Synthesis and Characterisation of Menthol-Based Hydrophobic Deep Eutectic Solvents

Hydrophobic deep eutectic solvents (HDESs) have found applications in water purification in recent years. The extent of their stability in aqueous media determines whether they are suitable materials for water purification or if they end up constituting a greater pollution load to the water they are...

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Main Authors: Deborah O. Adeoye, Zaharaddeen S. Gano, Omar U. Ahmed, Suleiman M. Shuwa, Abdulazeez Y. Atta, Samuel A. Iwarere, Baba Y. Jubril, Michael O. Daramola
Format: Article
Language:English
Published: MDPI AG 2023-11-01
Series:Chemistry Proceedings
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Online Access:https://www.mdpi.com/2673-4583/14/1/98
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author Deborah O. Adeoye
Zaharaddeen S. Gano
Omar U. Ahmed
Suleiman M. Shuwa
Abdulazeez Y. Atta
Samuel A. Iwarere
Baba Y. Jubril
Michael O. Daramola
author_facet Deborah O. Adeoye
Zaharaddeen S. Gano
Omar U. Ahmed
Suleiman M. Shuwa
Abdulazeez Y. Atta
Samuel A. Iwarere
Baba Y. Jubril
Michael O. Daramola
author_sort Deborah O. Adeoye
collection DOAJ
description Hydrophobic deep eutectic solvents (HDESs) have found applications in water purification in recent years. The extent of their stability in aqueous media determines whether they are suitable materials for water purification or if they end up constituting a greater pollution load to the water they are to purify. This work sought to prepare HDESs from a monoterpene (menthol), and three long-chain organic acids (octanoic acid, decanoic acid, and dodecanoic acid). The physicochemical characteristics of the prepared HDESs were investigated. Thereafter, their moisture absorption capacity and stability in an aqueous medium were determined to ascertain whether or not they were hydrophobic as predicted.
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series Chemistry Proceedings
spelling doaj-art-269e5cd3bbc543f4a5573a2ce71c1fa32025-08-20T02:00:35ZengMDPI AGChemistry Proceedings2673-45832023-11-011419810.3390/ecsoc-27-16334Synthesis and Characterisation of Menthol-Based Hydrophobic Deep Eutectic SolventsDeborah O. Adeoye0Zaharaddeen S. Gano1Omar U. Ahmed2Suleiman M. Shuwa3Abdulazeez Y. Atta4Samuel A. Iwarere5Baba Y. Jubril6Michael O. Daramola7Nigerian Institute of Leather and Science Technology, Zaria P.M.B 1034, Kaduna State, NigeriaNational Research Institute for Chemical Technology, Zaria P.M.B 1052, Kaduna State, NigeriaDepartment of Chemical and Petroleum Engineering, Bayero University, Kano P.M.B 3011, Kano State, NigeriaDepartment of Chemical Engineering, Ahmadu Bello University, Zaria P.M.B 06, Kaduna State, NigeriaDepartment of Chemical Engineering, Ahmadu Bello University, Zaria P.M.B 06, Kaduna State, NigeriaSustainable Energy and Environment Research Group, Department of Chemical Engineering, Faculty of Engineering, Built Environment and Information Technology, University of Pretoria, Hatfield, Pretoria 0028, South AfricaDepartment of Chemical Engineering, Ahmadu Bello University, Zaria P.M.B 06, Kaduna State, NigeriaSustainable Energy and Environment Research Group, Department of Chemical Engineering, Faculty of Engineering, Built Environment and Information Technology, University of Pretoria, Hatfield, Pretoria 0028, South AfricaHydrophobic deep eutectic solvents (HDESs) have found applications in water purification in recent years. The extent of their stability in aqueous media determines whether they are suitable materials for water purification or if they end up constituting a greater pollution load to the water they are to purify. This work sought to prepare HDESs from a monoterpene (menthol), and three long-chain organic acids (octanoic acid, decanoic acid, and dodecanoic acid). The physicochemical characteristics of the prepared HDESs were investigated. Thereafter, their moisture absorption capacity and stability in an aqueous medium were determined to ascertain whether or not they were hydrophobic as predicted.https://www.mdpi.com/2673-4583/14/1/98hydrophobic deep eutectic solventmentholoctanoic aciddecanoic aciddodecanoic acidmoisture absorption capacity
spellingShingle Deborah O. Adeoye
Zaharaddeen S. Gano
Omar U. Ahmed
Suleiman M. Shuwa
Abdulazeez Y. Atta
Samuel A. Iwarere
Baba Y. Jubril
Michael O. Daramola
Synthesis and Characterisation of Menthol-Based Hydrophobic Deep Eutectic Solvents
Chemistry Proceedings
hydrophobic deep eutectic solvent
menthol
octanoic acid
decanoic acid
dodecanoic acid
moisture absorption capacity
title Synthesis and Characterisation of Menthol-Based Hydrophobic Deep Eutectic Solvents
title_full Synthesis and Characterisation of Menthol-Based Hydrophobic Deep Eutectic Solvents
title_fullStr Synthesis and Characterisation of Menthol-Based Hydrophobic Deep Eutectic Solvents
title_full_unstemmed Synthesis and Characterisation of Menthol-Based Hydrophobic Deep Eutectic Solvents
title_short Synthesis and Characterisation of Menthol-Based Hydrophobic Deep Eutectic Solvents
title_sort synthesis and characterisation of menthol based hydrophobic deep eutectic solvents
topic hydrophobic deep eutectic solvent
menthol
octanoic acid
decanoic acid
dodecanoic acid
moisture absorption capacity
url https://www.mdpi.com/2673-4583/14/1/98
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