3). All the compounds have been characterized by elemental analyses, NMR and IR spectroscopy. Results indicate that treatment of N-aminorhodanine with aldehydes in acetonitrile as solvent or under solventless system led to the corresponding imines (2a-2e), while reactions were performed in solvent such as methanol 3a-3e was formed as products of ring cleavage and imination. |
| format | Article |
| id | doaj-art-26b051ade29440f1bf86aa56a15f9385 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2011-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-26b051ade29440f1bf86aa56a15f93852025-02-03T06:08:18ZengWileyE-Journal of Chemistry0973-49452090-98102011-01-018253554010.1155/2011/351203Fast and Efficient Method for Imination of N-Aminorhodanine Using Inorganic Solid Support under Microwave Irradiation and Classical HeatingMasoumeh Tabatabaee0Majid M. Heravi1Mahboubeh Sharif2Fatemeh Esfandiyari3Scientific Society of NanotechnologyIslamic Azad University, Yazd Branch, Yazd, IranDepartment of ChemistrySchool of Sciences, Alzahra University, Tehran, IranDepartment of ChemistryIslamic Azad University- Qom Branch, Qom, IranDepartment of ChemistryIslamic Azad University- Yazd Branch, Yazd, IranReaction of N-aminorhodanine with various aldehydes under classical heating (in various solvents, using hydrochloric acid or acetic acid as catalyst) or by using Al2O3 under microwave irradiation in solventless system led to the corresponding imines (2 or 3). All the compounds have been characterized by elemental analyses, NMR and IR spectroscopy. Results indicate that treatment of N-aminorhodanine with aldehydes in acetonitrile as solvent or under solventless system led to the corresponding imines (2a-2e), while reactions were performed in solvent such as methanol 3a-3e was formed as products of ring cleavage and imination.http://dx.doi.org/10.1155/2011/351203 |
| spellingShingle | Masoumeh Tabatabaee Majid M. Heravi Mahboubeh Sharif Fatemeh Esfandiyari Fast and Efficient Method for Imination of N-Aminorhodanine Using Inorganic Solid Support under Microwave Irradiation and Classical Heating E-Journal of Chemistry |
| title | Fast and Efficient Method for Imination of N-Aminorhodanine Using Inorganic Solid Support under Microwave Irradiation and Classical Heating |
| title_full | Fast and Efficient Method for Imination of N-Aminorhodanine Using Inorganic Solid Support under Microwave Irradiation and Classical Heating |
| title_fullStr | Fast and Efficient Method for Imination of N-Aminorhodanine Using Inorganic Solid Support under Microwave Irradiation and Classical Heating |
| title_full_unstemmed | Fast and Efficient Method for Imination of N-Aminorhodanine Using Inorganic Solid Support under Microwave Irradiation and Classical Heating |
| title_short | Fast and Efficient Method for Imination of N-Aminorhodanine Using Inorganic Solid Support under Microwave Irradiation and Classical Heating |
| title_sort | fast and efficient method for imination of n aminorhodanine using inorganic solid support under microwave irradiation and classical heating |
| url | http://dx.doi.org/10.1155/2011/351203 |
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